File name: Pandora115s1_Rome-ISAC_20250805_L2Fit_fwvt1c7d20240719p1-8.txt File generation date: 20250805T232138.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c7p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 115 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora115_OF_v1d20210305.txt Instrument calibration file used: Pandora115s1_CF_v7d20240719.txt Level 1 file used: Pandora115s1_Rome-ISAC_20250805_L1_smca1c7d20240719p1-8.txt Full location name: CNR ISAC Rome Short location name: Rome-ISAC Country of location: Italy Location latitude [deg]: 41.8403 Location longitude [deg]: 12.6475 Location altitude [m]: 117 Local noon date: 20250805 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1661 1809 Nominal wavelengths inside fitting window [nm]: 492.0748 492.1964 492.3181 492.4397 492.5613 492.6829 492.8045 492.9260 493.0476 493.1692 493.2907 493.4122 493.5337 493.6552 493.7767 493.8982 494.0197 494.1411 494.2626 494.3840 494.5054 494.6268 494.7482 494.8696 494.9910 495.1123 495.2337 495.3550 495.4763 495.5977 495.7190 495.8402 495.9615 496.0828 496.2041 496.3253 496.4465 496.5678 496.6890 496.8102 496.9314 497.0525 497.1737 497.2949 497.4160 497.5371 497.6583 497.7794 497.9005 498.0216 498.1426 498.2637 498.3848 498.5058 498.6268 498.7479 498.8689 498.9899 499.1109 499.2319 499.3528 499.4738 499.5947 499.7157 499.8366 499.9575 500.0784 500.1993 500.3202 500.4411 500.5620 500.6828 500.8037 500.9245 501.0453 501.1661 501.2869 501.4077 501.5285 501.6493 501.7700 501.8908 502.0115 502.1323 502.2530 502.3737 502.4944 502.6151 502.7358 502.8565 502.9771 503.0978 503.2184 503.3390 503.4597 503.5803 503.7009 503.8215 503.9421 504.0626 504.1832 504.3038 504.4243 504.5448 504.6654 504.7859 504.9064 505.0269 505.1474 505.2679 505.3883 505.5088 505.6293 505.7497 505.8701 505.9906 506.1110 506.2314 506.3518 506.4722 506.5925 506.7129 506.8333 506.9536 507.0740 507.1943 507.3146 507.4350 507.5553 507.6756 507.7959 507.9161 508.0364 508.1567 508.2769 508.3972 508.5174 508.6377 508.7579 508.8781 508.9983 509.1185 509.2387 509.3589 509.4790 509.5992 509.7194 509.8395 509.9597 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250805T042808.0Z 9348.186204 54 1 19.43 2 87.27 69.64 139.01 272.63 0.00 1 0.00 1 0 22 4.240e-03 4.237e-03 1.394e-04 1.392e-04 1.999334e+04 1.061868e+01 1.350817e+03 -6.000000e+00 2.445633e+02 288.86 -2.00 20.00 -2.00 505.36 0.00e+00 2.144977e-03 3.948623e-06 1.115371e-04 -6.000000e+00 1.216503e-04 288.86 -2.00 20.00 -2.00 500.68 0.00e+00 1.265513e+00 2.737664e-03 8.628944e-02 -6.000000e+00 8.495831e-02 232.19 -2.00 3.53 -2.00 502.24 0.00e+00 14.092 0.052 489.00 513.00 1 -2.1523e-01 2.1026e-04 2.2800e-02 -6.0000e+00 6.5293e-03 -9.8896e-03 5.2149e-05 2.7345e-03 -6.0000e+00 1.6880e-03 2.8534e-01 1.6806e-02 1.2572e-05 1.4365e-04 -6.0000e+00 4.4580e-04 8.4756e-02 -6.5927e-04 11 8 0 10 0 0 -6.15 14.59 1.26 0.08476 0.20133 517 110 2 2 0 35.900 15.00 14.59 23.87 21.38 20.77 34.8 971.18 -817 -752 -424 -133 315 473 598 729 686 589 349 91 -61 -183 -244 -340 -279 -159 -68 215 289 245 347 412 325 306 335 102 -96 -127 -460 -637 -448 -335 -79 152 168 10 -51 -29 -34 91 189 302 406 396 311 203 -97 -340 -463 -637 -602 -511 -456 -194 61 279 351 452 369 265 265 230 145 -13 -108 -279 -457 -351 -272 -260 -168 -290 -363 -268 -207 -282 -450 -340 -262 -214 -174 -258 -388 -243 -135 52 274 323 381 221 55 176 215 -62 -342 -873 -903 -440 -120 81 -146 -439 -492 -383 -264 -51 50 -11 47 336 713 1079 1281 1087 449 -173 -286 -255 61 550 577 258 282 241 -11 -40 -345 -847 -519 -89 -9 328 499 341 603 730 477 269 216 102 -39 -337 -863 -1175 -901 -35 692 -776 -721 -412 -130 314 470 600 731 681 588 344 89 -59 -177 -237 -337 -278 -159 -69 218 294 250 356 424 330 315 340 102 -95 -123 -452 -633 -451 -345 -82 156 171 11 -52 -29 -35 94 194 312 421 407 316 207 -96 -337 -458 -628 -592 -508 -467 -198 63 286 360 465 382 275 275 236 147 -13 -108 -277 -451 -345 -268 -260 -170 -289 -363 -263 -204 -275 -437 -331 -257 -208 -171 -257 -389 -243 -134 51 270 320 374 221 53 169 201 -58 -315 -796 -822 -399 -111 77 -144 -439 -496 -384 -262 -51 50 -11 47 339 718 1090 1289 1113 458 -176 -290 -257 61 544 575 259 284 239 -11 -40 -347 -845 -510 -87 -9 329 501 343 618 746 495 283 225 106 -41 -349 -900 -1211 -917 -36 706 SQ 20250805T042828.0Z 9348.186435 54 2 19.82 2 87.21 69.70 139.06 272.69 0.00 1 0.00 1 0 22 4.166e-03 4.165e-03 1.365e-04 1.363e-04 1.985717e+04 1.039159e+01 1.342481e+03 -6.000000e+00 2.403151e+02 288.86 -2.00 20.00 -2.00 505.36 0.00e+00 2.144685e-03 3.867543e-06 1.115714e-04 -6.000000e+00 1.195347e-04 288.86 -2.00 20.00 -2.00 500.67 0.00e+00 1.257080e+00 2.681847e-03 8.581767e-02 -6.000000e+00 8.347721e-02 232.19 -2.00 3.53 -2.00 502.23 0.00e+00 13.953 0.051 489.00 513.00 1 -2.3759e-01 2.0601e-04 2.2542e-02 -6.0000e+00 6.4155e-03 -9.5715e-03 5.1105e-05 2.7146e-03 -6.0000e+00 1.6585e-03 2.9780e-01 1.6675e-02 1.2319e-05 1.4267e-04 -6.0000e+00 4.3803e-04 8.9053e-02 -6.8108e-04 11 8 0 10 0 0 -8.10 14.59 1.24 0.08905 0.20472 517 110 2 2 0 35.900 15.00 14.59 23.87 21.38 20.77 34.8 971.18 -852 -744 -403 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1.22 0.08292 0.19610 517 110 2 2 0 35.900 15.00 14.59 23.87 21.38 20.77 34.8 971.18 -842 -735 -433 -132 312 454 533 719 644 575 349 113 -22 -173 -228 -341 -279 -169 -78 189 312 258 318 402 326 324 331 121 -70 -107 -446 -594 -432 -346 -98 133 167 21 -21 -40 -29 75 197 308 379 370 313 200 -101 -328 -431 -629 -600 -492 -448 -205 43 278 339 446 340 277 285 244 193 2 -108 -281 -462 -309 -243 -270 -196 -294 -375 -296 -211 -301 -449 -332 -237 -225 -152 -228 -344 -259 -134 46 285 335 375 206 23 155 179 -75 -307 -817 -891 -386 -121 63 -178 -456 -483 -368 -226 -20 84 -22 61 325 734 1020 1257 1047 416 -176 -332 -256 93 548 535 258 274 265 -2 -27 -356 -830 -491 -84 8 336 503 347 572 729 450 273 251 92 -77 -351 -871 -1156 -916 -43 703 -797 -704 -420 -131 311 451 535 720 639 573 344 111 -22 -170 -221 -338 -278 -172 -79 192 317 263 326 415 331 333 335 122 -69 -106 -438 -590 -443 -356 -102 136 170 21 -21 -40 -30 78 202 319 393 381 318 203 -102 -324 -425 -619 -589 -488 -457 -209 44 284 348 458 352 287 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