File name: Pandora117s1_Rome-SAP_20230724_L2Fit_fout2c14d20221111p1-8.txt File generation date: 20230726T111413.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 117 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora117_OF_v5d20200604.txt Instrument calibration file used: Pandora117s1_CF_v14d20221111.txt Level 1 file used: Pandora117s1_Rome-SAP_20230724_L1_smca1c14d20221111p1-8.txt Full location name: Department of Physics, University of Rome La Sapienza Short location name: Rome-SAP Country of location: Italy Location latitude [deg]: 41.9017 Location longitude [deg]: 12.5158 Location altitude [m]: 75 Local noon date: 20230724 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 11 "Modification of session 2 "Field cal based on session1"" fieldcal ref day 20230304 First and last pixel inside fitting window: 216 358 Nominal wavelengths inside fitting window [nm]: 305.0420 305.1832 305.3244 305.4656 305.6068 305.7480 305.8892 306.0303 306.1715 306.3126 306.4537 306.5948 306.7359 306.8770 307.0181 307.1591 307.3002 307.4412 307.5823 307.7233 307.8643 308.0053 308.1463 308.2873 308.4283 308.5692 308.7102 308.8511 308.9920 309.1330 309.2739 309.4148 309.5557 309.6965 309.8374 309.9782 310.1191 310.2599 310.4007 310.5416 310.6824 310.8231 310.9639 311.1047 311.2455 311.3862 311.5269 311.6677 311.8084 311.9491 312.0898 312.2305 312.3711 312.5118 312.6524 312.7931 312.9337 313.0743 313.2149 313.3555 313.4961 313.6367 313.7773 313.9178 314.0584 314.1989 314.3394 314.4799 314.6204 314.7609 314.9014 315.0419 315.1823 315.3228 315.4632 315.6036 315.7441 315.8845 316.0248 316.1652 316.3056 316.4460 316.5863 316.7266 316.8670 317.0073 317.1476 317.2879 317.4282 317.5684 317.7087 317.8490 317.9892 318.1294 318.2696 318.4099 318.5501 318.6902 318.8304 318.9706 319.1107 319.2509 319.3910 319.5311 319.6712 319.8113 319.9514 320.0915 320.2316 320.3716 320.5116 320.6517 320.7917 320.9317 321.0717 321.2117 321.3517 321.4916 321.6316 321.7715 321.9115 322.0514 322.1913 322.3312 322.4711 322.6109 322.7508 322.8907 323.0305 323.1703 323.3102 323.4500 323.5898 323.7295 323.8693 324.0091 324.1488 324.2886 324.4283 324.5680 324.7077 324.8474 324.9871 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230724T052948.4Z 8605.229032 81 1 40.34 2 74.45 76.98 135.94 37.12 0.00 1 0.00 1 0 25 8.304e-02 5.914e-03 4.110e-02 2.099e-03 4.664586e-01 1.100887e-03 5.423226e-03 -6.000000e+00 4.856293e-02 232.66 -2.00 3.53 -2.00 320.02 0.00e+00 9.953285e-04 3.043049e-04 2.622338e-04 -6.000000e+00 1.908581e-03 288.78 -2.00 20.00 -2.00 319.72 0.00e+00 3.662 0.001 302.00 328.00 3 2.2446e+00 3.1163e-03 4.4302e-02 -6.0000e+00 1.2306e-01 2.8578e-03 3.6788e-03 2.5155e-02 -6.0000e+00 1.3327e-01 -1.6860e-02 3.4487e-03 1.2901e-02 -6.0000e+00 7.8015e-02 -4.9053e-04 1.8338e-03 3.9215e-03 -6.0000e+00 3.2663e-02 8.6748e-04 -3.7599e-05 6.1629e-05 4.2576e-05 -6.0000e+00 2.2357e-03 2.8733e-02 0.0000e+00 12 1 1 12 1 1 85.19 17.46 0.22 0.02873 0.02845 71 17 4 8 0 557.780 15.00 17.46 33.43 20.56 20.87 38.9 982.46 -46304 9829 -33896 -22764 -28693 -37462 -6806 -31227 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17.46 0.33 0.02836 0.02912 27 9 4 8 0 1087.690 15.01 17.46 33.45 20.56 20.87 38.9 982.74 -27757 3923 4470 -37605 54867 -52377 -2782 -14003 -1959 -16735 -30693 20274 -10429 11988 -1856 7911 -12166 -3951 852 -8422 5794 -3528 9688 -1122 -12314 4634 -5861 1605 -4589 -1062 841 -991 2358 -5157 -1093 -1538 568 -96 459 1634 -1566 1501 -3544 1285 -453 246 1367 -1559 -599 -1497 1903 885 1887 608 -72 2437 -252 376 268 165 1410 525 2734 1436 912 -514 850 465 -448 1664 -776 828 -98 -595 -871 -1855 -473 -541 899 -971 -1148 -620 -2358 -927 -1038 97 -376 443 1322 185 1158 -243 1118 629 64 604 287 1191 -586 -425 -272 77 -499 -108 -615 -1919 -558 -179 214 -173 -88 584 -190 736 49 417 367 -110 265 -743 -489 156 756 -14 192 -11 399 1523 234 -511 66 93 267 -602 149 -407 -67 418 -231 -366 203 -55 900000 -531 62 74 -899 512 -1303 -46 -295 -41 -436 -940 407 -342 381 -81 360 -681 -236 52 -548 360 -241 609 -79 -1037 346 -488 127 -372 -87 71 -97 250 -609 -117 -167 68 -14 80 330 -359 353 -912 320 -116 63 347 -410 -158 -419 563 289 658 230 -29 974 -106 156 108 67 591 244 1289 743 474 -255 402 225 -242 1008 -523 567 -67 -385 -517 -998 -250 -287 524 -623 -841 -504 -2085 -854 -967 95 -389 466 1365 184 1119 -220 947 550 62 621 336 1544 -759 -565 -334 86 -536 -123 -756 -2507 -758 -242 312 -276 -149 995 -315 1132 70 579 522 -166 427 -1256 -818 252 1178 -21 275 -17 564 2259 365 -874 118 164 489 -1177 309 -833 -139 883 -485 -777 408 -106 900000 SS 20230724T054135.7Z 8605.237219 86 1 30.21 2 72.31 78.81 134.65 40.71 0.00 1 0.00 1 0 25 4.416e-02 5.803e-03 4.260e-02 3.072e-03 4.159447e-01 1.597058e-03 4.851102e-03 -6.000000e+00 2.582796e-02 232.66 -2.00 3.53 -2.00 319.63 0.00e+00 1.264416e-03 3.917121e-04 1.982207e-04 -6.000000e+00 1.014967e-03 288.78 -2.00 20.00 -2.00 319.32 0.00e+00 3.244 0.001 302.00 328.00 3 3.1233e+00 4.4497e-03 3.9250e-02 -6.0000e+00 6.5450e-02 4.0728e-03 5.1302e-03 2.2217e-02 -6.0000e+00 7.0876e-02 8.6819e-04 4.3897e-03 1.1253e-02 -6.0000e+00 4.1490e-02 -9.3670e-03 2.3568e-03 3.3665e-03 -6.0000e+00 1.7375e-02 5.6541e-04 2.0061e-04 9.0602e-05 3.5221e-05 -6.0000e+00 1.1888e-03 2.7370e-02 0.0000e+00 12 1 1 12 1 1 99.99 17.47 0.16 0.02737 0.02888 39 12 4 8 0 750.540 15.00 17.47 33.59 20.56 20.87 38.9 983.70 668 -7083 -4839 -6095 -17260 -7073 -30265 -22577 11679 -12142 -2702 3106 -11946 -6487 -4525 1469 318 1526 383 -427 1071 800 -5130 -1372 -4123 -397 -1423 -4943 -3942 -634 -64 6243 1393 1395 -3927 -2945 764 -1034 1525 -1677 -797 -1253 -688 -190 -930 -491 -1986 -234 -3248 1132 1615 330 -470 1504 1311 1223 65 -363 -168 632 1578 2119 1266 2593 622 463 374 814 1585 418 -320 -710 28 829 -44 -1077 -259 -763 179 -247 -1366 -927 -958 -1449 173 -990 -526 51 912 687 -248 1057 365 308 515 152 435 626 128 -1130 -38 9 -693 228 -1520 -1151 -575 -315 257 -44 312 58 195 282 286 561 154 277 -125 -273 -644 -51 927 -345 561 60 735 1149 392 -276 -35 -46 -247 -302 -102 -73 38 509 -140 -654 228 -136 900000 12 -157 -110 -133 -382 -139 -816 -612 265 -355 -77 90 -460 -286 -234 81 18 94 25 -30 76 57 -404 -112 -369 -36 -130 -446 -338 -55 -6 641 168 173 -485 -363 101 -166 291 -373 -193 -321 -183 -51 -253 -134 -551 -64 -925 322 499 113 -174 582 529 509 28 -156 -71 263 680 996 639 1394 339 238 193 423 869 265 -221 -510 19 547 -27 -619 -137 -406 104 -160 -1022 -768 -814 -1308 166 -1023 -567 55 984 705 -237 956 314 271 480 160 500 800 171 -1483 -45 11 -761 262 -1855 -1468 -769 -445 375 -70 526 96 319 430 421 795 224 411 -199 -454 -1070 -82 1431 -533 822 84 998 1646 600 -461 -62 -81 -451 -586 -204 -151 81 1091 -298 -1341 457 -264 900000 SS 20230724T055842.2Z 8605.249100 93 1 52.46 2 69.18 81.48 132.61 45.64 0.00 1 0.00 1 0 25 2.055e-02 5.402e-03 5.478e-03 6.546e-04 3.608826e-01 3.387562e-04 4.278688e-03 -6.000000e+00 1.201616e-02 232.65 -2.00 3.53 -2.00 319.00 0.00e+00 4.884772e-04 6.833296e-05 1.347221e-04 -6.000000e+00 4.722215e-04 288.78 -2.00 20.00 -2.00 318.68 0.00e+00 2.785 0.000 302.00 328.00 3 1.2728e+00 9.2681e-04 3.3809e-02 -6.0000e+00 3.0450e-02 -2.2536e-03 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