File name: Pandora115s1_Rome-ISAC_20240828_L2Fit_fout2c1d20211213p1-8.txt File generation date: 20240828T231805.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 115 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora115_OF_v1d20210305.txt Instrument calibration file used: Pandora115s1_CF_v1d20211213.txt Level 1 file used: Pandora115s1_Rome-ISAC_20240828_L1_smca1c1d20211213p1-8.txt Full location name: CNR ISAC Rome Short location name: Rome-ISAC Country of location: Italy Location latitude [deg]: 41.8403 Location longitude [deg]: 12.6475 Location altitude [m]: 117 Local noon date: 20240828 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 245 386 Nominal wavelengths inside fitting window [nm]: 305.0951 305.2366 305.3781 305.5196 305.6611 305.8026 305.9440 306.0855 306.2269 306.3683 306.5097 306.6511 306.7925 306.9339 307.0752 307.2166 307.3579 307.4992 307.6405 307.7818 307.9231 308.0644 308.2056 308.3468 308.4881 308.6293 308.7705 308.9117 309.0528 309.1940 309.3351 309.4763 309.6174 309.7585 309.8996 310.0407 310.1818 310.3228 310.4639 310.6049 310.7459 310.8869 311.0279 311.1689 311.3099 311.4508 311.5918 311.7327 311.8736 312.0145 312.1554 312.2963 312.4372 312.5780 312.7189 312.8597 313.0005 313.1413 313.2821 313.4229 313.5637 313.7044 313.8452 313.9859 314.1266 314.2673 314.4080 314.5487 314.6894 314.8300 314.9707 315.1113 315.2519 315.3925 315.5331 315.6737 315.8143 315.9549 316.0954 316.2360 316.3765 316.5170 316.6575 316.7980 316.9385 317.0789 317.2194 317.3599 317.5003 317.6407 317.7811 317.9215 318.0619 318.2023 318.3427 318.4830 318.6234 318.7637 318.9040 319.0443 319.1846 319.3249 319.4652 319.6054 319.7457 319.8859 320.0262 320.1664 320.3066 320.4468 320.5870 320.7271 320.8673 321.0074 321.1476 321.2877 321.4278 321.5679 321.7080 321.8481 321.9882 322.1282 322.2683 322.4083 322.5483 322.6883 322.8283 322.9683 323.1083 323.2483 323.3882 323.5282 323.6681 323.8080 323.9479 324.0878 324.2277 324.3676 324.5075 324.6473 324.7871 324.9270 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240828T061312.1Z 9006.259168 225 1 49.46 2 72.04 93.28 14.21 159.59 0.00 1 0.00 1 0 25 4.886e-02 5.905e-03 6.110e-03 6.453e-04 4.467915e-01 3.175965e-04 5.240923e-03 -6.000000e+00 2.693856e-02 230.65 -2.00 3.53 -2.00 318.90 0.00e+00 8.611151e-04 6.500718e-05 1.653556e-04 -6.000000e+00 1.074309e-03 288.04 -2.00 20.00 -2.00 318.58 0.00e+00 3.198 0.001 302.00 328.00 3 8.8049e-01 8.6526e-04 3.9437e-02 -6.0000e+00 6.7985e-02 1.2959e-02 9.8376e-04 2.3335e-02 -6.0000e+00 7.4170e-02 -2.5607e-02 7.6233e-04 1.1626e-02 -6.0000e+00 4.3482e-02 6.2255e-03 4.1369e-04 3.3576e-03 -6.0000e+00 1.8232e-02 5.4930e-03 -1.1992e-04 1.6597e-05 3.0336e-05 -6.0000e+00 1.1653e-03 4.0666e-02 