File name: Pandora138s1_Rome-IIA_20250412_L2Fit_fout2c1d20220121p1-8.txt File generation date: 20250412T231607.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v1d20220121.txt Level 1 file used: Pandora138s1_Rome-IIA_20250412_L1_smca1c1d20220121p1-8.txt Full location name: CNR-IIA Montelibretti Rome Short location name: Rome-IIA Country of location: Italy Location latitude [deg]: 42.1057 Location longitude [deg]: 12.6402 Location altitude [m]: 92 Local noon date: 20250412 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 210 351 Nominal wavelengths inside fitting window [nm]: 305.1046 305.2456 305.3867 305.5277 305.6687 305.8098 305.9508 306.0917 306.2327 306.3737 306.5147 306.6556 306.7965 306.9375 307.0784 307.2193 307.3602 307.5010 307.6419 307.7828 307.9236 308.0644 308.2053 308.3461 308.4869 308.6276 308.7684 308.9092 309.0499 309.1907 309.3314 309.4721 309.6128 309.7535 309.8942 310.0349 310.1756 310.3162 310.4569 310.5975 310.7381 310.8787 311.0193 311.1599 311.3005 311.4410 311.5816 311.7221 311.8627 312.0032 312.1437 312.2842 312.4247 312.5651 312.7056 312.8460 312.9865 313.1269 313.2673 313.4077 313.5481 313.6885 313.8289 313.9692 314.1096 314.2499 314.3902 314.5305 314.6709 314.8111 314.9514 315.0917 315.2319 315.3722 315.5124 315.6526 315.7929 315.9331 316.0732 316.2134 316.3536 316.4937 316.6339 316.7740 316.9141 317.0542 317.1943 317.3344 317.4745 317.6146 317.7546 317.8947 318.0347 318.1747 318.3147 318.4547 318.5947 318.7347 318.8746 319.0146 319.1545 319.2944 319.4344 319.5743 319.7141 319.8540 319.9939 320.1338 320.2736 320.4134 320.5533 320.6931 320.8329 320.9727 321.1124 321.2522 321.3920 321.5317 321.6714 321.8111 321.9509 322.0905 322.2302 322.3699 322.5096 322.6492 322.7889 322.9285 323.0681 323.2077 323.3473 323.4869 323.6264 323.7660 323.9056 324.0451 324.1846 324.3241 324.4636 324.6031 324.7426 324.8820 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250412T050213.5Z 9233.209878 195 1 48.00 2 85.61 82.14 100.44 269.42 0.00 1 0.00 1 0 49 5.913e-01 1.967e-01 2.740e-01 8.034e-02 5.339223e-01 4.205545e-02 6.658120e-03 -6.000000e+00 3.422489e-01 228.14 -2.00 3.53 -2.00 316.65 0.00e+00 1.259050e-03 3.988364e-03 4.534793e-05 -6.000000e+00 1.374460e-02 278.69 -2.00 20.00 -2.00 316.40 0.00e+00 10.780 0.024 302.00 328.00 3 8.6536e-01 1.0882e-01 1.1189e-01 -6.0000e+00 8.5783e-01 2.0691e+00 1.2209e-01 2.9790e-02 -6.0000e+00 9.3243e-01 -1.2090e+00 6.8923e-02 1.3677e-02 -6.0000e+00 5.4757e-01 2.9446e-01 3.0886e-02 3.9076e-03 -6.0000e+00 2.3136e-01 2.2635e-06 4.1292e-03 2.2797e-03 4.8730e-05 -6.0000e+00 1.6319e-02 -2.1002e-03 0.0000e+00 12 9 9 12 40 32 90.78 19.20 1.29 -0.00210 0.02893 12 3 4 8 0 4000.000 15.00 19.20 10.81 22.40 21.69 19.3 924.41 912 2233 3746 60385 -37344 -37394 -20725 -14684 261319 -35877 10515 25236 5441 82375 27320 72533 28675 14556 184336 11571 -23766 23429 212817 108136 14098 -23410 161271 170546 -24874 -18353 224650 -14098 75172 -14038 176310 102607 14999 69208 -26898 62812 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6.2310e-01 4.7281e-01 1.9775e-02 