File name: Pandora115s1_Rome-ISAC_20250127_L2Fit_fwvt1c5d20230305p1-8.txt File generation date: 20250128T013829.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 115 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora115_OF_v1d20210305.txt Instrument calibration file used: Pandora115s1_CF_v5d20230305.txt Level 1 file used: Pandora115s1_Rome-ISAC_20250127_L1_smca1c5d20230305p1-8.txt Full location name: CNR ISAC Rome Short location name: Rome-ISAC Country of location: Italy Location latitude [deg]: 41.8403 Location longitude [deg]: 12.6475 Location altitude [m]: 117 Local noon date: 20250127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1661 1809 Nominal wavelengths inside fitting window [nm]: 492.0749 492.1964 492.3179 492.4394 492.5609 492.6824 492.8039 492.9253 493.0468 493.1682 493.2896 493.4110 493.5324 493.6538 493.7752 493.8965 494.0179 494.1392 494.2606 494.3819 494.5032 494.6245 494.7457 494.8670 494.9883 495.1095 495.2307 495.3519 495.4732 495.5943 495.7155 495.8367 495.9579 496.0790 496.2002 496.3213 496.4424 496.5635 496.6846 496.8057 496.9267 497.0478 497.1688 497.2899 497.4109 497.5319 497.6529 497.7739 497.8949 498.0159 498.1368 498.2578 498.3787 498.4996 498.6205 498.7414 498.8623 498.9832 499.1041 499.2249 499.3458 499.4666 499.5874 499.7083 499.8291 499.9499 500.0707 500.1914 500.3122 500.4329 500.5537 500.6744 500.7951 500.9158 501.0366 501.1572 501.2779 501.3986 501.5193 501.6399 501.7605 501.8812 502.0018 502.1224 502.2430 502.3636 502.4842 502.6047 502.7253 502.8458 502.9664 503.0869 503.2074 503.3280 503.4485 503.5689 503.6894 503.8099 503.9304 504.0508 504.1713 504.2917 504.4121 504.5325 504.6529 504.7733 504.8937 505.0141 505.1345 505.2548 505.3752 505.4955 505.6159 505.7362 505.8565 505.9768 506.0971 506.2174 506.3377 506.4579 506.5782 506.6985 506.8187 506.9389 507.0592 507.1794 507.2996 507.4198 507.5400 507.6602 507.7803 507.9005 508.0207 508.1408 508.2610 508.3811 508.5012 508.6213 508.7415 508.8616 508.9817 509.1017 509.2218 509.3419 509.4620 509.5820 509.7021 509.8221 509.9421 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250127T072808.7Z 9158.311212 82 1 43.78 2 80.84 124.94 75.95 153.33 0.00 1 0.00 1 0 15 3.188e-03 3.187e-03 5.064e-04 5.058e-04 3.759531e+03 3.061601e+01 2.794610e+02 -6.000000e+00 1.732637e+02 273.82 -2.00 20.00 -2.00 505.29 0.00e+00 8.966299e-04 1.373282e-05 4.842187e-05 -6.000000e+00 8.816328e-05 273.82 -2.00 20.00 -2.00 500.54 0.00e+00 6.776571e-01 9.952468e-03 2.275440e-02 -6.000000e+00 6.379987e-02 224.06 -2.00 3.53 -2.00 502.12 0.00e+00 5.968 0.004 489.00 513.00 1 5.2813e+00 7.6168e-04 8.7372e-03 -6.0000e+00 4.8798e-03 -1.7066e-03 1.9344e-04 7.5448e-04 -6.0000e+00 1.2654e-03 4.0325e-03 1.4967e-02 5.0948e-05 4.4291e-05 -6.0000e+00 3.3469e-04 7.1205e-05 -2.0405e-05 10 0 0 10 0 0 92.31 14.51 1.27 0.00007 0.10389 43 10 1 2 0 1018.130 15.00 14.51 16.56 21.27 20.67 34.2 966.27 -477 -587 -555 -387 -95 198 90 343 294 427 367 205 66 -29 66 -182 -234 -334 -205 114 248 305 328 285 91 96 188 -6 201 387 58 -401 -353 -552 -288 51 250 170 171 69 19 128 112 171 191 186 105 199 -63 9 117 -177 -218 -403 -543 -471 -112 113 151 347 161 84 68 124 229 70 -23 -127 -223 -35 -6 -196 -217 -435 -321 34 181 -6 -172 -85 -82 -245 -36 -83 -150 -120 -7 92 184 198 181 56 -129 -87 69 -93 -201 -364 -209 71 85 39 -414 -632 -555 -202 -7 126 238 64 190 304 370 470 698 366 27 -169 -41 101 148 408 234 53 94 235 -1 38 -300 -802 -399 -17 182 446 604 452 264 391 279 245 300 139 -67 -672 -1101 -1249 -694 180 789 -457 -580 -553 -395 -97 