4.6207e-06 10 0 0 10 0 0 79.03 14.32 0.22 0.04067 0.03976 305 65 2 8 0 162.160 15.00 14.32 27.83 20.14 19.44 33.7 983.44 -7116 -21572 -5498 -21051 -17920 -16900 -21438 -13578 -15062 -7888 -19201 -5311 -11672 -1458 -4378 -1252 858 -2196 1953 -1568 1331 -2557 2244 -2953 -210 -1319 -690 -2149 -3137 933 -1309 2871 -1161 -706 -4359 -891 -1877 -1680 -641 -831 -330 -624 691 -298 826 -324 132 -159 103 1133 866 1414 745 1544 867 1172 284 748 439 895 1438 1076 1959 547 552 430 663 555 66 30 -68 -30 16 6 -634 35 -1315 -173 -986 -967 -1140 -1919 -1523 -1028 -459 -652 -295 417 628 353 414 823 814 519 32 411 783 80 -765 -257 65 -5 -126 -953 -1073 -813 -244 51 43 197 100 190 150 413 442 649 41 174 -644 -632 -446 691 -156 266 224 871 1424 471 126 -129 271 189 70 -31 -255 -33 39 -130 -706 -205 -93 114 -202 -772 -170 -678 -509 -489 -743 -509 -635 -316 -869 -242 -699 -96 -322 -99 71 -201 180 -158 130 -259 233 -354 -26 -172 -86 -255 -369 116 -193 464 -217 -125 -744 -156 -390 -396 -182 -268 -113 -225 252 -110 305 -122 49 -60 40 429 366 644 367 795 464 603 148 406 234 482 774 651 1309 364 372 270 408 366 48 24 -54 -24 13 5 -433 23 -837 -116 -732 -778 -1038 -1805 -1491 -1071 -484 -731 -341 479 697 364 415 803 783 515 34 471 1014 109 -1041 -323 77 -6 -148 -1183 -1409 -1058 -333 70 66 311 164 304 226 599 634 934 60 270 -1024 -1010 -688 1068 -235 380 322 1170 1950 692 196 -216 448 322 120 -57 -477 -64 75 -253 -1335 -381 -162 202 SS 20240828T062000.0Z 9006.263889 229 1 18.82 2 70.77 94.44 13.83 165.41 0.00 1 0.00 1 0 25 3.566e-02 6.062e-03 1.290e-02 1.783e-03 4.197344e-01 8.742542e-04 4.953946e-03 -6.000000e+00 1.965974e-02 230.65 -2.00 3.53 -2.00 318.59 0.00e+00 6.911282e-04 1.629096e-04 1.370847e-04 -6.000000e+00 7.840061e-04 288.04 -2.00 20.00 -2.00 318.26 0.00e+00 3.001 0.000 302.00 328.00 3 2.1380e+00 2.3643e-03 3.7009e-02 -6.0000e+00 4.9616e-02 2.2618e-02 2.6728e-03 2.1880e-02 -6.0000e+00 5.4129e-02 -2.5715e-02 1.9411e-03 1.0858e-02 -6.0000e+00 3.1733e-02 8.0971e-03 1.0463e-03 3.1158e-03 -6.0000e+00 1.3306e-02 1.9346e-03 -1.1169e-04 4.5488e-05 2.6736e-05 -6.0000e+00 8.5043e-04 4.0797e-02 1.3055e-05 12 1 1 12 1 1 80.17 14.33 0.23 0.04080 0.03996 30 17 4 8 0 607.020 15.01 14.33 28.38 20.14 19.44 33.7 985.57 -11668 -10921 -10255 -10277 -10120 -14874 -17665 -11896 -8265 -7518 -8710 -10361 -3785 -630 -3224 -596 1956 1 2720 1277 2066 -2295 1002 -2096 -2620 849 -2755 -3062 -2811 -154 -1316 1584 -1447 -2137 -3293 -2004 -1882 -525 274 -863 -426 -7 162 -457 456 665 -70 235 117 1442 444 1183 901 1820 918 1371 304 492 783 874 1469 849 2300 745 286 353 610 305 175 503 -358 -3 309 -422 -317 -15 -1370 -364 -1185 -1032 -934 -1852 -1385 -1172 -267 -547 -509 290 435 171 195 490 697 317 123 588 1083 -82 -1054 -422 222 -77 -288 -958 -1137 -830 -91 207 182 253 232 378 324 340 473 449 -164 212 -703 -691 -168 503 111 297 400 856 1076 535 167 -80 346 198 -46 -71 -293 -66 22 21 -765 -99 -238 23 -487 -490 -460 -411 -366 -579 -808 -600 -444 -408 -479 -663 -277 -54 -305 -60 204 0 318 159 253 -293 133 -314 -421 135 -438 -456 -408 -24 -236 313 -325 -461 -665 -424 -466 -145 91 -330 -159 -3 64 -182 183 266 -28 94 48 622 214 613 466 981 514 792 179 280 434 491 888 538 1593 550 200 227 411 205 138 415 -313 -3 258 -330 -235 -10 -945 -246 -945 -889 -852 -1854 -1360 -1227 -299 -617 -594 337 488 189 197 477 664 330 138 701 1380 -110 -1417 -549 271 -86 -334 -1175 -1476 -1122 -122 295 273 392 372 589 497 501 655 623 -241 318 -1085 -1075 -264 758 162 432 556 1168 1496 792 261 -128 569 335 -78 -124 -544 -125 41 39 -1438 -176 -415 39 SS 20240828T062624.6Z 9006.268341 232 1 49.44 2 69.58 95.55 13.59 171.12 0.00 1 0.00 1 0 25 2.762e-02 5.868e-03 2.778e-03 4.804e-04 3.969536e-01 2.354270e-04 4.714141e-03 -6.000000e+00 1.522853e-02 230.65 -2.00 3.53 -2.00 318.26 0.00e+00 6.136354e-04 3.958122e-05 1.149284e-04 -6.000000e+00 6.073340e-04 288.04 -2.00 20.00 -2.00 317.92 0.00e+00 2.837 0.000 302.00 328.00 3 7.5137e-01 6.3419e-04 3.4994e-02 -6.0000e+00 3.8432e-02 8.1535e-03 7.1357e-04 2.0693e-02 -6.0000e+00 4.1929e-02 -1.8909e-02 4.9068e-04 1.0237e-02 -6.0000e+00 2.4581e-02 4.7299e-03 2.6131e-04 2.9159e-03 -6.0000e+00 1.0307e-02 9.3851e-03 -8.1446e-05 1.2270e-05 2.5957e-05 -6.0000e+00 6.5877e-04 4.0830e-02 4.7240e-06 10 0 0 10 0 0 99.75 14.35 0.19 0.04083 0.04022 357 76 2 8 0 138.480 15.00 14.35 28.56 20.14 19.44 33.6 986.37 -8240 -6973 -7284 -9621 -11841 -12957 -8449 -10022 -5178 -8631 -8144 -5783 -3305 -1616 -925 -491 397 1035 1452 1200 109 857 943 -423 -987 -873 -890 -1852 -642 601 363 931 259 -1928 -2560 -1384 -1426 -1221 -411 -317 -629 -24 54 287 181 -12 -187 -47 -131 820 1081 829 1065 1156 1096 886 647 524 523 970 1262 1262 1638 612 -85 606 242 658 -72 110 20 -366 133 -288 -202 -42 -706 -247 -654 -1209 -1141 -1976 -1639 -999 -590 -510 -436 486 384 355 419 839 857 502 194 316 930 -89 -704 -363 127 -57 -216 -810 -1074 -826 -380 131 -49 250 -26 232 120 368 483 612 197 91 -429 -620 -259 571 -29 327 199 928 1378 668 60 -93 204 309 108 53 -290 -102 58 -160 -719 -381 -113 19 -438 -395 -415 -499 -568 -645 -458 -645 -350 -612 -573 -452 -278 -161 -107 -62 52 145 213 185 17 131 155 -77 -192 -174 -170 -334 -111 111 77 203 63 -453 -611 -317 -383 -404 -151 -131 -278 -11 24 134 80 -5 -88 -22 -62 383 557 462 591 673 656 551 405 319 311 584 819 855 1222 482 -63 412 161 465 -57 96 17 -320 118 -238 -158 -29 -506 -174 -510 -1090 -1093 -1962 -1690 -1040 -659 -576 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