File name: Pandora117s1_Rome-SAP_20240610_L2Fit_fwvt1c14d20221111p1-8.txt
File generation date: 20240610T231715.2Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c14p1-8
Local principal investigator: Stefano Casadio
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 117
Spectrometer number: 1
Processing software version used: BlickP v1.8.59
Instrument operation file used: Pandora117_OF_v5d20200604.txt
Instrument calibration file used: Pandora117s1_CF_v14d20221111.txt
Level 1 file used: Pandora117s1_Rome-SAP_20240610_L1_smca1c14d20221111p1-8.txt
Full location name: Department of Physics, University of Rome La Sapienza
Short location name: Rome-SAP
Country of location: Italy
Location latitude [deg]: 41.9017
Location longitude [deg]: 12.5158
Location altitude [m]: 75
Local noon date: 20240610
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 11 "Modification of session 2 "Field cal based on session1"" fieldcal ref day 20230304
First and last pixel inside fitting window: 1633 1782
Nominal wavelengths inside fitting window [nm]: 492.0759 492.1973 492.3188 492.4402 492.5616 492.6830 492.8043 492.9257 493.0470 493.1683 493.2896 493.4109 493.5321 493.6534 493.7746 493.8958 494.0170 494.1382 494.2594 494.3805 494.5017 494.6228 494.7439 494.8649 494.9860 495.1071 495.2281 495.3491 495.4701 495.5911 495.7121 495.8330 495.9539 496.0749 496.1958 496.3166 496.4375 496.5584 496.6792 496.8000 496.9208 497.0416 497.1624 497.2831 497.4039 497.5246 497.6453 497.7660 497.8866 498.0073 498.1279 498.2485 498.3691 498.4897 498.6103 498.7308 498.8514 498.9719 499.0924 499.2129 499.3334 499.4538 499.5742 499.6947 499.8151 499.9354 500.0558 500.1762 500.2965 500.4168 500.5371 500.6574 500.7777 500.8979 501.0182 501.1384 501.2586 501.3788 501.4989 501.6191 501.7392 501.8593 501.9794 502.0995 502.2196 502.3396 502.4597 502.5797 502.6997 502.8197 502.9397 503.0596 503.1795 503.2995 503.4193 503.5392 503.6591 503.7789 503.8988 504.0186 504.1384 504.2582 504.3779 504.4977 504.6174 504.7371 504.8568 504.9765 505.0962 505.2158 505.3354 505.4551 505.5747 505.6942 505.8138 505.9333 506.0529 506.1724 506.2919 506.4113 506.5308 506.6502 506.7697 506.8891 507.0085 507.1279 507.2472 507.3665 507.4859 507.6052 507.7245 507.8437 507.9630 508.0822 508.2015 508.3207 508.4398 508.5590 508.6782 508.7973 508.9164 509.0355 509.1546 509.2737 509.3927 509.5118 509.6308 509.7498 509.8688 509.9877
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 100: Humidity in head sensor [%], -9=no humidity signal
Column 101: Pressure in head sensor [hPa], -9=no pressure signal
Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20240610T042849.1Z 8927.186679 71 1 53.01 2 81.92 66.18 109.57 29.31 0.00 1 0.00 1 0 22 2.889e-03 2.868e-03 2.276e-04 2.270e-04 9.905864e+03 1.589342e+01 6.743655e+02 -6.000000e+00 1.630914e+02 285.32 -2.00 20.00 -2.00 505.29 0.00e+00 1.169552e-03 6.307059e-06 7.898536e-05 -6.000000e+00 8.188102e-05 285.32 -2.00 20.00 -2.00 500.41 0.00e+00 6.888647e-01 4.552663e-03 6.212211e-02 -6.000000e+00 5.809250e-02 232.65 -2.00 3.53 -2.00 502.00 0.00e+00 6.656 0.005 489.00 513.00 1 3.4854e+00 3.4804e-04 1.1025e-02 -6.0000e+00 4.4501e-03 1.0688e-03 8.9367e-05 1.6169e-03 -6.0000e+00 1.1649e-03 2.1525e-02 7.5400e-04 2.1998e-05 7.4090e-05 -6.0000e+00 3.0141e-04 -3.9490e-02 -4.1822e-04 12 1 1 12 4 4 99.98 29.39 1.29 -0.03949 -0.03426 785 145 1 2 0 64.480 15.00 29.39 27.28 22.29 22.71 39.6 1000.67 900000 -244 -308 39 