File name: Pandora117s1_Rome-SAP_20250221_L2Fit_fwvt1c17d20231005p1-8.txt File generation date: 20250221T233224.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c17p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 117 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora117_OF_v5d20200604.txt Instrument calibration file used: Pandora117s1_CF_v17d20231005.txt Level 1 file used: Pandora117s1_Rome-SAP_20250221_L1_smca1c17d20231005p1-8.txt Full location name: Department of Physics, University of Rome La Sapienza Short location name: Rome-SAP Country of location: Italy Location latitude [deg]: 41.9017 Location longitude [deg]: 12.5158 Location altitude [m]: 75 Local noon date: 20250221 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1634 1782 Nominal wavelengths inside fitting window [nm]: 492.1033 492.2247 492.3460 492.4673 492.5886 492.7099 492.8311 492.9524 493.0736 493.1948 493.3160 493.4372 493.5583 493.6795 493.8006 493.9217 494.0428 494.1639 494.2850 494.4060 494.5270 494.6481 494.7691 494.8900 495.0110 495.1319 495.2529 495.3738 495.4947 495.6156 495.7364 495.8573 495.9781 496.0989 496.2197 496.3405 496.4613 496.5820 496.7028 496.8235 496.9442 497.0649 497.1855 497.3062 497.4268 497.5474 497.6680 497.7886 497.9092 498.0298 498.1503 498.2708 498.3913 498.5118 498.6323 498.7527 498.8732 498.9936 499.1140 499.2344 499.3548 499.4751 499.5954 499.7158 499.8361 499.9564 500.0766 500.1969 500.3171 500.4374 500.5576 500.6778 500.7979 500.9181 501.0382 501.1583 501.2785 501.3985 501.5186 501.6387 501.7587 501.8787 501.9988 502.1187 502.2387 502.3587 502.4786 502.5985 502.7185 502.8383 502.9582 503.0781 503.1979 503.3178 503.4376 503.5574 503.6771 503.7969 503.9166 504.0364 504.1561 504.2758 504.3954 504.5151 504.6347 504.7544 504.8740 504.9936 505.1132 505.2327 505.3523 505.4718 505.5913 505.7108 505.8303 505.9497 506.0692 506.1886 506.3080 506.4274 506.5468 506.6662 506.7855 506.9048 507.0241 507.1434 507.2627 507.3820 507.5012 507.6205 507.7397 507.8589 507.9780 508.0972 508.2164 508.3355 508.4546 508.5737 508.6928 508.8118 508.9309 509.0499 509.1689 509.2879 509.4069 509.5259 509.6448 509.7637 509.8826 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250221T061043.0Z 9183.257442 159 1 45.30 2 88.37 105.63 70.08 190.01 0.00 1 0.00 1 0 29 9.322e-03 9.226e-03 4.281e-04 4.265e-04 8.933155e+03 2.793359e+01 6.158808e+02 -6.000000e+00 5.085609e+02 274.45 -2.00 20.00 -2.00 505.40 0.00e+00 3.707613e-03 1.171406e-05 2.024975e-04 -6.000000e+00 2.579227e-04 274.45 -2.00 20.00 -2.00 501.04 0.00e+00 1.136666e+00 8.323909e-03 7.652540e-02 -6.000000e+00 1.872015e-01 225.05 -2.00 3.53 -2.00 502.54 0.00e+00 17.160 0.095 489.00 513.00 1 3.3424e+00 6.3508e-04 