File name: Pandora115s1_Rome-ISAC_20250517_L2Fit_fout2c5d20230305p1-8.txt File generation date: 20250517T231706.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 115 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora115_OF_v1d20210305.txt Instrument calibration file used: Pandora115s1_CF_v5d20230305.txt Level 1 file used: Pandora115s1_Rome-ISAC_20250517_L1_smca1c5d20230305p1-8.txt Full location name: CNR ISAC Rome Short location name: Rome-ISAC Country of location: Italy Location latitude [deg]: 41.8403 Location longitude [deg]: 12.6475 Location altitude [m]: 117 Local noon date: 20250517 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 245 386 Nominal wavelengths inside fitting window [nm]: 305.1112 305.2528 305.3944 305.5360 305.6775 305.8191 305.9606 306.1021 306.2436 306.3851 306.5266 306.6681 306.8096 306.9510 307.0924 307.2338 307.3752 307.5166 307.6580 307.7994 307.9407 308.0820 308.2234 308.3647 308.5059 308.6472 308.7885 308.9297 309.0710 309.2122 309.3534 309.4946 309.6358 309.7770 309.9181 310.0593 310.2004 310.3415 310.4826 310.6237 310.7648 310.9058 311.0469 311.1879 311.3289 311.4699 311.6109 311.7519 311.8929 312.0338 312.1748 312.3157 312.4566 312.5975 312.7384 312.8793 313.0202 313.1610 313.3018 313.4427 313.5835 313.7243 313.8651 314.0058 314.1466 314.2873 314.4281 314.5688 314.7095 314.8502 314.9909 315.1315 315.2722 315.4128 315.5534 315.6941 315.8347 315.9753 316.1158 316.2564 316.3969 316.5375 316.6780 316.8185 316.9590 317.0995 317.2400 317.3804 317.5209 317.6613 317.8017 317.9421 318.0825 318.2229 318.3633 318.5036 318.6440 318.7843 318.9246 319.0649 319.2052 319.3455 319.4858 319.6260 319.7663 319.9065 320.0467 320.1869 320.3271 320.4673 320.6075 320.7476 320.8878 321.0279 321.1680 321.3081 321.4482 321.5883 321.7284 321.8684 322.0085 322.1485 322.2885 322.4285 322.5685 322.7085 322.8484 322.9884 323.1283 323.2683 323.4082 323.5481 323.6880 323.8279 323.9677 324.1076 324.2474 324.3872 324.5271 324.6669 324.8067 324.9464 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250517T043230.1Z 9268.189237 159 1 49.78 2 83.14 70.07 74.17 204.93 0.00 1 0.00 1 0 25 5.618e-01 2.274e-02 3.028e-01 7.551e-03 1.108213e+00 4.408698e-03 1.199074e-02 -6.000000e+00 3.162207e-01 231.11 -2.00 3.53 -2.00 322.33 0.00e+00 4.884553e-04 2.700507e-03 3.863039e-03 -6.000000e+00 1.493572e-02 282.62 -2.00 20.00 -2.00 321.90 0.00e+00 7.655 0.008 302.00 328.00 3 3.0041e-01 1.8181e-02 1.0090e-01 -6.0000e+00 7.9716e-01 1.3192e+00 2.6673e-02 7.0961e-02 -6.0000e+00 8.7056e-01 -1.6556e+00 2.6211e-02 3.5882e-02 -6.0000e+00 5.1264e-01 6.4610e-01 1.1813e-02 1.0743e-02 -6.0000e+00 2.1923e-01 6.0279e-05 -1.5757e-03 1.7255e-04 1.3309e-04 -6.0000e+00 1.3674e-02 2.6396e-03 0.0000e+00 12 9 8 11 8 0 7.12 14.78 0.41 0.00264 -0.00920 56 12 4 8 0 888.910 15.01 14.78 15.13 21.69 20.96 34.7 961.48 900000 -67466 -1052 6687 900000 -154890 -178814 -84011 -145644 900000 -186175 -46370 -61747 -7512 -78457 10671 900000 -113582 900000 -57349 900000 -65432 900000 -46494 55739 -2864 8669 29848 -81367 -7818 3991 900000 -40085 158217 -24963 900000 12415 -7839 123647 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976 1979 529 -2201 -17 -1136 1190 -1976 178 -2157 -258 -2283 -28 -1945 -1559 -3605 -3507 -4322 -3948 16 -2896 -2454 -1131 -343 110 250 1223 -561 980 -1276 1500 -2321 1916 822 4424 2425 1847 2860 1267 2083 298 290 348 2564 1093 799 -1164 268 -209 -831 583 -3873 2259 -2665 -739 SS 20250517T043835.9Z 9268.193471 162 1 49.47 2 82.07 71.04 74.64 206.21 0.00 1 0.00 1 0 25 6.509e-01 1.991e-02 2.320e-01 4.043e-03 1.006848e+00 2.286229e-03 1.107698e-02 -6.000000e+00 3.654641e-01 231.11 -2.00 3.53 -2.00 322.01 0.00e+00 6.381115e-03 1.309688e-03 1.290582e-03 -6.000000e+00 1.783365e-02 282.62 -2.00 20.00 -2.00 321.54 0.00e+00 6.767 0.006 302.00 328.00 3 2.9232e-01 8.8130e-03 8.8014e-02 -6.0000e+00 9.1438e-01 8.4381e-01 1.3342e-02 6.0112e-02 -6.0000e+00 9.9429e-01 -1.0899e+00 1.3816e-02 3.0437e-02 -6.0000e+00 5.9017e-01 4.3689e-01 6.2094e-03 1.1638e-02 -6.0000e+00 2.5250e-01 1.6477e-04 -1.6067e-03 9.3190e-05 1.2306e-04 -6.0000e+00 1.5920e-02 1.9564e-03 0.0000e+00 12 8 8 10 0 0 -2.37 14.79 0.38 0.00196 -0.01012 100 21 4 8 0 494.590 15.01 14.79 15.52 21.69 20.96 34.5 963.52 -72985 -222934 900000 -242722 900000 -250720 -87850 -245382 -4596 -80317 -194780 900000 -140747 900000 -130015 900000 -91411 18603 54107 -43963 43716 -94339 900000 -92522 900000 -106364 900000 -99969 42501 -63138 11085 39781 -30733 110294 -39109 293759 -45893 52524 3101 58675 15449 22475 43831 12067 90458 4560 97795 5147 53460 6657 47397 40749 34382 47131 22541 53458 15843 43262 5725 30985 15644 21356 22682 21699 20646 10965 23493 1211 17307 11165 1482 10253 12509 212 914 6138 -5664 8856 -2439 8661 -848 5826 -795 1795 1322 -2374 3110 -1248 3601 -607 1434 -3411 -613 -4376 -2408 -2358 -1484 -623 -2725 -457 -2141 800 -3951 -3524 -4755 -2725 -842 -1673 -1325 -938 277 -270 690 -702 807 360 768 209 -968 1095 945 3349 -3 1483 148 2212 1280 670 701 166 1059 803 332 -614 78 -614 175 -227 -723 86 -684 -454 -313 -4786 900000 -5732 900000 -5203 -377 -5532 -18 -374 -2927 900000 -2115 900000 -3071 900000 -1963 161 341 -676 293 -2160 900000 -2351 900000 -3235 900000 -2611 301 -1566 175 579 -957 912 -1293 1156 -1659 951 112 1409 620 885 1432 537 1851 226 2002 288 1999 405 2444 2518 2264 3247 1879 3724 1457 3150 516 2329 1338 2010 2508 2780 2734 1585 3136 222 3202 2489 383 2410 2663 45 169 982 -1046 1622 -627 2439 -311 2285 -356 826 648 -1268 1628 -680 1805 -296 642 -1562 -287 -2485 -1499 -1763 -1306 -626 -2910 -451 -1881 585 -2903 -2791 -4061 -2390 -782 -1761 -1515 -1253 409 -418 1055 -1050 1143 516 1154 336 -1632 1747 1399 4575 -4 1960 192 2908 1650 1043 1213 330 2278 1731 777 -1572 211 -1576 449 -582 -1882 203 -1570 -978 SS 20250517T045841.1Z 9268.207420 168 1 49.56 2 78.50 74.19 76.33 210.33 0.00 1 0.00 1 0 25 5.430e-01 9.028e-03 4.068e-02 1.146e-03 7.671128e-01 5.971837e-04 8.656809e-03 -6.000000e+00 3.012027e-01 231.11 -2.00 3.53 -2.00 320.92 0.00e+00 2.925812e-03 2.635087e-04 8.361919e-04 -6.000000e+00 1.314853e-02 282.62 -2.00 20.00 -2.00 320.35 0.00e+00 4.849 0.002 302.00 328.00 3 2.5406e-01 1.9178e-03 6.3380e-02 -6.0000e+00 7.5557e-01 1.6387e-01 2.6544e-03 4.1610e-02 -6.0000e+00 8.2007e-01 -1.7139e-01 2.7769e-03 2.1980e-02 -6.0000e+00 4.8664e-01 5.9779e-02 1.3433e-03 7.5198e-03 -6.0000e+00 2.0812e-01 1.4339e-03 -9.5703e-04 2.6961e-05 6.7428e-05 -6.0000e+00 1.2948e-02 1.9840e-03 0.0000e+00 11 8 0 10 0 0 15.59 14.83 0.25 0.00198 -0.00521 323 69 2 8 0 153.420 14.97 14.83 17.47 21.79 20.96 34.9 975.49 -190707 -186175 -158578 -191467 -181463 -187558 -172061 -173081 -149884 -151675 -149135 -144594 -99521 -95360 -64220 -59376 -50312 -56120 -36482 -34901 -47582 -30265 -38200 -26408 -35612 -32088 -38989 -41800 -30673 -31465 -14490 -11521 -4838 -8229 -13135 -10410 -11847 -5030 -3160 365 644 2869 1955 2610 4094 2704 2132 2832 1170 3337 5857 5472 5560 4689 5666 3275 4107 3636 1296 1823 2816 3370 3799 3714 2192 3168 2032 2444 1296 1540 -213 559 382 -196 4 -847 -1692 -703 -717 -1268 -874 -1605 -1715 -1210 -519 -371 -714 478 946 460 -537 116 -8 -91 -231 -192 888 -22 -874 -675 178 225 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