253 390 647 636 587 449 362 311 93 -186 -227 -29 1 -68 -1 -17 -16 156 281 230 283 282 94 33 -39 -426 -380 56 -119 -228 -96 -111 -191 -43 -69 -186 -137 -36 41 85 182 166 159 51 11 -185 -449 -570 -425 -433 -316 -222 -182 -69 83 182 193 301 226 178 91 56 97 -83 -211 -353 -418 -199 -104 -199 -292 -242 -234 -156 -162 -371 -504 -391 -282 -375 -291 -191 -262 -245 -159 108 133 152 307 257 175 327 346 -19 -364 -688 -700 -423 -472 -455 -481 -448 -250 -70 -137 -74 24 -39 99 356 560 629 634 577 359 194 314 265 221 277 222 12 179 351 118 241 114 -169 26 115 -194 -169 66 6 165 292 218 220 264 295 138 46 -106 -281 -336 -267 900000 -238 -307 38 254 401 678 676 628 479 381 323 95 -189 -228 -29 1 -71 -1 -18 -17 161 292 239 295 295 98 35 -40 -446 -388 57 -122 -240 -100 -117 -202 -45 -71 -190 -139 -37 43 89 191 176 168 53 11 -188 -444 -577 -422 -431 -319 -219 -185 -71 86 188 199 312 235 186 95 57 98 -83 -208 -345 -405 -192 -101 -196 -290 -240 -230 -150 -154 -350 -476 -371 -269 -362 -283 -187 -259 -242 -157 106 131 151 308 258 174 316 324 -17 -325 -635 -643 -375 -432 -435 -478 -453 -252 -70 -135 -73 24 -38 97 350 551 621 632 580 362 194 308 256 211 264 212 12 173 338 114 232 109 -160 25 111 -188 -158 63 5 163 292 221 224 270 303 142 47 -107 -278 -328 -259
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SQ 20240610T044322.0Z 8927.196782 74 2 5.92 2 79.42 68.44 108.27 32.40 0.00 1 0.00 1 0 22 2.653e-03 2.634e-03 1.518e-04 1.515e-04 7.756861e+03 1.023366e+01 5.334324e+02 -6.000000e+00 1.498190e+02 285.33 -2.00 20.00 -2.00 505.29 0.00e+00 1.029936e-03 4.222658e-06 6.976407e-05 -6.000000e+00 7.519877e-05 285.33 -2.00 20.00 -2.00 500.45 0.00e+00 5.178167e-01 3.042198e-03 5.087563e-02 -6.000000e+00 5.332472e-02 232.65 -2.00 3.53 -2.00 502.04 0.00e+00 5.235 0.003 489.00 513.00 1 9.1165e-01 2.3308e-04 8.7696e-03 -6.0000e+00 4.0855e-03 -4.5470e-04 6.0032e-05 1.2987e-03 -6.0000e+00 1.0683e-03 3.5165e-01 -2.7409e-04 1.4889e-05 6.3343e-05 -6.0000e+00 2.7682e-04 -7.0229e-02 -1.7411e-04 12 1 1 12 4 4 53.36 29.42 1.56 -0.07023 -0.07213 452 84 2 2 0 11.690 15.00 29.42 28.51 22.29 22.71 39.7 1004.27 900000 -198 -267 17 235 372 559 607 588 515 370 314 120 -165 -189 -69 42 -115 -51 -29 -24 160 262 237 267 234 85 41 -66 -412 -321 75 -105 -249 -133 -141 -182 -24 -50 -119 -155 -58 56 92 148 141 131 55 -33 -146 -410 -484 -383 -338 -248 -229 -228 -121 48 147 206 304 203 127 95 64 45 -70 -149 -309 -408 -174 -78 -195 -276 -229 -226 -113 -136 -334 -451 -286 -253 -360 -224 -194 -228 -230 -179 63 106 135 246 237 144 276 315 -40 -336 -627 -571 -352 -437 -398 -438 -458 -272 -73 -147 -46 36 13 130 326 502 550 649 526 340 178 278 270 163 241 173 11 191 297 150 216 132 -136 -33 142 -158 -182 70 84 91 228 179 193 282 263 168 34 -146 -267 -342 -179 900000 -191 -263 17 238 385 569 627 611 533 378 317 124 -168 -191 -70 43 -119 -52 -30 -25 169 277 251 283 249 90 43 -69 -418 -317 76 -104 -253 -139 -146 -188 -25 -52 -123 -161 -61 58 94 153 147 136 56 -33 -150 -411 -473 -381 -336 -242 -230 -234 -122 49 149 209 308 207 130 96 64 46 -71 -149 -305 -400 -169 -76 -194 -277 -230 -224 -110 -130 -319 -431 -275 -245 -352 -221 -193 -229 -223 -178 63 103 133 243 235 141 265 304 -38 -309 -588 -532 -321 -411 -389 -429 -456 -270 -71 -142 -44 35 13 131 330 493 543 645 527 340 177 280 268 159 236 170 11 189 295 148 213 130 -132 -31 134 -149 -175 69 81 89 226 180 195 285 267 170 34 -145 -260 -329 -170
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