2.8964e-02 -6.0000e+00 1.4313e-02 -4.1689e-02 1.6036e-04 2.3011e-03 -6.0000e+00 3.7293e-03 5.3208e-03 4.2368e-03 4.3350e-05 1.1524e-04 -6.0000e+00 1.0019e-03 1.3873e-02 9.0625e-06 12 8 8 10 0 0 79.01 20.35 4.36 0.01387 0.04326 77 14 4 2 0 588.090 15.01 49.20 10.76 20.35 20.25 40.2 1021.10 -1934 -1393 -322 418 1086 1547 1543 1552 1117 895 435 -301 -871 -933 -624 -525 -186 237 338 537 817 945 899 1028 916 714 262 -568 -1225 -1331 -1166 -884 -288 191 285 246 90 -151 -329 -206 131 416 815 995 1105 949 552 204 -568 -1318 -1667 -1592 -1320 -765 -164 143 630 786 870 973 1142 1086 905 698 414 106 -470 -767 -1070 -1180 -930 -723 -605 -601 -888 -944 -1194 -1302 -1634 -1540 -1198 -1163 -816 -742 -584 -596 -452 -548 -71 225 525 889 859 810 776 132 -567 -1407 -1955 -2004 -1565 -1024 -549 -398 -460 -436 -678 -678 -263 126 535 962 1540 1842 1952 1972 1628 1193 825 815 457 559 685 594 578 775 781 514 496 82 -440 -351 -720 -893 -620 -151 103 470 587 475 603 589 613 441 41 -572 -1270 -1495 -1453 -1701 -1255 -298 396 1000 1448 1461 1472 1056 837 403 -278 -800 -853 -572 -488 -176 229 331 529 806 936 896 986 884 689 252 -563 -1193 -1277 -1121 -864 -277 188 284 245 89 -149 -323 -203 130 418 827 1021 1140 979 566 207 -568 -1295 -1612 -1527 -1277 -755 -166 142 630 789 873 979 1156 1105 923 710 417 106 -466 -753 -1043 -1147 -905 -709 -600 -601 -887 -930 -1162 -1257 -1578 -1491 -1165 -1141 -805 -740 -586 -600 -453 -550 -71 226 535 913 882 820 767 128 -538 -1319 -1819 -1870 -1486 -1003 -557 -398 -465 -439 -680 -680 -265 129 554 1005 1615 1943 2077 2039 1700 1247 856 866 482 586 722 607 595 799 807 533 514 85 -451 -356 -730 -914 -644 -160 110 511 647 509 651 640 669 482 45 -614 -1349 -1577 -1538 SQ 20250221T062114.8Z 9183.264755 167 1 51.38 2 86.49 107.41 70.47 192.40 0.00 1 0.00 1 0 15 4.586e-03 4.558e-03 1.289e-04 1.287e-04 6.505683e+03 8.171510e+00 4.672877e+02 -6.000000e+00 2.502670e+02 274.45 -2.00 20.00 -2.00 505.34 0.00e+00 2.374526e-03 3.516958e-06 1.332040e-04 -6.000000e+00 1.268858e-04 274.45 -2.00 20.00 -2.00 500.79 0.00e+00 1.214374e+00 2.537428e-03 5.270859e-02 -6.000000e+00 9.201768e-02 225.05 -2.00 3.53 -2.00 502.33 0.00e+00 12.457 0.036 489.00 513.00 1 1.8410e+00 1.9386e-04 1.9191e-02 -6.0000e+00 7.0371e-03 -2.6961e-02 4.9355e-05 1.5853e-03 -6.0000e+00 1.8307e-03 4.7022e-02 1.8916e-03 1.3265e-05 8.1999e-05 -6.0000e+00 4.9297e-04 -1.0587e-02 2.4062e-04 11 8 0 10 0 0 50.23 20.25 1.72 -0.01059 0.00253 588 109 2 2 0 86.040 14.99 47.88 11.53 20.25 20.25 39.7 1023.29 -729 -516 -58 315 630 900 888 849 708 574 451 14 -310 -315 -129 -76 -83 67 32 198 475 476 510 507 419 213 27 -314 -680 -395 -221 -412 -297 -157 -152 -129 5 -168 -214 -182 -46 149 236 372 360 348 128 -1 -339 -723 -724 -705 -574 -404 -289 -144 129 341 406 500 544 434 355 260 127 11 -199 -406 -625 -562 -350 -313 -415 -413 -465 -419 -430 -569 -752 -760 -587 -596 -499 -309 -383 -353 -335 -199 105 193 323 416 401 370 450 187 -278 -709 -996 -861 -785 -673 -530 -577 -495 -279 -223 -231 -43 28 167 436 750 943 1015 1064 813 534 453 515 357 345 395 226 205 488 392 324 313 4 -225 -34 -151 -385 -209 -33 45 233 375 312 367 420 351 200 -44 -373 -546 -621 -568 -687 -480 -55 299 612 889 889 851 705 565 439 14 -297 -299 -123 -73 -81 68 32 197 474 477 512 512 426 216 27 -311 -681 -387 -217 -399 -296 -160 -158 -133 5 -171 -216 -185 -47 154 238 379 369 356 129 -1 -344 -716 -702 -677 -555 -400 -294 -144 131 347 413 509 558 447 366 267 129 11 -197 -398 -607 -561 -338 -305 -410 -411 -461 -409 -414 -562 -741 -726 -565 -578 -488 -305 -381 -352 -334 -198 105 193 328 413 398 375 446 181 -264 -683 -949 -821 -737 -653 -515 -577 -498 -278 -221 -228 -42 28 171 450 756 956 1036 1095 842 552 463 519 367 353 394 227 207 493 396 328 316 4 -224 -34 -152 -379 -208 -34 47 238 387 325 385 443 373 212 -47 -387 -557 -626 -574 SQ 20250221T063732.4Z 9183.276070 172 1 12.63 2 83.62 110.21 71.22 196.06 0.00 1 0.00 1 0 15 3.173e-03 3.163e-03 1.259e-04 1.258e-04 4.193863e+03 7.723149e+00 3.127333e+02 -6.000000e+00 1.731502e+02 274.45 -2.00 20.00 -2.00 505.30 0.00e+00 1.512420e-03 3.427079e-06 8.619785e-05 -6.000000e+00 8.778263e-05 274.45 -2.00 20.00 -2.00 500.64 0.00e+00 8.906691e-01 2.497913e-03 3.349924e-02 -6.000000e+00 6.365453e-02 225.06 -2.00 3.53 -2.00 502.20 0.00e+00 8.135 0.010 489.00 513.00 1 9.9005e-01 1.9103e-04 1.2137e-02 -6.0000e+00 4.8681e-03 -1.3379e-02 4.8912e-05 1.0112e-03 -6.0000e+00 1.2663e-03 2.1068e-01 1.2864e-03 1.3072e-05 5.4761e-05 -6.0000e+00 3.4102e-04 3.4880e-03 1.6213e-04 10 0 0 10 0 0 -4.01 20.35 1.39 0.00349 0.01241 538 99 2 2 0 21.430 15.01 47.32 12.44 20.35 20.25 40.0 1026.62 -362 -330 6 205 473 681 642 644 513 455 341 33 -181 -142 54 36 -44 8 -31 81 342 354 373 347 283 47 -34 -286 -526 -159 56 -250 -255 -239 -270 -193 -50 -111 -173 -121 -24 48 119 217 184 164 22 -89 -304 -530 -443 -370 -348 -280 -307 -217 -3 188 296 328 354 251 182 149 92 34 -143 -296 -443 -371 -150 -212 -302 -389 -376 -287 -181 -267 -480 -512 -379 -422 -345 -210 -265 -259 -246 -96 174 181 244 324 224 216 301 159 -236 -481 -641 -496 -451 -569 -493 -609 -506 -202 -97 -102 7 5 72 259 482 627 671 704 538 307 345 443 278 267 260 104 112 341 260 196 235 -29 -190 96 30 -191 -106 4 -28 168 282 264 331 352 255 81 -46 -281 -349 -337 -310 -340 -318 6 202 477 699 645 648 513 464 343 33 -178 -139 53 36 -44 8 -31 84 352 365 386 361 295 49 -35 -289 -519 -159 56 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