File name: Pandora115s1_Rome-ISAC_20240912_L2Fit_fout2c1d20211213p1-8.txt File generation date: 20240912T231103.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 115 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora115_OF_v1d20210305.txt Instrument calibration file used: Pandora115s1_CF_v1d20211213.txt Level 1 file used: Pandora115s1_Rome-ISAC_20240912_L1_smca1c1d20211213p1-8.txt Full location name: CNR ISAC Rome Short location name: Rome-ISAC Country of location: Italy Location latitude [deg]: 41.8403 Location longitude [deg]: 12.6475 Location altitude [m]: 117 Local noon date: 20240912 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 245 386 Nominal wavelengths inside fitting window [nm]: 305.0951 305.2366 305.3781 305.5196 305.6611 305.8026 305.9440 306.0855 306.2269 306.3683 306.5097 306.6511 306.7925 306.9339 307.0752 307.2166 307.3579 307.4992 307.6405 307.7818 307.9231 308.0644 308.2056 308.3468 308.4881 308.6293 308.7705 308.9117 309.0528 309.1940 309.3351 309.4763 309.6174 309.7585 309.8996 310.0407 310.1818 310.3228 310.4639 310.6049 310.7459 310.8869 311.0279 311.1689 311.3099 311.4508 311.5918 311.7327 311.8736 312.0145 312.1554 312.2963 312.4372 312.5780 312.7189 312.8597 313.0005 313.1413 313.2821 313.4229 313.5637 313.7044 313.8452 313.9859 314.1266 314.2673 314.4080 314.5487 314.6894 314.8300 314.9707 315.1113 315.2519 315.3925 315.5331 315.6737 315.8143 315.9549 316.0954 316.2360 316.3765 316.5170 316.6575 316.7980 316.9385 317.0789 317.2194 317.3599 317.5003 317.6407 317.7811 317.9215 318.0619 318.2023 318.3427 318.4830 318.6234 318.7637 318.9040 319.0443 319.1846 319.3249 319.4652 319.6054 319.7457 319.8859 320.0262 320.1664 320.3066 320.4468 320.5870 320.7271 320.8673 321.0074 321.1476 321.2877 321.4278 321.5679 321.7080 321.8481 321.9882 322.1282 322.2683 322.4083 322.5483 322.6883 322.8283 322.9683 323.1083 323.2483 323.3882 323.5282 323.6681 323.8080 323.9479 324.0878 324.2277 324.3676 324.5075 324.6473 324.7871 324.9270 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240912T061657.8Z 9021.261780 75 1 49.74 2 74.11 99.11 166.09 23.56 0.00 1 0.00 1 0 25 2.157e-01 2.373e-02 1.353e-01 1.036e-02 4.889487e-01 5.248271e-03 5.767796e-03 -6.000000e+00 1.199795e-01 229.36 -2.00 3.53 -2.00 319.99 0.00e+00 4.540264e-03 1.446153e-03 2.366528e-04 -6.000000e+00 5.323190e-03 286.85 -2.00 20.00 -2.00 319.67 0.00e+00 3.589 0.001 302.00 328.00 3 4.8852e+00 1.4606e-02 4.3889e-02 -6.0000e+00 3.0257e-01 1.9649e-01 1.7308e-02 2.5800e-02 -6.0000e+00 3.3115e-01 -1.1903e-01 1.5866e-02 1.3169e-02 -6.0000e+00 1.9209e-01 4.5101e-02 8.4978e-03 3.9433e-03 -6.0000e+00 8.0705e-02 5.9703e-05 -1.2922e-03 2.7843e-04 3.7475e-05 -6.0000e+00 5.3682e-03 4.2795e-02 -8.9790e-05 12 8 8 10 0 0 99.98 14.27 0.60 0.04280 0.03309 26 6 2 8 0 1912.650 15.00 14.27 27.52 20.14 19.33 33.2 976.27 -53850 -22481 10193 900000 900000 -24096 900000 -124573 900000 -107518 900000 -17155 29142 21864 -50591 63088 61506 -19375 84694 2500 -34605 20810 16162 -13973 -5560 -873 5498 -2795 23898 -26705 37705 27899 8575 -7908 29505 33894 -3165 7944 14510 7054 32 7036 1584 4234 1072 393 -9156 14433 7036 -4523 9116 1655 3126 -1673 4165 4693 8843 14721 1015 5713 6657 2292 2413 4001 5373 4291 -1263 -150 -1101 5646 -17284 -2291 5047 -11764 -4995 -3279 -787 3417 -3004 -594 -1043 -930 -1491 -2236 1871 2157 884 1987 2051 -909 -676 -1088 312 722 634 -1469 2500 537 -1090 -951 -779 1061 -2031 -2564 -3983 254 231 1068 -548 2155 743 1245 2610 823 -440 -1276 1196 450 -2150 -5 -1699 1403 -265 1227 491 2006 -440 785 -1220 569 -659 1076 415 51 -828 -1152 -136 -617 -873 1888 -322 588 -1453 -493 167 900000 900000 -448 900000 -7451 900000 -5968 900000 -482 664 659 -3596 1712 1814 -1317 2274 151 -2939 1035 885 -1088 -419 -64 371 -195 1296 -2597 2343 2172 888 -919 2225 2573 -394 1080 2215 1297 7 1443 353 925 246 92 -2355 3026 1613 -1242 2438 514 1021 -600 1448 1672 3028 4634 355 1945 2430 976 1143 1972 2496 1886 -577 -72 -620 3309 -13076 -1509 2974 -7532 -2694 -1584 -360 1608 -1752 -389 -769 -741 -1242 -1988 1710 2069 887 1975 1981 -843 -578 -870 243 611 607 -1609 2963 703 -1447 -1185 -874 1078 -2154 -2976 -4914 314 299 1459 -825 3426 1236 2033 4014 1202 -618 -1807 1731 696 -3565 -8 -2723 2126 -395 1738 674 2579 -591 1152 -1998 976 -1177 1940 786 102 -1750 -2468 -294 -1339 -1839 3707 -612 1083 SS 20240912T062827.0Z 9021.269757 77 1 49.49 2 72.01 101.15 165.14 32.37 0.00 1 0.00 1 0 17 4.573e-02 6.080e-03 3.427e-03 4.218e-04 4.401266e-01 2.061406e-04 5.203955e-03 -6.000000e+00 2.510091e-02 229.36 -2.00 3.53 -2.00 318.71 0.00e+00 7.210392e-04 4.013149e-05 1.516740e-04 -6.000000e+00 1.005496e-03 286.85 -2.00 20.00 -2.00 318.39 0.00e+00 3.194 0.001 302.00 328.00 3 6.4304e-02 5.5772e-04 3.9069e-02 -6.0000e+00 6.3154e-02 3.2433e-02 6.3220e-04 2.2862e-02 -6.0000e+00 6.8961e-02 -2.4561e-02 4.7372e-04 1.1401e-02 -6.0000e+00 4.0469e-02 5.8644e-03 2.5737e-04 3.2960e-03 -6.0000e+00 1.7022e-02 1.2460e-02 -2.0824e-04 1.0788e-05 2.9402e-05 -6.0000e+00 1.0903e-03 3.9156e-02 2.8629e-05 10 0 0 10 0 0 99.05 14.28 0.19 0.03916 0.03759 609 129 2 8 0 81.250 15.01 14.28 28.07 20.14 19.33 33.8 982.91 -16397 -12062 -13611 -15732 -18510 -19982 -15163 -17232 -9841 -14114 -12553 -10010 -6375 -4575 -1462 -2065 -824 -680 1064 734 -1055 -30 292 -727 -1280 -1060 -1013 -2233 -1580 -117 676 1144 577 -2123 -2834 -1629 -1556 -1566 -824 -148 -606 -73 107 652 325 324 -116 66 143 1254 1191 970 1383 1292 1188 781 