File name: Pandora84s1_Rotterdam-Haven_20240607_L2Fit_fout2c5d20240501p1-8.txt File generation date: 20250501T133113.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 84 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora84_OF_v3d20231130.txt Instrument calibration file used: Pandora84s1_CF_v5d20240501.txt Level 1 file used: Pandora84s1_Rotterdam-Haven_20240607_L1_smca1c5d20240501p1-8.txt Full location name: De Slufter Visitor Centre Short location name: Rotterdam-Haven Country of location: Netherlands Location latitude [deg]: 51.9335 Location longitude [deg]: 3.9998 Location altitude [m]: 0 Local noon date: 20240607 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on OoB session 2 for fieldcal First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2233 305.3642 305.5050 305.6459 305.7867 305.9276 306.0684 306.2092 306.3500 306.4908 306.6316 306.7724 306.9131 307.0539 307.1946 307.3353 307.4760 307.6167 307.7574 307.8981 308.0388 308.1794 308.3201 308.4607 308.6014 308.7420 308.8826 309.0232 309.1638 309.3043 309.4449 309.5854 309.7260 309.8665 310.0070 310.1475 310.2880 310.4285 310.5690 310.7095 310.8499 310.9904 311.1308 311.2712 311.4116 311.5520 311.6924 311.8328 311.9731 312.1135 312.2538 312.3942 312.5345 312.6748 312.8151 312.9554 313.0957 313.2359 313.3762 313.5164 313.6567 313.7969 313.9371 314.0773 314.2175 314.3577 314.4978 314.6380 314.7781 314.9183 315.0584 315.1985 315.3386 315.4787 315.6188 315.7588 315.8989 316.0389 316.1790 316.3190 316.4590 316.5990 316.7390 316.8790 317.0189 317.1589 317.2988 317.4388 317.5787 317.7186 317.8585 317.9984 318.1383 318.2781 318.4180 318.5578 318.6977 318.8375 318.9773 319.1171 319.2569 319.3967 319.5364 319.6762 319.8159 319.9556 320.0954 320.2351 320.3748 320.5145 320.6541 320.7938 320.9335 321.0731 321.2127 321.3524 321.4920 321.6316 321.7711 321.9107 322.0503 322.1898 322.3294 322.4689 322.6084 322.7479 322.8874 323.0269 323.1664 323.3058 323.4453 323.5847 323.7242 323.8636 324.0030 324.1424 324.2818 324.4211 324.5605 324.6998 324.8392 324.9785 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240607T051848.2Z 8924.221391 109 1 54.53 2 75.80 71.02 77.85 60.68 0.00 1 0.00 1 0 17 2.997e-01 8.307e-03 5.595e-02 1.377e-03 6.719481e-01 7.280415e-04 8.232320e-03 -6.000000e+00 1.758320e-01 232.96 -2.00 3.84 -2.00 320.16 0.00e+00 2.000978e-03 2.539174e-04 1.399150e-03 -6.000000e+00 7.552616e-03 279.77 -2.00 20.00 -2.00 319.56 0.00e+00 3.988 0.001 302.00 328.00 3 2.2033e+00 2.1412e-03 5.6334e-02 -6.0000e+00 4.4256e-01 5.0715e-02 2.6521e-03 3.9216e-02 -6.0000e+00 4.7974e-01 -6.9821e-02 2.4880e-03 1.9945e-02 -6.0000e+00 2.8410e-01 2.3145e-02 1.2633e-03 6.1845e-03 -6.0000e+00 1.1757e-01 4.9951e-04 -2.5430e-04 3.7028e-05 7.2014e-05 -6.0000e+00 8.4447e-03 9.4670e-03 0.0000e+00 11 8 0 10 0 0 98.39 24.06 0.33 0.00947 0.00756 105 11 1 5 0 519.210 32.75 20.05 24.06 20.08 1.3 934.56 -66852 15212 -110153 -59515 -107707 -122340 -117147 -109267 -97573 -58408 -88444 -98708 -102079 -34771 -36557 -27828 -10584 -24101 -22240 -2827 -30963 -17277 -13823 -11246 -19552 -9970 -13266 -22994 -20136 -14542 -3653 -9347 1787 -11408 -13159 -8933 -2458 -6449 4191 -2789 -1526 2653 -3232 1763 -137 2056 3989 -769 -880 362 2393 1652 1684 2538 3344 1401 1086 1195 -1180 -485 1043 2659 3491 3252 1556 477 -275 515 1516 1690 1873 1697 974 860 154 -937 -281 -2047 -698 -1420 -857 -2103 -1962 -1115 -1083 45 631 670 835 863 186 -160 -676 -344 -607 -737 335 753 -63 -510 -886 -1103 -439 -438 -1256 -1426 -1036 -681 51 858 478 436 169 -334 -439 101 166 529 351 239 124 641 679 593 512 -94 346 1042 175 -107 -239 -318 -100 -242 -48 -122 427 447 241 -105 -386 -522 -541 -404 47 -1272 -400 -1099 -1479 -1495 -1482 -1337 -588 -1295 -1896 -2605 -584 -786 -654 -237 -689 -678 -75 -1119 -555 -460 -402 -822 -403 -561 -1044 -898 -687 -187 -604 119 -907 -1030 -689 -201 -664 478 -406 -223 399 -541 288 -23 350 684 -144 -175 77 562 437 490 797 1104 451 360 392 -386 -157 349 976 1447 1501 754 229 -133 241 787 1002 1121 1050 593 528 86 -481 -136 -1053 -405 -913 -637 -1675 -1695 -952 -990 43 629 641 838 825 167 -144 -599 -300 -602 -799 391 941 -85 -671 -1087 -1291 -505 -488 -1511 -1713 -1315 -927 73 1283 750 711 274 -522 -680 151 252 843 564 394 201 991 1060 889 774 -138 497 1513 277 -181 -421 -596 -188 -487 -99 -252 893 946 503 -217 -783 -1001 -1024 SS 20240607T052925.0Z 8924.228761 112 1 54.31 2 74.25 72.98 76.46 62.49 0.00 1 0.00 1 0 17 1.965e-01 7.544e-03 2.475e-02 1.088e-03 6.116384e-01 5.678366e-04 7.548980e-03 -6.000000e+00 1.152886e-01 232.96 -2.00 3.84 -2.00 319.70 0.00e+00 1.781589e-03 1.696986e-04 9.993977e-04 -6.000000e+00 4.951876e-03 279.78 -2.00 20.00 -2.00 319.07 0.00e+00 3.618 0.001 302.00 328.00 3 2.1911e+00 1.6263e-03 5.1053e-02 -6.0000e+00 2.9018e-01 2.6190e-02 1.9349e-03 3.5317e-02 -6.0000e+00 3.1455e-01 -4.2456e-02 1.6562e-03 1.7658e-02 -6.0000e+00 1.8628e-01 1.3300e-02 8.6025e-04 5.3414e-03 -6.0000e+00 7.7091e-02 7.6984e-04 -2.1966e-04 2.9848e-05 5.9809e-05 -6.0000e+00 5.5367e-03 9.2383e-03 0.0000e+00 12 9 1 12 1 1 98.05 24.09 0.30 0.00924 0.00759 112 12 1 5 0 480.490 32.75 20.07 24.09 20.51 1.3 938.31 -45518 -28022 -67249 -61197 -63785 -84797 -81764 -57328 -65871 -56319 -59495 -60369 -53262 -22266 -16679 -8928 -8973 -15836 -3893 -5199 -16429 -9726 -8738 -6951 -9973 -5766 -8138 -13427 -9603 -10013 -2637 -5587 -1339 -4374 -8739 -7221 -4306 -4325 1520 -1339 -1076 1151 -522 1502 1105 929 2002 330 485 516 1798 1831 1583 1681 2076 1847 1299 494 -746 -234 