File name: Pandora115s1_Rome-ISAC_20240520_L2Fit_fwvt1c1d20211213p1-8.txt File generation date: 20240520T231341.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 115 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora115_OF_v1d20210305.txt Instrument calibration file used: Pandora115s1_CF_v1d20211213.txt Level 1 file used: Pandora115s1_Rome-ISAC_20240520_L1_smca1c1d20211213p1-8.txt Full location name: CNR ISAC Rome Short location name: Rome-ISAC Country of location: Italy Location latitude [deg]: 41.8403 Location longitude [deg]: 12.6475 Location altitude [m]: 117 Local noon date: 20240520 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1660 1809 Nominal wavelengths inside fitting window [nm]: 492.0467 492.1681 492.2895 492.4109 492.5323 492.6537 492.7751 492.8964 493.0177 493.1390 493.2603 493.3816 493.5029 493.6241 493.7454 493.8666 493.9878 494.1090 494.2301 494.3513 494.4724 494.5935 494.7146 494.8357 494.9568 495.0778 495.1988 495.3199 495.4409 495.5619 495.6828 495.8038 495.9247 496.0456 496.1665 496.2874 496.4083 496.5292 496.6500 496.7708 496.8916 497.0124 497.1332 497.2540 497.3747 497.4954 497.6161 497.7368 497.8575 497.9782 498.0988 498.2195 498.3401 498.4607 498.5812 498.7018 498.8224 498.9429 499.0634 499.1839 499.3044 499.4249 499.5453 499.6658 499.7862 499.9066 500.0270 500.1474 500.2677 500.3881 500.5084 500.6287 500.7490 500.8693 500.9896 501.1098 501.2300 501.3503 501.4705 501.5906 501.7108 501.8310 501.9511 502.0712 502.1913 502.3114 502.4315 502.5516 502.6716 502.7917 502.9117 503.0317 503.1517 503.2716 503.3916 503.5115 503.6315 503.7514 503.8713 503.9911 504.1110 504.2309 504.3507 504.4705 504.5903 504.7101 504.8299 504.9496 505.0694 505.1891 505.3088 505.4285 505.5482 505.6679 505.7875 505.9072 506.0268 506.1464 506.2660 506.3856 506.5051 506.6247 506.7442 506.8637 506.9832 507.1027 507.2222 507.3417 507.4611 507.5805 507.6999 507.8193 507.9387 508.0581 508.1775 508.2968 508.4161 508.5354 508.6547 508.7740 508.8933 509.0126 509.1318 509.2510 509.3702 509.4894 509.6086 509.7278 509.8469 509.9661 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240520T040627.2Z 8906.171148 135 1 50.34 2 87.18 65.35 114.06 279.62 0.00 1 0.00 1 0 22 3.642e-03 3.598e-03 7.158e-04 7.145e-04 2.166776e+04 5.440445e+01 1.438822e+03 -6.000000e+00 2.049241e+02 283.02 -2.00 20.00 -2.00 505.37 0.00e+00 2.051257e-03 1.994014e-05 1.374317e-04 -6.000000e+00 1.026887e-04 283.02 -2.00 20.00 -2.00 500.65 0.00e+00 1.369181e+00 1.419004e-02 1.233555e-01 -6.000000e+00 7.268206e-02 231.35 -2.00 3.53 -2.00 502.21 0.00e+00 13.950 0.051 489.00 513.00 1 4.5278e+00 1.0869e-03 2.3774e-02 -6.0000e+00 5.5778e-03 -1.6415e-03 2.7079e-04 3.4046e-03 -6.0000e+00 1.4361e-03 2.5093e-03 2.9073e-03 6.2826e-05 1.5394e-04 -6.0000e+00 3.8109e-04 4.2342e-02 -2.0830e-04 10 0 0 10 0 0 91.13 15.41 1.23 0.04234 0.06251 18 4 1 2 0 2796.480 15.00 15.41 22.07 21.88 21.27 34.2 1000.23 -81 -127 192 297 341 810 819 535 499 147 303 184 -98 -223 -218 219 63 137 126 63 199 252 308 342 335 184 -61 -203 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125 -41 -102 -318 -171 164 471 847 1720 429 122 38 276 257 87 561 373 174 169 298 -88 165 -133 -471 -93 175 -240 -9 162 104 16 454 176 182 163 276 429 225 150 -240 -68 -231 -257 SQ 20240520T040949.3Z 8906.173487 137 1 49.72 2 86.61 65.89 114.67 280.21 0.00 1 0.00 1 0 22 3.236e-03 3.191e-03 4.540e-04 4.532e-04 1.937575e+04 3.398455e+01 1.292185e+03 -6.000000e+00 1.820986e+02 283.02 -2.00 20.00 -2.00 505.36 0.00e+00 1.893635e-03 1.264067e-05 1.261067e-04 -6.000000e+00 9.125047e-05 283.02 -2.00 20.00 -2.00 500.62 0.00e+00 1.252610e+00 9.003386e-03 1.123170e-01 -6.000000e+00 6.458610e-02 231.35 -2.00 3.53 -2.00 502.19 0.00e+00 12.657 0.038 489.00 513.00 1 3.8151e+00 6.8972e-04 2.1261e-02 -6.0000e+00 4.9565e-03 -3.7974e-04 1.7215e-04 3.0695e-03 -6.0000e+00 1.2761e-03 6.2305e-03 2.9907e-03 4.0697e-05 1.3989e-04 -6.0000e+00 3.3862e-04 3.1282e-02 -1.4076e-04 10 0 0 10 0 0 4.88 15.41 1.08 0.03128 0.05203 41 9 1 2 0 1212.640 15.00 15.41 22.62 21.79 21.27 33.7 1001.17 -18 -32 234 327 428 584 606 464 446 295 111 121 -219 -158 -127 138 114 169 116 -57 193 360 260 247 298 80 -52 -231 -545 -325 134 4 -129 -12 -300 -259 -157 -83 -247 -100 -5 17 112 190 227 214 36 -156 -331 -512 -599 -495 -374 -251 -237 -280 -214 7 163 297 281 251 171 109 -8 16 -94 -197 -269 -437 -161 -80 -247 -279 -343 -402 -223 -226 -297 -334 -237 -107 -269 -30 -233 -319 -163 -34 162 261 223 185 59 126 568 439 86 -202 -790 -818 -577 -592 -705 -754 -743 -432 -81 -50 50 -62 -156 -48 272 539 750 1228 455 278 29 199 381 368 499 344 56 123 354 69 88 40 -284 -32 121 -150 -109 13 88 76 360 164 80 175 199 431 224 79 -139 -173 -282 -269 -17 -30 229 324 427 582 615 476 455 299 111 121 -219 -156 -125 136 115 171 118 -58 198 371 269 257 305 82 -53 -238 -549 -324 131 4 -129 -13 -312 -270 -162 -85 -250 -101 -5 17 116 195 236 222 37 -162 -337 -520 -593 -490 -369 -246 -239 -285 -218 7 167 303 288 258 177 112 -8 16 -95 -197 -271 -436 -160 -80 -244 -279 -344 -399 -221 -220 -287 -321 -228 -104 -263 -29 -230 -315 -161 -34 160 258 219 183 58 124 548 415 79 -184 -713 -734 -524 -547 -674 -730 -743 -427 -81 -49 49 -61 -155 -48 273 539 753 1221 463 286 29 201 381 362 489 339 56 123 354 69 88 40 -280 -31 117 -146 -108 12 89 77 367 167 83 181 207 447 231 81 -143 -175 -285 -274 SQ 20240520T041511.1Z 8906.177212 140 1 49.66 2 85.69 66.76 115.63 281.14 0.00 1 0.00 1 0 22 2.790e-03 2.763e-03 2.775e-04 2.771e-04 1.660219e+04 2.033635e+01 1.115301e+03 -6.000000e+00 1.570152e+02 283.02 -2.00 20.00 -2.00 505.34 0.00e+00 1.633435e-03 7.725039e-06 1.099458e-04 -6.000000e+00 7.868081e-05 283.02 -2.00 20.00 -2.00 500.59 0.00e+00 1.115908e+00 5.514050e-03 9.900192e-02 -6.000000e+00 5.568650e-02 231.35 -2.00 3.53 -2.00 502.16 0.00e+00 10.905 0.024 489.00 513.00 1 3.1017e+00 4.2263e-04 1.8135e-02 -6.0000e+00 4.2736e-03 6.9897e-04 1.0579e-04 2.6693e-03 -6.0000e+00 1.1002e-03 1.6580e-02 2.7241e-03 2.5412e-05 1.2298e-04 -6.0000e+00 2.9198e-04 3.5176e-02 -1.6062e-04 10 0 0 10 0 0 45.24 15.42 1.03 0.03518 0.05407 111 24 1 2 0 447.360 15.00 15.42 22.70 21.88 21.27 33.8 1002.18 14 -55 164 200 365 512 538 296 328 148 152 38 -171 -120 -29 171 142 187 30 -8 143 270 242 300 332 58 -67 -210 -408 -312 166 62 -72 12 -263 -308 -204 -62 -124 -40 -11 46 75 140 130 91 65 -75 -233 -503 -495 -355 -306 -182 -180 -337 -258 -91 165 279 318 290 63 151 57 36 -45 -187 -328 -394 -149 -112 -197 -257 -328 -333 -145 -92 -216 -338 -226 -73 -281 -120 -215 -296 -195 -43 132 249 201 150 123 2 330 434 98 -225 -595 -614 -413 -539 -601 -717 -765 -365 -109 2 99 -5 -162 -93 260 521 741 823 515 270 62 278 385 368 459 332 7 135 257 44 85 -12 -268 26 260 -61 -34 17 -67 20 315 144 117 144 183 245 108 -24 -140 -144 -205 -197 14 -53 159 200 368 517 552 302 339 152 153 37 -172 -119 -29 170 141 191 31 -9 148 280 248 308 343 60 -69 -218 -413 -313 163 62 -73 12 -274 -318 -212 -64 -127 -41 -11 47 78 145 135 95 67 -77 -238 -512 -490 -350 -301 -181 -182 -344 -263 -93 168 285 326 298 66 155 59 37 -45 -186 -329 -392 -147 -111 -195 -257 -329 -329 -143 -90 -208 -331 -218 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