783 485 542 955 1191 1281 1776 698 -82 526 340 686 -199 100 -56 -235 182 -299 -251 -102 -666 -427 -749 -1166 -1110 -1897 -1692 -1045 -619 -628 -513 522 472 359 285 873 868 520 180 287 1003 -8 -661 -334 252 20 -179 -800 -1151 -833 -373 187 -45 264 -54 209 124 378 563 679 246 54 -587 -698 -300 663 -69 228 249 1014 1393 629 -41 -94 261 350 17 64 -330 -118 30 -151 -713 -340 4 110 -601 -461 -535 -565 -619 -696 -575 -781 -459 -703 -618 -553 -418 -359 -120 -188 -79 -70 113 83 -120 -3 35 -97 -184 -157 -144 -302 -208 -16 110 211 119 -430 -535 -322 -360 -411 -261 -53 -215 -27 40 245 124 124 -45 25 56 523 553 489 693 682 648 444 447 270 294 523 703 790 1212 508 -57 336 213 458 -147 83 -46 -194 152 -233 -185 -68 -425 -289 -559 -1011 -1023 -1813 -1685 -1104 -665 -716 -605 610 535 398 290 860 839 519 195 333 1309 -10 -911 -427 300 23 -212 -1000 -1526 -1095 -514 261 -66 422 -85 323 189 554 810 934 357 80 -938 -1124 -467 986 -105 328 359 1361 1904 923 -63 -151 431 593 29 114 -619 -226 56 -285 -1352 -608 7 188 SS 20240912T065659.3Z 9021.289576 94 1 49.86 2 66.85 106.39 161.81 49.75 0.00 1 0.00 1 0 17 1.824e-02 6.112e-03 5.809e-03 1.340e-03 3.527443e-01 6.551307e-04 4.246014e-03 -6.000000e+00 1.001406e-02 229.35 -2.00 3.53 -2.00 317.80 0.00e+00 5.560766e-04 9.773870e-05 8.677030e-05 -6.000000e+00 4.011359e-04 286.85 -2.00 20.00 -2.00 317.47 0.00e+00 2.524 0.000 302.00 328.00 3 3.1154e+00 1.7465e-03 3.1044e-02 -6.0000e+00 2.5195e-02 3.4620e-02 1.9603e-03 1.8322e-02 -6.0000e+00 2.7512e-02 -1.1546e-02 1.2719e-03 9.0668e-03 -6.0000e+00 1.6145e-02 1.0349e-03 6.6422e-04 2.5805e-03 -6.0000e+00 6.7911e-03 1.2432e-03 -1.7240e-04 3.4591e-05 2.3722e-05 -6.0000e+00 4.3497e-04 3.8642e-02 2.0852e-05 10 0 0 10 0 0 99.97 14.32 0.31 0.03864 0.03735 45 10 2 8 0 1107.990 15.00 14.32 29.00 20.14 19.33 33.4 985.32 -4857 -6860 -6293 -3865 -6445 -5804 -3439 -6430 -3477 -4460 -4665 -5917 -3201 -1795 -1042 1168 1698 -1130 2976 -307 243 881 2596 -550 -635 1283 -368 -156 -1803 1128 161 1152 -1000 -2022 -2546 -141 -668 -1868 -385 -917 -56 -325 -85 80 280 173 -605 107 -272 1354 462 955 733 1051 1200 834 1084 683 394 965 1402 1312 1966 665 -11 110 358 397 -238 280 -1029 -70 37 -461 -744 -69 -1027 26 -842 -1405 -847 -1908 -1451 -1060 -509 -669 -301 503 459 47 -26 803 839 457 128 370 996 253 -720 -294 368 -108 -101 -814 -1099 -812 -211 320 -82 254 106 323 114 484 295 595 -28 170 -412 -652 -285 682 -186 362 168 923 1190 830 251 -263 51 380 125 59 -304 -247 4 -115 -740 -271 -77 80 -369 -518 -519 -276 -424 -385 -253 -566 -327 -428 -441 -634 -363 -239 -160 190 287 -208 550 -61 48 171 528 -125 -154 312 -87 -34 -386 249 41 295 -286 -555 -706 -40 -205 -712 -161 -435 -28 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