986 1922 3136 2774 1192 260 -303 366 1078 1562 1067 1314 1033 392 -87 -551 -851 -2311 -1085 -1496 -1016 -1960 -2150 -1358 -928 -11 421 502 778 870 540 -33 -614 -343 -411 -594 340 749 71 -512 -955 -1032 -454 -493 -1055 -1115 -1026 -592 187 602 630 409 186 -148 -201 -64 136 552 535 97 17 656 671 631 364 -122 203 888 179 83 -209 -374 -163 -90 -58 -105 428 366 23 -115 -389 -462 -412 -430 -256 -963 -792 -792 -1322 -1370 -864 -1223 -1028 -1193 -1422 -1475 -574 -504 -295 -332 -694 -164 -234 -847 -477 -453 -388 -619 -362 -528 -890 -613 -708 -206 -528 -138 -486 -978 -816 -534 -588 239 -257 -229 256 -124 357 268 231 502 87 134 140 538 609 578 664 796 739 535 204 -303 -94 412 884 1610 1463 654 140 -163 204 666 1024 765 910 702 268 -55 -335 -492 -1397 -684 -1045 -818 -1690 -1899 -1263 -921 -11 434 528 808 860 525 -30 -548 -320 -408 -645 401 945 96 -677 -1180 -1209 -521 -583 -1281 -1426 -1325 -817 268 914 998 645 301 -230 -307 -94 203 828 849 159 27 1016 1045 943 522 -177 287 1325 276 136 -361 -682 -300 -170 -112 -212 878 735 48 -226 -747 -874 -768 SS 20240607T053958.4Z 8924.236093 115 1 39.42 2 72.68 74.92 75.05 64.30 0.00 1 0.00 1 0 17 3.657e-01 1.254e-02 1.999e-01 4.730e-03 5.581205e-01 2.516770e-03 6.940696e-03 -6.000000e+00 2.150853e-01 232.96 -2.00 3.84 -2.00 320.10 0.00e+00 3.745159e-03 8.511339e-04 9.488008e-04 -6.000000e+00 1.006337e-02 279.78 -2.00 20.00 -2.00 319.49 0.00e+00 3.311 0.001 302.00 328.00 3 4.6739e+00 7.4202e-03 4.6775e-02 -6.0000e+00 5.4078e-01 5.4501e-02 9.0984e-03 3.2456e-02 -6.0000e+00 5.8685e-01 -2.7010e-03 8.2555e-03 1.6940e-02 -6.0000e+00 3.4705e-01 -9.6362e-03 4.2169e-03 6.1513e-03 -6.0000e+00 1.4599e-01 8.7909e-05 -8.7279e-04 1.3704e-04 6.7161e-05 -6.0000e+00 1.0458e-02 1.3772e-02 0.0000e+00 12 9 9 12 33 1 99.99 24.13 0.82 0.01377 0.00721 21 3 1 5 0 1791.330 32.75 19.99 24.13 20.82 1.3 940.11 900000 900000 -11125 152080 900000 35796 -126795 97713 -96885 294902 900000 -49243 -88845 51912 -35260 34427 15970 -37723 7258 78992 -48139 4583 -19045 5006 3481 -5059 -2254 -18969 -10900 -2547 19332 -8573 7832 -5738 -8600 -16053 9824 -21796 27897 -2768 -15714 15375 -5072 1660 -1116 3497 14583 3348 -1945 -821 8107 -2413 -917 -374 3095 -3257 1899 4565 2341 -2931 -2244 3105 4759 5377 1826 -1323 13 2324 1483 1212 1845 1378 2254 -621 1389 -684 7834 -4232 -4700 -2897 839 -89 -2933 -953 -1460 754 934 -853 1231 44 -646 343 -239 397 311 -1451 -2211 1392 22 651 -1041 -2025 -398 -115 -518 -2038 -844 -630 -100 1200 615 1147 373 -315 -544 -336 -526 124 694 -26 -36 1292 -113 -246 622 338 570 1451 -139 -373 465 -233 291 -66 74 168 118 99 164 -162 -486 -616 -375 900000 900000 -75 701 900000 165 -2656 450 -1908 1359 900000 -862 -2907 526 -1056 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