1.3399e-02 -6.0000e+00 2.6237e-01 2.5090e-05 -5.1930e-04 2.7282e-04 1.7911e-04 -6.0000e+00 1.8958e-02 -1.6930e-03 0.0000e+00 12 8 8 10 0 0 92.69 19.18 0.32 -0.00169 -0.00560 58 13 4 8 0 844.520 15.00 19.18 11.26 22.40 21.69 19.3 927.25 900000 -231053 -415 900000 -225257 -298016 -243181 -127498 900000 -229139 900000 900000 -161498 900000 900000 900000 900000 -100764 900000 -117568 57902 -74328 900000 900000 28331 -9526 -32221 900000 -32744 -101424 900000 46181 -1196 96610 900000 900000 47320 15083 -29553 54929 123642 -13401 900000 98037 62050 1052 13003 35375 -484 82523 -37453 60002 49254 167068 42141 58193 22163 26697 2462 13743 31356 -3810 21997 6369 21362 12237 20775 8855 26108 10182 13926 12968 6122 9576 -12098 6629 -6441 -2679 7183 597 -10266 5816 8703 -4108 4283 -466 4636 -2245 10437 6066 4374 -418 -3994 -2611 -3563 1114 -3724 2326 532 -867 -1345 -2399 -3757 -2387 -540 -4987 -1286 -3794 -1317 628 -65 -471 -2254 -1038 -595 369 -1544 1724 1184 674 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2.669730e-03 1.040928e-02 -6.000000e+00 4.355364e-01 228.14 -2.00 3.53 -2.00 322.05 0.00e+00 1.026017e-02 1.195240e-03 1.468559e-03 -6.000000e+00 1.979372e-02 278.69 -2.00 20.00 -2.00 321.72 0.00e+00 6.662 0.005 302.00 328.00 3 1.1806e+00 8.8614e-03 8.5230e-02 -6.0000e+00 1.0934e+00 5.7603e-01 1.4798e-02 5.4968e-02 -6.0000e+00 1.1902e+00 -8.0117e-01 1.8152e-02 3.2704e-02 -6.0000e+00 6.9775e-01 3.3189e-01 8.4387e-03 1.1726e-02 -6.0000e+00 2.9902e-01 8.0598e-05 -4.5345e-04 1.2697e-04 1.5011e-04 -6.0000e+00 2.1265e-02 -2.0865e-03 0.0000e+00 12 8 8 10 0 0 47.59 19.17 0.25 -0.00209 -0.00549 119 26 4 8 0 413.180 15.00 19.17 11.49 22.40 21.69 19.3 929.19 -259894 900000 -325829 900000 -253774 29970 -232785 -219074 900000 -251014 900000 -202811 900000 -184381 900000 -127494 -62895 -105852 -22774 120408 -100511 900000 -97982 900000 -55606 178977 -46476 191294 -16770 -57617 900000 -60681 59759 -28915 224558 9238 10562 15676 -23711 41795 -7072 54697 25574 41357 28162 42483 8030 28256 18625 15697 900000 4920 38500 29603 35789 21777 19705 16841 10122 19550 -22504 9038 10902 18202 9334 14821 5453 10094 14911 6583 13328 5240 11079 4018 4907 -2733 1717 -1610 -1124 4828 -4887 4043 -1125 4 -504 2396 366 -204 4223 976 3126 -3082 -3088 -4133 -955 -1633 -934 -134 -158 -7 -1392 -349 -1797 -434 -2673 -2044 -2771 -1185 -957 -1086 -545 -846 -361 -1007 -30 -911 261 683 355 337 1243 2406 1279 871 409 919 597 304 775 927 391 -164 324 69 -162 -128 470 -128 -80 -295 -766 -753 -2968 900000 -8450 900000 -2778 133 -2107 -1824 900000 -3148 900000 -2201 900000 -3216 900000 -2057 -628 -1794 -184 536 -1719 900000 -1663 900000 -676 797 -530 851 -152 -953 900000 -1639 593 -693 999 149 186 309 -807 893 -262 1209 778 1115 883 1213 336 1055 828 802 900000 355 2240 2022 2410 1723 1599 1360 836 1466 -2652 904 1258 2227 1297 1989 838 1610 2581 1388 2836 1212 2308 821 891 -487 295 -317 -264 1304 -1689 1469 -462 2 -231 1124 180 -102 2002 455 1340 -1363 -1408 -2119 -561 -1143 -757 -123 -153 -7 -1234 -275 -1326 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