File name: Pandora115s1_Rome-ISAC_20250522_L2Fit_fwvt1c5d20230305p1-8.txt File generation date: 20250522T231417.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 115 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora115_OF_v1d20210305.txt Instrument calibration file used: Pandora115s1_CF_v5d20230305.txt Level 1 file used: Pandora115s1_Rome-ISAC_20250522_L1_smca1c5d20230305p1-8.txt Full location name: CNR ISAC Rome Short location name: Rome-ISAC Country of location: Italy Location latitude [deg]: 41.8403 Location longitude [deg]: 12.6475 Location altitude [m]: 117 Local noon date: 20250522 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1661 1809 Nominal wavelengths inside fitting window [nm]: 492.0749 492.1964 492.3179 492.4394 492.5609 492.6824 492.8039 492.9253 493.0468 493.1682 493.2896 493.4110 493.5324 493.6538 493.7752 493.8965 494.0179 494.1392 494.2606 494.3819 494.5032 494.6245 494.7457 494.8670 494.9883 495.1095 495.2307 495.3519 495.4732 495.5943 495.7155 495.8367 495.9579 496.0790 496.2002 496.3213 496.4424 496.5635 496.6846 496.8057 496.9267 497.0478 497.1688 497.2899 497.4109 497.5319 497.6529 497.7739 497.8949 498.0159 498.1368 498.2578 498.3787 498.4996 498.6205 498.7414 498.8623 498.9832 499.1041 499.2249 499.3458 499.4666 499.5874 499.7083 499.8291 499.9499 500.0707 500.1914 500.3122 500.4329 500.5537 500.6744 500.7951 500.9158 501.0366 501.1572 501.2779 501.3986 501.5193 501.6399 501.7605 501.8812 502.0018 502.1224 502.2430 502.3636 502.4842 502.6047 502.7253 502.8458 502.9664 503.0869 503.2074 503.3280 503.4485 503.5689 503.6894 503.8099 503.9304 504.0508 504.1713 504.2917 504.4121 504.5325 504.6529 504.7733 504.8937 505.0141 505.1345 505.2548 505.3752 505.4955 505.6159 505.7362 505.8565 505.9768 506.0971 506.2174 506.3377 506.4579 506.5782 506.6985 506.8187 506.9389 507.0592 507.1794 507.2996 507.4198 507.5400 507.6602 507.7803 507.9005 508.0207 508.1408 508.2610 508.3811 508.5012 508.6213 508.7415 508.8616 508.9817 509.1017 509.2218 509.3419 509.4620 509.5820 509.7021 509.8221 509.9421 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250522T044727.8Z 9273.199627 137 1 2.10 2 79.86 71.59 52.73 141.82 0.00 1 0.00 1 0 22 3.498e-03 3.496e-03 1.087e-03 1.086e-03 6.771148e+03 7.169122e+01 4.788934e+02 -6.000000e+00 1.974113e+02 283.13 -2.00 20.00 -2.00 505.29 0.00e+00 8.335430e-04 3.015897e-05 4.729504e-05 -6.000000e+00 9.894196e-05 283.13 -2.00 20.00 -2.00 500.53 0.00e+00 5.399913e-01 2.150264e-02 3.639989e-02 -6.000000e+00 7.032417e-02 231.41 -2.00 3.53 -2.00 502.11 0.00e+00 5.440 0.003 489.00 513.00 1 3.6478e+00 1.6494e-03 8.4240e-03 -6.0000e+00 5.3921e-03 -7.0818e-03 4.1694e-04 1.0604e-03 -6.0000e+00 1.3979e-03 2.2280e-02 1.5223e-02 1.0778e-04 6.0954e-05 -6.0000e+00 3.6779e-04 -1.9326e-02 4.5704e-05 12 1 1 12 1 1 9.93 14.83 1.21 -0.01933 0.08627 6 35 1 2 0 299.910 15.01 14.83 22.50 21.69 20.96 35.1 1003.03 -569 -569 -448 -281 114 118 -46 305 234 338 313 261 39 38 -20 45 -282 -268 -138 141 336 193 160 204 62 224 178 -94 333 417 29 -358 -547 -429 -270 300 192 167 207 82 27 17 57 269 300 310 227 300 -145 -180 -34 -249 -439 -528 -693 -323 -124 84 337 490 171 108 228 244 205 53 70 -286 -150 -80 -7 -291 -393 -428 -337 -18 -47 3 -259 -173 -182 -348 -33 -86 -144 -56 -89 70 376 200 212 115 -173 2 -214 -87 -306 -303 -162 -175 137 -5 -228 -750 -596 -457 137 46 298 198 65 235 520 721 782 413 157 -224 -32 15 260 604 66 -143 100 194 236 27 -202 -366 -240 -298 255 522 594 347 410 409 291 52 255 203 -256 -708 -1102 -1369 -809 42 1090 -553 -558 -446 -283 117 120 -48 315 240 347 317 261 40 38 -20 45 -286 -277 -142 145 346 199 167 213 64 232 183 -96 335 412 28 -360 -558 -441 -279 312 198 170 210 83 27 18 59 278 310 319 231 304 -147 -177 -33 -242 -432 -525 -698 -331 -126 85 341 495 174 111 232 245 207 52 70 -284 -147 -78 -7 -289 -389 -426 -331 -18 -46 2 -253 -167 -176 -341 -33 -84 -142 -55 -88 69 371 200 211 116 -172 2 -208 -83 -291 -283 -153 -164 131 -5 -224 -756 -599 -454 134 46 294 199 65 237 525 730 785 418 159 -226 -33 15 258 598 65 -142 98 192 232 27 -198 -361 -233 -286 248 505 586 344 406 411 295 53 257 206 -260 -718 -1103 -1366 -803 42 1071 SQ 20250522T045654.5Z 9273.206187 141 1 8.05 2 78.18 73.06 51.66 144.41 0.00 1 0.00 1 0 22 3.231e-03 3.223e-03 5.282e-04 5.276e-04 5.775519e+03 3.432198e+01 4.100524e+02 -6.000000e+00 1.823169e+02 283.13 -2.00 20.00 -2.00 505.29 0.00e+00 7.774859e-04 1.465067e-05 4.517028e-05 -6.000000e+00 9.136229e-05 283.13 -2.00 20.00 -2.00 500.52 0.00e+00 4.691400e-01 1.045587e-02 3.238657e-02 -6.000000e+00 6.490667e-02 231.41 -2.00 3.53 -2.00 502.10 0.00e+00 4.729 0.002 489.00 513.00 1 3.7759e+00 8.0219e-04 7.3510e-03 -6.0000e+00 4.9772e-03 -3.1536e-03 2.0307e-04 9.2605e-04 -6.0000e+00 1.2894e-03 2.1836e-02 1.4254e-02 5.2622e-05 5.2801e-05 -6.0000e+00 3.3954e-04 -2.8488e-03 -1.3263e-05 12 1 1 12 1 1 42.48 14.84 1.26 -0.00285 0.09603 27 36 1 2 0 287.370 15.00 14.84 22.79 21.69 20.96 35.0 1004.56 -405 -502 -467 -375 46 92 47 257 303 431 335 235 134 67 128 2 -301 -297 -313 100 283 227 248 223 136 127 199 78 121 334 91 -319 -416 -468 -287 118 244 200 162 155 -44 -3 57 -8 168 201 121 190 57 -43 93 -94 -221 -444 -572 -448 -245 88 157 355 109 -18 132 106 135 105 18 -114 -173 -81 32 -74 -124 -396 -267 -36 47 47 -241 -75 -219 -157 -58 -33 -208 -187 44 42 61 167 176 -143 -280 -57 61 -76 -210 -343 -206 195 20 32 -414 -629 -569 -179 -33 217 229 40 151 224 466 571 653 429 148 -217 -88 148 217 461 220 -77 62 198 134 118 -263 -718 -364 0 280 512 662 313 353 408 241 210 238 92 -249 -626 -1189 -1204 -812 211 1066 -396 -496 -468 -379 48 95 49 267 311 444 340 235 133 67 128 2 -306 -308 -323 104 293 235 258 233 142 132 204 79 122 330 90 -320 -424 -488 -296 123 251 203 164 156 -45 -3 58 -9 173 206 125 192 57 -43 91 -91 -216 -440 -574 -458 -252 90 161 364 110 -18 133 108 135 104 18 -112 -169 -79 31 -73 -124 -391 -265 -35 46 45 -234 -73 -211 -153 -57 -33 -205 -184 43 41 60 166 174 -143 -278 -56 60 -73 -200 -321 -194 182 20 31 -406 -629 -568 -176 -33 214 224 40 153 223 467 574 661 438 151 -220 -88 147 213 453 218 -76 61 196 132 117 -260 -702 -355 0 269 498 644 306 350 411 240 211 240 93 -254 -635 -1190 -1200 -793 207 1049 SQ 20250522T050518.9Z 9273.212024 145 1 27.43 2 76.68 74.36 50.76 146.78 0.00 1 0.00 1 0 22 3.136e-03 3.124e-03 1.434e-04 1.433e-04 5.289945e+03 9.244163e+00 3.788622e+02 -6.000000e+00 1.769537e+02 283.13 -2.00 20.00 -2.00 505.28 0.00e+00 7.767477e-04 3.975376e-06 4.314695e-05 -6.000000e+00 8.870437e-05 283.13 -2.00 20.00 -2.00 500.48 0.00e+00 4.221013e-01 2.839698e-03 2.695688e-02 -6.000000e+00 6.310418e-02 231.41 -2.00 3.53 -2.00 502.07 0.00e+00 4.232 0.001 489.00 513.00 1 2.4963e+00 2.1786e-04 6.5336e-03 -6.0000e+00 4.8374e-03 -4.7776e-03 5.5272e-05 8.0404e-04 -6.0000e+00 1.2559e-03 8.4560e-02 1.6855e-02 1.4337e-05 5.0176e-05 -6.0000e+00 3.2978e-04 3.5091e-03 -1.7931e-04 10 0 0 10 0 0 99.92 14.85 1.30 0.00351 0.12042 551 117 1 2 0 49.230 15.01 14.85 23.03 21.69 20.96 35.1 1007.06 -359 -543 -473 -308 38 132 130 301 329 438 334 129 123 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