205 92 358 304 435 368 208 66 -29 66 -181 -239 -342 -212 118 257 316 341 298 95 100 193 -6 201 379 57 -407 -362 -568 -297 52 258 173 174 71 19 132 115 177 197 192 106 202 -63 9 113 -170 -212 -404 -549 -474 -114 114 153 350 164 86 69 125 232 70 -23 -123 -221 -34 -6 -191 -215 -432 -316 34 176 -6 -166 -82 -81 -237 -35 -82 -149 -120 -7 91 183 195 181 56 -129 -86 68 -90 -193 -344 -195 66 82 38 -412 -638 -557 -200 -7 124 235 64 190 306 375 478 713 368 27 -172 -41 99 147 406 229 52 93 231 -1 37 -294 -796 -389 -16 174 432 597 446 265 389 280 247 304 142 -69 -685 -1106 -1229 -682 175 773 SQ 20250127T074229.0Z 9158.321169 89 1 8.53 2 78.69 127.62 74.84 156.27 0.00 1 0.00 1 0 15 3.077e-03 3.067e-03 1.275e-04 1.274e-04 3.172018e+03 7.606988e+00 2.320701e+02 -6.000000e+00 1.672542e+02 273.82 -2.00 20.00 -2.00 505.28 0.00e+00 8.436205e-04 3.453821e-06 4.668611e-05 -6.000000e+00 8.510199e-05 273.82 -2.00 20.00 -2.00 500.51 0.00e+00 5.075511e-01 2.508901e-03 2.059263e-02 -6.000000e+00 6.156763e-02 224.06 -2.00 3.53 -2.00 502.09 0.00e+00 4.927 0.002 489.00 513.00 1 1.0490e+00 1.9201e-04 7.2593e-03 -6.0000e+00 4.7094e-03 5.5534e-03 4.8897e-05 6.4385e-04 -6.0000e+00 1.2207e-03 3.2603e-01 1.4301e-02 1.2856e-05 3.7067e-05 -6.0000e+00 3.2301e-04 -4.4915e-04 6.6123e-06 12 1 1 12 1 1 15.20 14.50 1.32 -0.00045 0.09875 482 118 2 2 0 17.440 15.00 14.50 16.88 21.27 20.67 34.2 968.42 -409 -590 -504 -358 -26 62 75 295 337 417 319 129 97 83 62 -134 -261 -312 -255 86 259 202 213 222 101 112 184 130 274 497 95 -298 -450 -567 -275 79 263 166 169 120 39 44 77 81 158 171 151 143 -17 14 71 -101 -155 -373 -542 -433 -179 118 220 248 150 14 73 49 133 34 10 -112 -199 26 3 -157 -224 -328 -270 -7 140 57 -144 -131 -101 -99 -4 -102 -186 -98 -27 70 157 139 156 -46 -155 -62 37 -134 -225 -307 -222 149 119 20 -358 -663 -531 -230 -53 215 284 110 164 277 428 522 517 354 44 -192 -52 101 217 405 179 -39 103 146 69 61 -247 -624 -401 2 210 552 616 355 296 355 262 220 297 152 -209 -666 -1133 -1205 -702 236 800 -396 -579 -510 -366 -27 64 77 309 349 425 326 131 97 82 62 -136 -266 -321 -266 90 270 211 223 233 104 117 190 133 277 493 95 -301 -462 -587 -286 82 271 170 171 122 40 46 80 84 164 176 154 145 -17 14 69 -98 -153 -371 -546 -444 -181 120 222 251 152 15 74 49 134 33 10 -111 -194 25 3 -156 -221 -324 -268 -7 137 55 -140 -126 -97 -97 -4 -100 -183 -97 -27 69 155 139 155 -46 -156 -61 37 -131 -215 -292 -209 141 114 19 -354 -667 -530 -226 -52 212 278 110 163 278 432 529 518 356 44 -195 -52 100 214 399 177 -39 101 143 67 60 -244 -611 -385 2 202 536 599 348 294 351 261 221 299 154 -212 -673 -1129 -1194 -681 230 771 SQ 20250127T074858.1Z 9158.325673 93 1 5.29 2 77.74 128.85 74.38 157.62 0.00 1 0.00 1 0 15 3.087e-03 3.077e-03 1.174e-04 1.172e-04 2.950000e+03 6.963027e+00 2.148287e+02 -6.000000e+00 1.677665e+02 273.82 -2.00 20.00 -2.00 505.28 0.00e+00 7.537269e-04 3.177141e-06 4.179665e-05 -6.000000e+00 8.536460e-05 273.82 -2.00 20.00 -2.00 500.50 0.00e+00 4.791845e-01 2.308953e-03 1.905338e-02 -6.000000e+00 6.176762e-02 224.06 -2.00 3.53 -2.00 502.09 0.00e+00 4.573 0.002 489.00 513.00 1 4.7347e-01 1.7668e-04 6.7301e-03 -6.0000e+00 4.7245e-03 4.5787e-03 4.5015e-05 5.9717e-04 -6.0000e+00 1.2249e-03 6.1147e-01 1.4660e-02 1.1848e-05 3.4083e-05 -6.0000e+00 3.2403e-04 3.6674e-04 -1.2116e-05 10 0 0 10 0 0 10.42 14.50 1.33 0.00037 0.10206 656 144 2 2 0 8.050 15.00 14.50 17.33 21.27 20.67 34.7 973.29 -382 -569 -507 -373 -29 28 47 265 333 410 314 141 104 109 91 -108 -271 -336 -273 83 275 214 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