File name: Pandora115s1_Rome-ISAC_20231113_L2Fit_fout2c1d20211213p1-8.txt File generation date: 20231113T230232.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 115 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora115_OF_v1d20210305.txt Instrument calibration file used: Pandora115s1_CF_v1d20211213.txt Level 1 file used: Pandora115s1_Rome-ISAC_20231113_L1_smca1c1d20211213p1-8.txt Full location name: CNR ISAC Rome Short location name: Rome-ISAC Country of location: Italy Location latitude [deg]: 41.8403 Location longitude [deg]: 12.6475 Location altitude [m]: 117 Local noon date: 20231113 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 245 386 Nominal wavelengths inside fitting window [nm]: 305.0951 305.2366 305.3781 305.5196 305.6611 305.8026 305.9440 306.0855 306.2269 306.3683 306.5097 306.6511 306.7925 306.9339 307.0752 307.2166 307.3579 307.4992 307.6405 307.7818 307.9231 308.0644 308.2056 308.3468 308.4881 308.6293 308.7705 308.9117 309.0528 309.1940 309.3351 309.4763 309.6174 309.7585 309.8996 310.0407 310.1818 310.3228 310.4639 310.6049 310.7459 310.8869 311.0279 311.1689 311.3099 311.4508 311.5918 311.7327 311.8736 312.0145 312.1554 312.2963 312.4372 312.5780 312.7189 312.8597 313.0005 313.1413 313.2821 313.4229 313.5637 313.7044 313.8452 313.9859 314.1266 314.2673 314.4080 314.5487 314.6894 314.8300 314.9707 315.1113 315.2519 315.3925 315.5331 315.6737 315.8143 315.9549 316.0954 316.2360 316.3765 316.5170 316.6575 316.7980 316.9385 317.0789 317.2194 317.3599 317.5003 317.6407 317.7811 317.9215 318.0619 318.2023 318.3427 318.4830 318.6234 318.7637 318.9040 319.0443 319.1846 319.3249 319.4652 319.6054 319.7457 319.8859 320.0262 320.1664 320.3066 320.4468 320.5870 320.7271 320.8673 321.0074 321.1476 321.2877 321.4278 321.5679 321.7080 321.8481 321.9882 322.1282 322.2683 322.4083 322.5483 322.6883 322.8283 322.9683 323.1083 323.2483 323.3882 323.5282 323.6681 323.8080 323.9479 324.0878 324.2277 324.3676 324.5075 324.6473 324.7871 324.9270 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231113T063837.4Z 8717.276821 58 1 49.34 2 83.78 120.85 84.70 123.44 0.00 1 0.00 1 0 25 5.855e-01 2.598e-02 3.415e-01 1.001e-02 8.831758e-01 5.376837e-03 9.485835e-03 -6.000000e+00 3.164481e-01 223.19 -2.00 3.53 -2.00 322.05 0.00e+00 3.593985e-03 2.376828e-03 1.158903e-03 -6.000000e+00 1.426532e-02 279.39 -2.00 20.00 -2.00 321.69 0.00e+00 8.301 0.011 302.00 328.00 3 1.8590e-01 1.7318e-02 9.4000e-02 -6.0000e+00 7.8781e-01 9.4443e-01 2.5061e-02 4.7049e-02 -6.0000e+00 8.6597e-01 -1.2384e+00 2.7238e-02 2.6704e-02 -6.0000e+00 5.0683e-01 5.0181e-01 1.3271e-02 9.3346e-03 -6.0000e+00 2.1556e-01 5.4479e-05 -6.1393e-04 2.4988e-04 1.0848e-04 -6.0000e+00 1.4088e-02 