File name: Pandora115s1_Rome-ISAC_20240606_L2Fit_fout2c1d20211213p1-8.txt File generation date: 20240606T231211.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 115 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora115_OF_v1d20210305.txt Instrument calibration file used: Pandora115s1_CF_v1d20211213.txt Level 1 file used: Pandora115s1_Rome-ISAC_20240606_L1_smca1c1d20211213p1-8.txt Full location name: CNR ISAC Rome Short location name: Rome-ISAC Country of location: Italy Location latitude [deg]: 41.8403 Location longitude [deg]: 12.6475 Location altitude [m]: 117 Local noon date: 20240606 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 245 386 Nominal wavelengths inside fitting window [nm]: 305.0951 305.2366 305.3781 305.5196 305.6611 305.8026 305.9440 306.0855 306.2269 306.3683 306.5097 306.6511 306.7925 306.9339 307.0752 307.2166 307.3579 307.4992 307.6405 307.7818 307.9231 308.0644 308.2056 308.3468 308.4881 308.6293 308.7705 308.9117 309.0528 309.1940 309.3351 309.4763 309.6174 309.7585 309.8996 310.0407 310.1818 310.3228 310.4639 310.6049 310.7459 310.8869 311.0279 311.1689 311.3099 311.4508 311.5918 311.7327 311.8736 312.0145 312.1554 312.2963 312.4372 312.5780 312.7189 312.8597 313.0005 313.1413 313.2821 313.4229 313.5637 313.7044 313.8452 313.9859 314.1266 314.2673 314.4080 314.5487 314.6894 314.8300 314.9707 315.1113 315.2519 315.3925 315.5331 315.6737 315.8143 315.9549 316.0954 316.2360 316.3765 316.5170 316.6575 316.7980 316.9385 317.0789 317.2194 317.3599 317.5003 317.6407 317.7811 317.9215 318.0619 318.2023 318.3427 318.4830 318.6234 318.7637 318.9040 319.0443 319.1846 319.3249 319.4652 319.6054 319.7457 319.8859 320.0262 320.1664 320.3066 320.4468 320.5870 320.7271 320.8673 321.0074 321.1476 321.2877 321.4278 321.5679 321.7080 321.8481 321.9882 322.1282 322.2683 322.4083 322.5483 322.6883 322.8283 322.9683 323.1083 323.2483 323.3882 323.5282 323.6681 323.8080 323.9479 324.0878 324.2277 324.3676 324.5075 324.6473 324.7871 324.9270 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240606T042052.4Z 8923.181161 54 1 49.30 2 83.31 65.39 78.13 65.90 0.00 1 0.00 1 0 25 6.062e-01 2.377e-02 2.973e-01 8.853e-03 1.034512e+00 5.078404e-03 1.063342e-02 -6.000000e+00 3.464301e-01 232.38 -2.00 3.53 -2.00 322.32 0.00e+00 4.282947e-03 2.273619e-03 1.457509e-03 -6.000000e+00 1.404592e-02 284.74 -2.00 20.00 -2.00 321.96 0.00e+00 7.810 0.009 302.00 328.00 3 8.1648e-02 1.6922e-02 9.5846e-02 -6.0000e+00 8.8375e-01 1.2872e+00 2.4462e-02 5.6431e-02 -6.0000e+00 9.6783e-01 -1.6707e+00 2.6500e-02 3.1915e-02 -6.0000e+00 5.5859e-01 6.6274e-01 1.2909e-02 1.1118e-02 -6.0000e+00 2.3049e-01 7.2035e-05 -5.9580e-04 2.2388e-04 1.2620e-04 -6.0000e+00 1.4943e-02 2.6716e-02 7.3327e-05 12 8 8 10 0 0 -13.94 15.46 0.52 0.02672 0.02224 47 10 4 8 0 1048.760 15.00 15.46 23.72 21.98 21.27 34.1 1004.94 -85098 -83674 6977 -85338 900000 -138087 900000 -189383 900000 -112307 144090 -104619 -76582 146772 -54708 900000 4451 331774 900000 71766 -24379 -35519 24855 47892 48550 -87760 69062 -90472 900000 -78059 900000 36666 900000 74411 46821 900000 -53777 88916 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682 1061 1155 -1037 -1239 -2962 -79 -1541 -1306 -4437 -280 -1508 -3322 -715 -1156 -792 -4565 -2158 -4562 663 -2996 -676 -2449 -453 -1455 941 1842 -1349 1608 -1579 264 -2634 -617 620 1745 2452 1520 4656 1962 3832 -922 3069 -519 3541 632 2977 1867 -2241 1051 -978 947 -2333 -2340 1811 -1387 -3159 SS 20240606T042658.3Z 8923.185397 57 1 49.52 2 82.27 66.35 77.12 66.76 0.00 1 0.00 1 0 25 6.053e-01 1.962e-02 2.809e-01 4.746e-03 9.505677e-01 2.578768e-03 