File name: Pandora84s1_Rotterdam-Haven_20240615_L2Fit_fwvt1c5d20240501p1-8.txt File generation date: 20250501T133631.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 84 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora84_OF_v3d20231130.txt Instrument calibration file used: Pandora84s1_CF_v5d20240501.txt Level 1 file used: Pandora84s1_Rotterdam-Haven_20240615_L1_smca1c5d20240501p1-8.txt Full location name: De Slufter Visitor Centre Short location name: Rotterdam-Haven Country of location: Netherlands Location latitude [deg]: 51.9335 Location longitude [deg]: 3.9998 Location altitude [m]: 0 Local noon date: 20240615 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on OoB session 2 for fieldcal First and last pixel inside fitting window: 1617 1766 Nominal wavelengths inside fitting window [nm]: 492.1185 492.2396 492.3607 492.4818 492.6029 492.7240 492.8450 492.9660 493.0871 493.2081 493.3290 493.4500 493.5709 493.6919 493.8128 493.9337 494.0545 494.1754 494.2962 494.4171 494.5379 494.6587 494.7795 494.9002 495.0210 495.1417 495.2624 495.3831 495.5038 495.6244 495.7451 495.8657 495.9863 496.1069 496.2275 496.3480 496.4686 496.5891 496.7096 496.8301 496.9506 497.0711 497.1915 497.3119 497.4323 497.5527 497.6731 497.7935 497.9138 498.0341 498.1544 498.2747 498.3950 498.5153 498.6355 498.7557 498.8759 498.9961 499.1163 499.2365 499.3566 499.4767 499.5968 499.7169 499.8370 499.9571 500.0771 500.1971 500.3171 500.4371 500.5571 500.6771 500.7970 500.9169 501.0368 501.1567 501.2766 501.3964 501.5163 501.6361 501.7559 501.8757 501.9955 502.1152 502.2350 502.3547 502.4744 502.5941 502.7138 502.8334 502.9530 503.0727 503.1923 503.3118 503.4314 503.5510 503.6705 503.7900 503.9095 504.0290 504.1485 504.2679 504.3874 504.5068 504.6262 504.7456 504.8649 504.9843 505.1036 505.2229 505.3422 505.4615 505.5808 505.7000 505.8193 505.9385 506.0577 506.1768 506.2960 506.4152 506.5343 506.6534 506.7725 506.8916 507.0106 507.1297 507.2487 507.3677 507.4867 507.6057 507.7246 507.8436 507.9625 508.0814 508.2003 508.3192 508.4381 508.5569 508.6757 508.7945 508.9133 509.0321 509.1508 509.2696 509.3883 509.5070 509.6257 509.7444 509.8630 509.9817 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240615T065831.9Z 8932.290647 158 1 3.63 2 60.58 89.01 130.41 8.66 0.00 1 0.00 1 0 15 2.360e-03 2.365e-03 8.904e-04 8.891e-04 1.809719e+03 5.458732e+01 1.307692e+02 -6.000000e+00 1.371698e+02 280.71 -2.00 20.00 -2.00 505.26 0.00e+00 4.269183e-04 2.476692e-05 2.473627e-05 -6.000000e+00 6.715954e-05 280.71 -2.00 20.00 -2.00 500.49 0.00e+00 2.491243e-01 1.805972e-02 1.477942e-02 -6.000000e+00 4.818068e-02 233.55 -2.00 3.84 -2.00 502.08 0.00e+00 2.026 0.000 489.00 513.00 1 4.7929e+00 1.3884e-03 3.2066e-03 -6.0000e+00 3.7050e-03 6.2638e-03 3.5157e-04 3.7873e-04 -6.0000e+00 9.4095e-04 1.1863e-02 3.0292e-04 1.0342e-04 1.6468e-05 -6.0000e+00 2.8225e-04 1.0833e-02 -4.6008e-05 12 1 1 12 1 1 98.10 23.98 0.91 0.01083 0.01293 9 16 1 4 0 361.610 32.75 19.86 23.98 18.18 1.4 920.31 -150 -49 -147 -260 158 320 227 320 351 184 126 -74 -159 -115 -354 -74 -2 177 -26 25 -6 273 420 569 375 62 133 73 -380 -271 -112 -166 65 139 -318 -184 -235 -141 -128 24 106 129 138 243 262 110 200 40 -27 -244 -435 -567 -504 -303 -107 -282 -372 -209 126 429 358 272 255 230 159 69 154 -55 -155 -166 -223 -102 -169 59 38 -311 -306 -289 -64 -99 -308 -446 -302 2 -99 -266 -189 -10 0 131 123 435 293 302 144 -27 -168 -243 -240 -313 -317 -184 -44 -314 -659 -249 -286 -56 113 94 14 177 90 236 388 416 302 274 49 185 231 313 342 358 178 52 59 280 105 69 -1 -196 -274 -207 152 133 -176 -84 -108 43 56 162 130 180 -4 -200 -162 -81 -8 -133 -147 -49 -148 -265 165 334 237 334 368 191 129 -76 -162 -116 -357 -75 -2 184 -27 26 -6 288 443 593 391 64 138 75 -388 -274 -113 -167 67 145 -332 -192 -243 -146 -131 25 109 133 142 252 272 115 205 41 -27 -243 -429 -560 -491 -300 -106 -284 -381 -215 129 437 367 275 258 234 160 68 153 -54 -153 -162 -219 -100 -166 58 37 -304 -299 -279 -61 -95 -298 -437 -293 2 -98 -261 -185 -10 0 130 123 432 293 300 144 -27 -164 -235 -229 -296 -303 -177 -43 -310 -657 -246 -280 -55 111 92 14 176 90 238 387 417 303 273 49 182 228 306 334 351 175 51 58 274 103 67 -1 -189 -261 -196 146 127 -172 -82 -106 42 56 161 129 179 -4 -198 -157 -78 -7 -128 SQ 20240615T071737.4Z 8932.303905 168 1 10.85 2 57.64 92.80 129.91 14.65 0.00 1 0.00 1 0 15 2.222e-03 2.225e-03 8.024e-05 8.015e-05 1.706242e+03 4.892794e+00 1.221506e+02 -6.000000e+00 1.291468e+02 280.71 -2.00 20.00 -2.00 505.26 0.00e+00 4.672563e-04 2.233949e-06 2.753069e-05 -6.000000e+00 6.323567e-05 280.71 -2.00 20.00 -2.00 500.52 0.00e+00 1.512332e-01 1.624367e-03 1.433196e-02 -6.000000e+00 4.538502e-02 233.55 -2.00 3.84 -2.00 502.10 0.00e+00 1.861 0.000 489.00 513.00 1 6.1669e-01 1.2487e-04 2.9918e-03 -6.0000e+00 3.4898e-03 5.4304e-04 3.1643e-05 3.5850e-04 -6.0000e+00 8.8678e-04 7.9642e-01 8.6033e-04 9.2963e-06 1.6776e-05 -6.0000e+00 2.6585e-04 1.1293e-02 -8.1961e-05 10 0 0 10 0 0 99.98 24.03 0.89 0.01129 0.01726 1959 206 1 4 0 3.030 32.75 19.93 24.03 18.80 1.3 924.97 -173 -118 -140 -119 72 313 359 346 306 276 176 0 -87 -87 -176 -164 -1 106 -41 -78 79 225 333 440 382 211 107 -103 -280 -231 -174 -89 193 66 -286 -301 -114 -34 -103 1 47 80 147 210 237 186 173 85 -148 -351 -449 -516 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-140 -161 -50 46 139 254 231 118 -27 -167 -218 -203 -114 -76 SQ 20240615T071748.3Z 8932.304031 168 2 10.72 2 57.61 92.84 129.90 14.70 0.00 1 0.00 1 0 15 2.095e-03 2.102e-03 2.440e-04 2.436e-04 1.731387e+03 1.492948e+01 1.236525e+02 -6.000000e+00 1.217755e+02 280.71 -2.00 20.00 -2.00 505.25 0.00e+00 4.342720e-04 6.777934e-06 2.573175e-05 -6.000000e+00 5.962624e-05 280.71 -2.00 20.00 -2.00 500.47 0.00e+00 1.626582e-01 4.947604e-03 1.438860e-02 -6.000000e+00 4.279587e-02 233.55 -2.00 3.84 -2.00 502.06 0.00e+00 1.860 0.000 489.00 513.00 1 2.7457e+00 3.8020e-04 2.9830e-03 -6.0000e+00 3.2907e-03 5.7987e-03 9.6432e-05 3.6109e-04 -6.0000e+00 8.3622e-04 9.4716e-02 8.7641e-04 2.8263e-05 1.6024e-05 -6.0000e+00 2.5068e-04 1.1427e-02 -8.5451e-05 10 0 0 10 0 0 99.99 24.03 0.88 0.01143 0.01751 1959 206 1 4 0 3.030 32.50 19.93 24.03 18.82 1.3 924.97 -94 -124 -130 -150 28 339 337 266 258 260 198 -10 -58 -92 -155 -132 27 85 -99 -72 103 207 314 376 395 179 85 -135 -267 -237 -106 -79 175 77 -296 -319 -72 -72 -88 20 56 86 147 198 223 151 154 80 -97 -320 -421 -437 -452 -170 -148 -259 -304 -204 5 204 319 315 210 178 114 128 6 -45 -77 -116 -59 -171 -110 29 -167 -336 -259 -135 -110 -90 -269 -355 -226 -68 -196 -263 -143 -52 -28 80 236 329 200 76 164 32 -159 -222 -214 -292 -289 -172 -82 -330 -499 -441 -244 25 163 147 30 32 90 162 329 438 389 331 219 166 157 267 394 164 78 146 172 151 206 153 -64 -92 -157 -89 81 91 -159 -161 -106 67 57 225 188 105 -9 -146 -223 -123 -98 -74 -91 -123 -133 -153 29 358 349 277 266 274 206 -10 -58 -92 -156 -135 28 88 -103 -76 108 218 330 396 417 188 88 -139 -275 -240 -107 -80 176 80 -312 -336 -75 -75 -91 21 57 88 153 207 234 158 159 81 -97 -322 -415 -425 -440 -168 -150 -260 -309 -208 5 208 326 322 215 182 115 127 6 -45 -76 -114 -57 -168 -110 28 -162 -334 -254 -131 -106 -86 -261 -348 -223 -66 -191 -257 -140 -51 -27 80 236 332 203 77 163 31 -152 -215 -204 -277 -276 -164 -80 -329 -488 -443 -242 25 161 146 29 31 90 163 332 443 394 333 219 163 152 258 379 158 76 141 167 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