File name: Pandora115s1_Rome-ISAC_20240410_L2Fit_fout2c5d20230305p1-8.txt File generation date: 20241031T005913.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 115 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora115_OF_v1d20210305.txt Instrument calibration file used: Pandora115s1_CF_v5d20230305.txt Level 1 file used: Pandora115s1_Rome-ISAC_20240410_L1_smca1c5d20230305p1-8.txt Full location name: CNR ISAC Rome Short location name: Rome-ISAC Country of location: Italy Location latitude [deg]: 41.8403 Location longitude [deg]: 12.6475 Location altitude [m]: 117 Local noon date: 20240410 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 245 386 Nominal wavelengths inside fitting window [nm]: 305.1112 305.2528 305.3944 305.5360 305.6775 305.8191 305.9606 306.1021 306.2436 306.3851 306.5266 306.6681 306.8096 306.9510 307.0924 307.2338 307.3752 307.5166 307.6580 307.7994 307.9407 308.0820 308.2234 308.3647 308.5059 308.6472 308.7885 308.9297 309.0710 309.2122 309.3534 309.4946 309.6358 309.7770 309.9181 310.0593 310.2004 310.3415 310.4826 310.6237 310.7648 310.9058 311.0469 311.1879 311.3289 311.4699 311.6109 311.7519 311.8929 312.0338 312.1748 312.3157 312.4566 312.5975 312.7384 312.8793 313.0202 313.1610 313.3018 313.4427 313.5835 313.7243 313.8651 314.0058 314.1466 314.2873 314.4281 314.5688 314.7095 314.8502 314.9909 315.1315 315.2722 315.4128 315.5534 315.6941 315.8347 315.9753 316.1158 316.2564 316.3969 316.5375 316.6780 316.8185 316.9590 317.0995 317.2400 317.3804 317.5209 317.6613 317.8017 317.9421 318.0825 318.2229 318.3633 318.5036 318.6440 318.7843 318.9246 319.0649 319.2052 319.3455 319.4858 319.6260 319.7663 319.9065 320.0467 320.1869 320.3271 320.4673 320.6075 320.7476 320.8878 321.0279 321.1680 321.3081 321.4482 321.5883 321.7284 321.8684 322.0085 322.1485 322.2885 322.4285 322.5685 322.7085 322.8484 322.9884 323.1283 323.2683 323.4082 323.5481 323.6880 323.8279 323.9677 324.1076 324.2474 324.3872 324.5271 324.6669 324.8067 324.9464 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240410T054001.6Z 8866.236130 63 1 49.86 2 79.13 88.76 87.69 69.52 0.00 1 0.00 1 0 25 5.375e-01 1.055e-02 2.008e-01 3.491e-03 7.650737e-01 1.825125e-03 8.617629e-03 -6.000000e+00 2.952510e-01 228.08 -2.00 3.53 -2.00 321.10 0.00e+00 2.957025e-03 8.190249e-04 1.443003e-03 -6.000000e+00 1.286151e-02 278.62 -2.00 20.00 -2.00 320.59 0.00e+00 5.109 0.002 302.00 328.00 3 2.1134e+00 5.8864e-03 6.4990e-02 -6.0000e+00 7.3712e-01 2.0503e-01 8.3665e-03 4.1657e-02 -6.0000e+00 8.0367e-01 -2.1426e-01 9.0913e-03 2.2855e-02 -6.0000e+00 4.7653e-01 7.7299e-02 4.3679e-03 7.8334e-03 -6.0000e+00 2.0356e-01 1.7610e-04 -9.4631e-04 8.4130e-05 7.7403e-05 -6.0000e+00 1.2812e-02 7.9466e-03 