3.7054e-02 9.7421e-07 12 8 8 10 0 0 93.57 15.26 0.52 0.03705 0.03244 31 7 4 8 0 1591.450 15.00 15.26 15.76 21.27 20.67 31.9 926.39 156079 -140657 -61925 -84890 900000 -167397 54864 -200138 900000 900000 -148544 -65358 -132050 -19175 18356 238503 15483 21240 900000 250569 55818 -6637 81557 -60500 20644 -78136 63739 -31492 22783 29071 3320 133382 22048 161019 -27215 102433 24926 44110 59186 62704 66073 66812 46291 -6765 139774 58521 41861 22741 35371 723 47483 59969 19345 51078 26709 38072 29694 92811 21842 27297 23234 29727 25091 25508 32668 20897 29680 3644 7142 17547 15493 12591 13281 2704 -7325 5920 -495 15707 -4255 7323 -3646 4630 4110 -4393 4990 -2163 5984 -3338 2245 -2095 -1032 -1107 -3231 -311 -3483 -777 -3927 -2278 -4256 1641 -3794 -3015 -5009 -5490 -2642 -3723 984 -2397 -359 -1824 460 -699 2063 -269 1217 -741 -459 445 -2146 2335 72 3469 1404 2853 1162 1213 1106 1565 807 656 2168 673 1495 -904 355 -1454 -360 -802 -802 1348 -898 -1279 1522 -5113 -988 -1430 900000 -5195 535 -9760 900000 900000 -4478 -1043 -5386 -323 260 2326 275 377 900000 2444 643 -135 795 -2360 366 -3672 678 -810 343 490 91 1301 665 1570 -1134 1299 707 1252 1732 2001 2168 2251 1929 -468 2454 2340 1856 1290 1882 60 2821 3802 1818 3714 2558 3342 2791 4798 1956 2275 2184 3031 3137 3528 4171 2946 3974 698 1558 3843 3613 2970 2873 580 -1513 987 -90 2799 -1147 2117 -1377 1810 1709 -2107 2314 -1133 2982 -1814 1111 -1007 -461 -482 -1518 -166 -2310 -595 -3656 -2163 -4206 1557 -3324 -2296 -3859 -4659 -2312 -3470 946 -2461 -423 -2524 681 -1077 3047 -389 1669 -1052 -688 705 -3614 3640 107 4799 1944 3789 1522 1521 1490 2512 1534 1297 4554 1527 3634 -2433 921 -3877 -960 -2138 -2176 3283 -2042 -2802 SS 20231113T064442.4Z 8717.281047 61 1 49.47 2 82.81 121.93 83.80 124.51 0.00 1 0.00 1 0 25 5.634e-01 1.522e-02 2.217e-01 4.567e-03 8.193794e-01 2.370124e-03 8.786203e-03 -6.000000e+00 3.024663e-01 223.19 -2.00 3.53 -2.00 321.74 0.00e+00 3.586582e-03 1.009448e-03 9.782880e-04 -6.000000e+00 1.238735e-02 279.39 -2.00 20.00 -2.00 321.39 0.00e+00 7.366 0.007 302.00 328.00 3 -1.2199e-01 7.3903e-03 8.4033e-02 -6.0000e+00 7.5050e-01 4.4131e-01 1.1359e-02 4.3783e-02 -6.0000e+00 8.2299e-01 -5.9920e-01 1.3622e-02 2.5317e-02 -6.0000e+00 4.8518e-01 2.4834e-01 6.5635e-03 8.8514e-03 -6.0000e+00 2.0701e-01 2.0452e-04 -3.4892e-04 1.1248e-04 9.1597e-05 -6.0000e+00 1.3411e-02 3.5052e-02 8.9519e-05 12 8 8 10 0 0 15.99 15.26 0.31 0.03505 0.03243 85 18 4 8 0 581.960 15.01 15.26 16.34 21.27 20.67 31.7 929.33 -211272 -200440 -176628 -128921 26509 -239352 -47534 -266839 58100 -99699 -173602 -202365 -137675 -96101 -62977 19017 -48522 39365 7796 -15983 -70293 -42015 -34116 -76319 -63785 -66535 -49840 -51867 10669 -58776 -3619 -16356 453 9413 -23891 28070 -32821 8131 1145 10929 7149 53289 15805 12454 19212 23638 16829 14729 21126 1294 21582 32352 21571 12448 11086 10997 14466 23325 2073 8685 3698 9226 11413 15000 9428 11527 3577 2950 3388 6106 6263 5413 5794 1601 720 -3299 -5880 936 -1785 555 357 62 -181 -876 -1981 265 -294 1172 1368 622 -379 -1907 -631 -2056 -1333 -1358 -147 -1591 -1909 -905 -259 -321 -2524 -1767 -2277 -1963 -207 -352 -766 -376 416 418 419 -516 592 13 333 -142 -350 -103 1004 738 194 918 916 1977 680 563 287 845 679 627 261 -325 -200 -454 222 -276 -636 114 -382 -630 -3079 -2921 -2073 -918 118 -4166 -212 -7669 259 -666 -2551 -4956 -2391 -1455 -869 135 -756 280 80 -214 -1565 -692 -562 -2107 -1647 -1807 -1110 -1132 128 -1701 -77 -481 13 239 -777 562 -1403 286 53 530 392 1946 866 704 1035 1253 997 951 1373 115 1797 2694 2200 1497 1284 1459 1855 2617 274 1071 524 1307 1857 2629 1740 2044 711 651 883 1743 1879 1626 1621 422 168 -738 -1378 233 -564 206 155 31 -94 -489 -1194 165 -191 747 841 359 -207 -1022 -349 -1331 -1026 -1131 -142 -1758 -2159 -947 -236 -258 -2058 -1568 -2155 -1947 -217 -412 -1047 -543 647 663 651 -770 837 19 503 -231 -592 -169 1534 1082 280 1275 1334 2719 1006 911 543 1651 1426 1395 626 -791 -511 -1179 579 -723 -1588 280 -863 -1374 SS 20231113T065807.4Z 8717.290363 64 1 49.39 2 80.72 124.37 81.87 126.90 0.00 1 0.00 1 0 25 4.406e-01 7.807e-03 6.333e-02 1.696e-03 6.873964e-01 8.518813e-04 7.709195e-03 -6.000000e+00 2.365209e-01 223.19 -2.00 3.53 -2.00 320.96 0.00e+00 2.657615e-03 3.149511e-04 5.801919e-04 -6.000000e+00 9.688281e-03 279.39 -2.00 20.00 -2.00 320.64 0.00e+00 5.897 0.004 302.00 328.00 3 -2.4565e-01 2.4927e-03 6.7812e-02 -6.0000e+00 5.8686e-01 1.2191e-01 3.4510e-03 3.6019e-02 -6.0000e+00 6.4360e-01 -1.3334e-01 4.0867e-03 1.9876e-02 -6.0000e+00 3.7942e-01 4.8342e-02 2.0623e-03 6.5726e-03 -6.0000e+00 1.6186e-01 1.0563e-03 -2.9431e-04 4.2230e-05 6.5692e-05 -6.0000e+00 1.0491e-02 3.5177e-02 4.7491e-05 11 8 0 10 0 0 9.21 15.27 0.29 0.03518 0.03297 216 46 4 8 0 228.630 15.01 15.27 17.39 21.27 20.67 31.9 936.66 -163164 -164559 -123059 -175990 -111216 -179750 -114490 -155502 -115195 -104650 -121986 -97283 -99044 -49452 -75955 -27514 -42656 -29141 -29490 -29126 -27949 -34642 -13812 -28471 -25161 -30095 -18807 -37973 -18733 -32001 -10608 -9513 -2971 -6692 -13356 -6011 -10286 -1061 -2857 1584 -370 1339 2951 2206 3672 2083 4828 1037 4201 1257 5458 4732 4401 4731 2679 3775 1498 3788 -860 2565 682 2922 3961 3883 2113 3072 1989 1174 1467 1210 1820 -143 682 -244 11 -709 -1781 -485 -1557 -1104 -1503 -1747 -1995 -1118 -731 -711 -324 396 917 264 411 -106 398 -230 -319 60 689 318 -442 -264 9 30 -756 -1179 -1492 -1063 -164 -164 -116 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