9.987416e-03 -6.000000e+00 3.365302e-01 232.38 -2.00 3.53 -2.00 321.99 0.00e+00 4.533295e-03 1.110201e-03 1.201243e-03 -6.000000e+00 1.331408e-02 284.74 -2.00 20.00 -2.00 321.64 0.00e+00 6.917 0.006 302.00 328.00 3 6.4692e-02 8.3189e-03 8.6025e-02 -6.0000e+00 8.5296e-01 7.6409e-01 1.2690e-02 5.2331e-02 -6.0000e+00 9.2850e-01 -1.0389e+00 1.4710e-02 2.9501e-02 -6.0000e+00 5.4356e-01 4.2428e-01 7.0105e-03 1.0083e-02 -6.0000e+00 2.2761e-01 2.0044e-04 -6.4521e-04 1.1566e-04 1.0976e-04 -6.0000e+00 1.4431e-02 2.6434e-02 8.4666e-05 12 8 8 10 0 0 11.90 15.47 0.39 0.02643 0.02159 86 18 4 8 0 575.750 15.01 15.47 24.24 21.98 21.27 34.1 1008.06 -148451 -213334 -12645 -173848 56493 -235796 -143735 -227163 -170837 6849 -223609 -38147 -183785 38931 -65219 -18 -67880 -5131 136865 -4289 27749 -74203 45064 -94417 17952 -83035 96183 -43032 49583 -48948 -22261 -922 -42585 201309 -42981 78108 -42362 44089 7596 21599 20398 27266 36317 -1404 78920 11896 44907 21389 20488 13951 26873 49835 33405 41369 22021 32752 18917 43855 10109 24152 17118 25110 17212 25759 24814 8730 20421 1872 14657 5583 10849 10323 11250 8223 -4832 5266 -9321 9828 -2060 5246 -89 1446 -714 1 1586 466 1530 -566 3221 -2401 2259 -5219 -913 -4157 -3128 -2651 -2100 -1084 -1711 -79 -1064 -964 -3927 -2417 -2108 -2237 -461 -2365 -763 -1226 83 -653 615 -240 574 -202 -272 -180 -728 1158 624 2585 327 1704 837 2016 1429 1035 770 307 749 619 595 -410 14 30 56 -263 -912 111 -892 -911 -1749 -5295 -59 -2560 261 -5357 -1391 -5543 -2515 32 -5832 -212 -5412 180 -988 0 -1371 -66 633 -58 257 -1654 355 -2939 208 -2410 490 -836 390 -1246 -567 -23 -1852 932 -1651 904 -1862 1000 302 860 887 1161 1445 -81 2045 617 1746 1128 1176 955 1865 3067 2659 3274 2001 3046 1830 3450 1048 2135 1751 2754 2194 3414 3351 1366 2964 361 2947 1388 2693 2554 2560 1726 -1006 908 -1906 1898 -558 1607 -34 616 -331 1 809 253 852 -321 1698 -1248 1050 -2543 -447 -2450 -2212 -2043 -1903 -1111 -1824 -78 -930 -730 -2980 -1968 -1820 -2029 -443 -2598 -968 -1680 124 -1019 941 -355 812 -291 -414 -291 -1229 1859 940 3623 458 2479 1192 2708 2042 1641 1451 610 1613 1424 1479 -1041 38 82 152 -714 -2365 279 -2058 -1993 SS 20240606T044719.9Z 8923.199536 63 1 49.45 2 78.76 69.51 73.70 69.62 0.00 1 0.00 1 0 25 4.918e-01 8.646e-03 3.791e-02 1.193e-03 7.245811e-01 6.105422e-04 7.988983e-03 -6.000000e+00 2.733793e-01 232.38 -2.00 3.53 -2.00 320.86 0.00e+00 3.248386e-03 2.164525e-04 5.734033e-04 -6.000000e+00 1.081651e-02 284.75 -2.00 20.00 -2.00 320.54 0.00e+00 4.951 0.002 302.00 328.00 3 -1.1087e-01 1.7811e-03 6.2634e-02 -6.0000e+00 6.9290e-01 1.2984e-01 2.4197e-03 3.9035e-02 -6.0000e+00 7.5428e-01 -1.6878e-01 2.8160e-03 2.0914e-02 -6.0000e+00 4.4157e-01 6.5770e-02 1.4232e-03 6.6348e-03 -6.0000e+00 1.8490e-01 2.0233e-03 -1.4568e-04 2.8928e-05 6.0995e-05 -6.0000e+00 1.1725e-02 2.5747e-02 3.6624e-05 11 8 0 10 0 0 4.03 15.55 0.19 0.02575 0.02465 313 66 2 8 0 157.960 15.01 15.55 25.67 22.09 21.38 34.1 1016.27 -197012 -162932 -160508 -146606 -165613 -175960 -149693 -148227 -130411 -139157 -144482 -132758 -98121 -78646 -53429 -46558 -34834 -31864 -24002 -30541 -41546 -33747 -42581 -25817 -35134 -29213 -29718 -29481 -25093 -25648 -15161 -12293 -4698 -6572 -12652 -10353 -9478 -2510 1142 1828 1496 2289 3039 3964 3593 3749 1747 3730 2198 3922 4734 5188 5723 4151 4314 3294 2454 1896 293 2518 3495 3599 4334 4172 2443 2263 944 2222 1008 1194 1029 612 421 -238 -564 -1192 -1992 -692 -1361 -1504 -928 -1481 -1509 -1193 -639 -568 -241 662 942 702 148 130 -248 -257 -604 -240 618 -71 -566 -191 -100 -131 -361 -1257 -1430 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