0.0000e+00 12 8 8 10 0 0 99.93 15.48 0.31 0.00795 0.00084 49 10 4 8 0 1017.500 15.01 15.48 19.68 21.98 21.27 33.6 990.43 -212077 -154711 -186501 161128 -185282 -123411 -250656 -191118 -131186 -47805 -107267 -152953 -19067 -127463 81801 -92265 23992 -52691 900000 -38487 -19514 -25964 -41604 14337 -58427 -23806 -77727 -10902 -47104 -4556 -7729 -1150 18251 -5676 2076 6161 8854 -23596 4500 -5214 5814 5006 7512 -1906 8791 7830 -8335 11752 -498 3276 2095 12208 7180 2388 5869 1366 5170 3351 3664 -557 10147 -154 5705 4323 2787 5770 -242 2050 -967 3243 112 3233 -727 1523 -157 -2815 -1652 516 -949 -1294 517 -1834 -1005 -2002 155 -425 -302 896 217 955 -1377 -507 -1043 856 -1415 145 647 69 -1242 -653 -43 -803 -189 -2027 -1176 -1654 200 -231 -343 447 146 598 -92 215 86 930 423 732 -742 -198 629 728 37 350 500 523 1244 -67 -110 -162 98 485 -141 0 -344 -177 -128 97 -540 93 -24 -16 -2428 -1149 -2020 548 -1663 -611 -5041 -2484 -1055 -195 -763 -2130 -104 -2485 278 -1941 196 -946 900000 -679 -284 -402 -824 200 -1663 -501 -2766 -192 -1224 -92 -206 -35 531 -209 66 194 318 -1468 263 -394 432 400 609 -171 726 673 -877 1076 -55 389 290 1711 1166 440 1097 280 1030 656 686 -109 1931 -38 1530 1203 784 1669 -70 631 -364 1325 50 1397 -308 574 -53 -892 -565 176 -402 -659 301 -1227 -651 -1392 113 -328 -242 707 167 678 -932 -352 -743 627 -1255 149 711 85 -1597 -782 -45 -802 -185 -2053 -1253 -1852 235 -299 -476 698 232 959 -144 339 128 1387 666 1222 -1233 -321 1017 1123 56 508 699 742 1698 -109 -193 -316 191 989 -309 0 -811 -424 -310 234 -1251 209 -49 -31 SS 20240410T054704.2Z 8866.241020 66 1 49.53 2 77.82 89.94 86.48 70.61 0.00 1 0.00 1 0 25 3.944e-01 7.857e-03 1.021e-01 2.523e-03 6.960672e-01 1.292030e-03 7.914066e-03 -6.000000e+00 2.161427e-01 228.08 -2.00 3.53 -2.00 320.70 0.00e+00 2.054701e-03 5.211601e-04 7.078088e-04 -6.000000e+00 9.389549e-03 278.62 -2.00 20.00 -2.00 320.17 0.00e+00 4.600 0.002 302.00 328.00 3 2.0874e+00 3.9787e-03 5.8511e-02 -6.0000e+00 5.3897e-01 1.4302e-01 5.3072e-03 3.7088e-02 -6.0000e+00 5.8689e-01 -1.2448e-01 5.5101e-03 1.9483e-02 -6.0000e+00 3.4834e-01 3.9485e-02 2.7298e-03 6.3722e-03 -6.0000e+00 1.4931e-01 3.1402e-04 -8.8734e-04 6.1378e-05 5.9530e-05 -6.0000e+00 9.4002e-03 7.5001e-03 0.0000e+00 11 8 0 10 0 0 99.96 15.48 0.15 0.00750 0.00083 71 15 4 8 0 697.500 15.01 15.48 20.03 21.98 21.27 33.6 992.41 -114903 -158577 -102229 -135315 -127724 -157309 -150271 -137264 -73620 21219 -130925 -102628 -100672 -77312 -16120 -15380 -24607 -26244 17844 -34492 8321 -40455 4518 -26297 -33720 -21700 -34732 -9852 -25915 -12794 -18399 -597 -10533 5331 -15674 9025 -10416 -7401 1607 -1409 3885 -1170 4242 -4016 7772 2970 2083 3751 879 2703 2774 7265 2150 3074 965 3369 1598 4208 