File name: Pandora115s1_Rome-ISAC_20241009_L2Fit_fout2c1d20211213p1-8.txt File generation date: 20241009T225950.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 115 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora115_OF_v1d20210305.txt Instrument calibration file used: Pandora115s1_CF_v1d20211213.txt Level 1 file used: Pandora115s1_Rome-ISAC_20241009_L1_smca1c1d20211213p1-8.txt Full location name: CNR ISAC Rome Short location name: Rome-ISAC Country of location: Italy Location latitude [deg]: 41.8403 Location longitude [deg]: 12.6475 Location altitude [m]: 117 Local noon date: 20241009 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 245 386 Nominal wavelengths inside fitting window [nm]: 305.0951 305.2366 305.3781 305.5196 305.6611 305.8026 305.9440 306.0855 306.2269 306.3683 306.5097 306.6511 306.7925 306.9339 307.0752 307.2166 307.3579 307.4992 307.6405 307.7818 307.9231 308.0644 308.2056 308.3468 308.4881 308.6293 308.7705 308.9117 309.0528 309.1940 309.3351 309.4763 309.6174 309.7585 309.8996 310.0407 310.1818 310.3228 310.4639 310.6049 310.7459 310.8869 311.0279 311.1689 311.3099 311.4508 311.5918 311.7327 311.8736 312.0145 312.1554 312.2963 312.4372 312.5780 312.7189 312.8597 313.0005 313.1413 313.2821 313.4229 313.5637 313.7044 313.8452 313.9859 314.1266 314.2673 314.4080 314.5487 314.6894 314.8300 314.9707 315.1113 315.2519 315.3925 315.5331 315.6737 315.8143 315.9549 316.0954 316.2360 316.3765 316.5170 316.6575 316.7980 316.9385 317.0789 317.2194 317.3599 317.5003 317.6407 317.7811 317.9215 318.0619 318.2023 318.3427 318.4830 318.6234 318.7637 318.9040 319.0443 319.1846 319.3249 319.4652 319.6054 319.7457 319.8859 320.0262 320.1664 320.3066 320.4468 320.5870 320.7271 320.8673 321.0074 321.1476 321.2877 321.4278 321.5679 321.7080 321.8481 321.9882 322.1282 322.2683 322.4083 322.5483 322.6883 322.8283 322.9683 323.1083 323.2483 323.3882 323.5282 323.6681 323.8080 323.9479 324.0878 324.2277 324.3676 324.5075 324.6473 324.7871 324.9270 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241009T062645.6Z 9048.268584 66 1 43.09 2 77.97 110.22 145.95 80.52 0.00 1 0.00 1 0 25 3.139e-01 1.289e-02 1.229e-01 3.978e-03 5.730590e-01 1.972347e-03 6.607725e-03 -6.000000e+00 1.714631e-01 226.36 -2.00 3.53 -2.00 320.20 0.00e+00 2.070869e-03 5.939769e-04 3.315741e-04 -6.000000e+00 6.957468e-03 283.63 -2.00 20.00 -2.00 319.88 0.00e+00 4.652 0.002 302.00 328.00 3 2.6346e+00 5.5362e-03 5.4535e-02 -6.0000e+00 4.2828e-01 1.2726e-01 6.7658e-03 2.9779e-02 -6.0000e+00 4.6900e-01 -1.1844e-01 6.8352e-03 1.5506e-02 -6.0000e+00 2.7486e-01 4.3486e-02 3.6266e-03 4.7894e-03 -6.0000e+00 1.1597e-01 2.0555e-04 -6.4366e-04 1.0149e-04 4.4448e-05 -6.0000e+00 7.5148e-03 4.1149e-02 1.1931e-05 12 8 8 10 0 0 94.22 14.17 0.25 0.04115 0.03631 17 4 2 8 0 2534.360 15.00 14.17 23.33 20.14 19.33 33.7 960.44 -96080 -323 -121436 234643 -41539 900000 -90947 -110404 -13197 -102805 -4688 -83784 5330 -43291 6132 -29560 7538 -53427 60646 6192 -530 -1715 -16460 -12163 -23680 21794 -23846 -2362 -9184 -9339 -7761 14985 -4109 -9522 7200 2947 7477 -10369 12037 -1236 6305 2685 5429 2863 3002 5916 -4761 10416 -2943 4416 829 5283 1025 -149 3494 3289 5457 2989 3280 -889 5699 265 3849 2045 443 4814 1721 1714 -1970 3640 -7758 1012 759 -3296 -3288 -1780 -301 138 1155 -1584 -156 -2695 -198 -1650 437 -1004 -369 1459 428 1394 -1031 1047 -921 886 -242 489 820 -60 -474 -345 551 -1705 -178 -2491 -1606 -1439 270 179 -889 1056 291 912 88 578 93 818 255 180 -1347 -316 156 608 528 339 580 776 1821 219 -540 23 342 1250 279 -379 -914 -261 -208 -327 -972 339 177 290 -1771 -3 -3247 910 -427 900000 -1763 -2993 -155 -2959 -54 -2478 85 -1390 149 -1148 224 -3097 1250 225 -20 -67 -801 -625 -1450 895 -1474 -114 -475 -548 -539 976 -360 -852 512 230 653 -1319 1503 -199 1017 471 957 519 555 1083 -978 1923 -637 970 211 1404 305 -47 1114 1090 1783 970 1034 -294 1919 105 1655 951 203 2024 746 796 -1086 2106 -5144 625 451 -1893 -1708 -843 -139 68 659 -1054 -114 -2177 -163 -1446 399 -968 -364 1421 409 1255 -889 845 -757 782 -241 537 993 -78 -623 -432 628 -1837 -191 -2931 -1955 -1809 350 245 -1329 1671 479 1488 140 874 136 1194 387 286 -2242 -521 249 945 804 504 836 1073 2569 341 -916 41 628 2339 547 -780 -1949 -559 -451 -711 -2068 687 345 554 SS 20241009T063231.5Z 9048.272586 68 1 44.34 2 76.96 111.27 144.95 81.68 0.00 1 0.00 1 0 25 1.384e-01 7.511e-03 6.541e-02 2.741e-03 5.364890e-01 1.351925e-03 6.205414e-03 -6.000000e+00 7.538653e-02 226.36 -2.00 3.53 -2.00 319.97 0.00e+00 1.412018e-03 3.837064e-04 2.886476e-04 -6.000000e+00 3.098756e-03 283.63 -2.00 20.00 -2.00 319.66 0.00e+00 4.319 0.001 302.00 328.00 3 2.3205e+00 3.7602e-03 5.0730e-02 -6.0000e+00 1.8820e-01 5.9887e-02 4.5306e-03 2.7789e-02 -6.0000e+00 2.0607e-01 -3.9186e-02 4.4696e-03 1.4388e-02 -6.0000e+00 1.2093e-01 9.7523e-03 2.3951e-03 4.4096e-03 -6.0000e+00 5.1142e-02 4.0657e-04 -4.4746e-04 7.0344e-05 3.9849e-05 -6.0000e+00 3.3025e-03 4.1225e-02 1.7113e-05 11 9 0 11 8 0 98.19 14.17 0.14 0.04122 0.03786 37 8 4 8 0 1198.190 15.00 14.17 23.55 20.14 19.33 33.7 961.58 -16707 -34196 -15192 -28161 900000 -66345 4070 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-1531 -729 -116 -547 154 -567 -500 -472 -607 -1451 -537 -334 -8 -273 548 817 228 317 472 869 59 181 350 997 158 -1159 -356 -102 108 -445 -1344 -2447 -1001 -576 347 -219 389 630 101 694 828 974 820 569 -222 -1229 -887 -670 821 114 1046 219 1595 1192 634 -505 -342 268 1177 394 -676 -883 -926 251 -181 -1466 -7 200 745 SS 20241009T064344.6Z 9048.280378 74 1 49.67 2 75.03 113.34 142.98 83.83 0.00 1 0.00 1 0 25 7.877e-02 6.436e-03 1.221e-02 1.020e-03 4.777819e-01 4.956040e-04 5.608191e-03 -6.000000e+00 4.275259e-02 226.36 -2.00 3.53 -2.00 319.26 0.00e+00 9.685469e-04 1.145215e-04 1.995224e-04 -6.000000e+00 1.731850e-03 283.63 -2.00 20.00 -2.00 318.94 0.00e+00 3.796 0.001 302.00 328.00 3 1.1805e+00 1.3488e-03 4.4722e-02 -6.0000e+00 1.0682e-01 4.5921e-02 1.5583e-03 2.4561e-02 -6.0000e+00 1.1692e-01 -3.1719e-02 1.3128e-03 1.2445e-02 -6.0000e+00 6.8769e-02 8.0492e-03 7.1673e-04 3.6986e-03 -6.0000e+00 2.9108e-02 2.2316e-03 -3.4218e-04 2.6050e-05 3.3089e-05 -6.0000e+00 1.8771e-03 4.0772e-02 2.9636e-05 11 8 0 10 0 0 98.65 14.18 0.22 0.04077 0.03820 143 30 4 8 0 347.280 15.01 14.18 24.02 20.14 19.33 33.7 964.36 -18187 -33433 -18290 -32595 -23514 -39128 -25179 -30522 -14799 -20324 -24178 -12434 -15471 -4311 -7640 -1068 -1416 -1945 1765 -1352 -1952 -4214 1401 -4175 -2216 -2810 -1827 -4660 -1030 -443 -434 926 -1069 -2291 -4592 422 -3500 -1001 -907 69 -813 -41 318 -329 1361 -277 498 118 272 1245 1506 1169 1275 1738 1366 1114 525 1040 381 1327 1447 1392 1909 843 281 896 939 700 -68 132 -392 -198 400 -492 -437 -298 -1440 103 -950 -930 -1230 -1823 -1509 -995 -430 -594 -454 398 561 161 365 840 908 377 176 388 991 95 -831 -243 251 241 -304 -827 -1321 -1028 -164 186 -124 2 37 271 220 459 480 754 122 121 -651 -667 -312 848 -230 225 208 1150 1415 562 -139 -219 388 311 -64 -62 -350 -162 81 -100 -807 -329 98 281 -405 -951 -455 -840 -503 -1008 -646 -968 -446 -665 -834 -445 -712 -219 -438 -64 -91 -137 126 -105 -151 -335 114 -394 -220 -290 -180 -446 -94 -44 -51 124 -163 -339 -645 60 -604 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