1173 1454 4604 1384 3422 2409 1108 2048 422 82 102 2050 1579 465 188 1088 -2547 -1108 -2447 -460 -1581 -1040 -364 -1235 -1030 -1014 -443 -769 296 -132 523 3 -435 403 -298 325 -472 44 685 357 -757 -584 -122 -42 -219 -1434 -1383 -892 210 -251 -143 -30 324 318 -51 302 429 859 64 316 -572 39 -72 807 -20 483 170 584 959 274 50 -131 13 320 -57 -174 -251 -150 -49 -18 -616 67 22 175 -868 -2066 -824 -1389 -1117 -1878 -1903 -1812 -595 73 -2034 -1470 -1860 -1481 -217 -241 -468 -564 270 -904 146 -1132 90 -784 -1165 -699 -1250 -271 -841 -423 -799 -26 -583 253 -846 401 -648 -553 136 -142 407 -137 490 -504 892 367 266 500 127 422 490 1367 461 704 235 840 410 1023 283 350 1162 408 1132 882 405 717 152 32 46 1014 823 246 95 506 -1101 -435 -965 -194 -794 -605 -238 -891 -776 -801 -370 -672 265 -119 454 2 -340 300 -225 268 -443 47 802 454 -987 -724 -138 -43 -224 -1589 -1606 -1064 261 -334 -208 -47 535 529 -82 470 642 1285 99 512 -965 66 -115 1251 -30 716 248 811 1358 431 86 -242 24 634 -118 -377 -564 -339 -113 -41 -1380 142 45 346 SS 20240410T055721.2Z 8866.248162 71 1 49.35 2 75.90 91.65 84.71 72.17 0.00 1 0.00 1 0 25 2.100e-01 5.908e-03 3.245e-02 1.245e-03 6.189867e-01 6.265564e-04 7.141205e-03 -6.000000e+00 1.150637e-01 228.08 -2.00 3.53 -2.00 320.10 0.00e+00 1.283091e-03 2.100513e-04 3.896235e-04 -6.000000e+00 4.998275e-03 278.63 -2.00 20.00 -2.00 319.53 0.00e+00 4.015 0.001 302.00 328.00 3 1.4800e+00 1.8247e-03 5.1346e-02 -6.0000e+00 2.8692e-01 8.7834e-02 2.2643e-03 3.2541e-02 -6.0000e+00 3.1242e-01 -6.5396e-02 2.1576e-03 1.6514e-02 -6.0000e+00 1.8543e-01 1.7159e-02 1.1137e-03 5.0446e-03 -6.0000e+00 7.9493e-02 1.0948e-03 -7.3893e-04 3.0665e-05 4.5739e-05 -6.0000e+00 5.0038e-03 6.9307e-03 0.0000e+00 10 0 0 10 0 0 99.96 15.49 0.23 0.00693 0.00138 155 33 4 8 0 318.330 14.98 15.49 20.34 21.98 21.27 33.6 994.72 -79781 -79567 -67671 -78976 -68844 -87125 -59773 -76397 -39164 -44502 -59749 -53299 -39622 -22982 -25308 -8596 -18703 -9342 -9120 -5129 -12895 -10726 -4636 -9176 -8808 -13493 -5754 -9268 -5659 -5482 -2503 -3525 -2231 -3165 -5445 -785 -3545 -1866 278 -297 -335 6 1046 -84 1996 1047 896 -167 1216 901 2144 1934 1565 1932 1333 1418 776 1072 36 914 1418 1495 2418 1438 93 1274 400 484 507 788 790 -63 434 -268 -668 -824 -1192 -888 -804 -933 -1127 -1470 -1788 -797 -649 -305 -357 498 585 501 265 217 493 119 -101 146 1136 228 -531 -271 -234 -43 -250 -927 -1279 -841 -260 237 -18 171 80 337 65 328 492 771 262 2 -409 -421 -75 875 -175 129 -86 649 1089 334 -263 -108 -90 267 -79 -251 -210 -90 116 -2 -603 18 5 253 -891 -1004 -797 -959 -685 -1068 -639 -1141 -456 -578 -936 -932 -784 -494 -694 -232 -615 -310 -322 -184 -502 -409 -181 -420 -436 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