File name: Pandora84s1_Rotterdam-Haven_20240627_L2Fit_fout2c5d20240501p1-8.txt File generation date: 20250501T133151.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 84 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora84_OF_v3d20231130.txt Instrument calibration file used: Pandora84s1_CF_v5d20240501.txt Level 1 file used: Pandora84s1_Rotterdam-Haven_20240627_L1_smca1c5d20240501p1-8.txt Full location name: De Slufter Visitor Centre Short location name: Rotterdam-Haven Country of location: Netherlands Location latitude [deg]: 51.9335 Location longitude [deg]: 3.9998 Location altitude [m]: 0 Local noon date: 20240627 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on OoB session 2 for fieldcal First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2233 305.3642 305.5050 305.6459 305.7867 305.9276 306.0684 306.2092 306.3500 306.4908 306.6316 306.7724 306.9131 307.0539 307.1946 307.3353 307.4760 307.6167 307.7574 307.8981 308.0388 308.1794 308.3201 308.4607 308.6014 308.7420 308.8826 309.0232 309.1638 309.3043 309.4449 309.5854 309.7260 309.8665 310.0070 310.1475 310.2880 310.4285 310.5690 310.7095 310.8499 310.9904 311.1308 311.2712 311.4116 311.5520 311.6924 311.8328 311.9731 312.1135 312.2538 312.3942 312.5345 312.6748 312.8151 312.9554 313.0957 313.2359 313.3762 313.5164 313.6567 313.7969 313.9371 314.0773 314.2175 314.3577 314.4978 314.6380 314.7781 314.9183 315.0584 315.1985 315.3386 315.4787 315.6188 315.7588 315.8989 316.0389 316.1790 316.3190 316.4590 316.5990 316.7390 316.8790 317.0189 317.1589 317.2988 317.4388 317.5787 317.7186 317.8585 317.9984 318.1383 318.2781 318.4180 318.5578 318.6977 318.8375 318.9773 319.1171 319.2569 319.3967 319.5364 319.6762 319.8159 319.9556 320.0954 320.2351 320.3748 320.5145 320.6541 320.7938 320.9335 321.0731 321.2127 321.3524 321.4920 321.6316 321.7711 321.9107 322.0503 322.1898 322.3294 322.4689 322.6084 322.7479 322.8874 323.0269 323.1664 323.3058 323.4453 323.5847 323.7242 323.8636 324.0030 324.1424 324.2818 324.4211 324.5605 324.6998 324.8392 324.9785 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240627T050245.4Z 8944.210247 191 1 54.11 2 78.33 66.97 62.02 191.00 0.00 1 0.00 1 0 17 4.833e-01 1.475e-02 1.998e-01 4.347e-03 6.438215e-01 2.376054e-03 8.316962e-03 -6.000000e+00 2.852870e-01 233.73 -2.00 3.84 -2.00 320.94 0.00e+00 7.212568e-03 1.053162e-03 3.812817e-03 -6.000000e+00 1.348851e-02 281.79 -2.00 20.00 -2.00 320.36 0.00e+00 4.783 0.002 302.00 328.00 3 3.4419e+00 7.6542e-03 6.2511e-02 -6.0000e+00 7.1818e-01 4.7749e-02 1.0224e-02 4.1140e-02 -6.0000e+00 7.7826e-01 -1.1572e-01 1.0225e-02 2.3992e-02 -6.0000e+00 4.6046e-01 3.9678e-02 4.9242e-03 9.3640e-03 -6.0000e+00 1.9325e-01 7.3211e-05 -2.7911e-04 1.2414e-04 1.3455e-04 -6.0000e+00 1.4087e-02 6.4729e-03 0.0000e+00 12 9 8 11 32 0 99.46 24.47 0.83 0.00647 0.00438 29 3 1 5 0 1865.660 33.00 20.00 24.47 24.91 1.2 971.88 900000 -226472 -127860 900000 900000 -200743 -168562 -100175 -190247 -99099 900000 -70979 -125429 -17169 -64907 116873 89248 -27349 162538 10159 -115469 -3252 -26560 -23526 -28192 -53189 3942 -64705 18586 -59068 66474 -30050 42976 -13035 -12980 15370 39893 -15761 49858 7986 -4998 32465 10093 9362 5253 14309 30314 16646 -8940 -5717 2654 -841 3659 1288 8118 -588 3011 4974 -217 878 -2144 5235 6572 8752 4079 1497 4820 3407 7474 1941 4090 -769 136 2041 698 1270 7893 -2451 1091 -2712 -3349 1452 -2839 -1000 -3811 347 -795 -2356 1145 1174 -1102 614 -232 -451 -1337 -1449 -1278 1210 -118 223 -2012 -826 -259 -570 -803 -2142 -1211 -505 -44 690 641 1352 -119 -645 12 764 -1428 1088 1510 -77 -275 1480 -350 796 902 -31 973 689 -1071 93 627 -483 1026 -563 -40 -321 185 49 167 -360 -676 -280 150 900000 -4797 -1083 900000 900000 -3169 -2077 -694 -3590 -801 900000 -547 -2174 -132 -1025 495 454 -498 689 146 -5967 -55 -596 -548 -728 -1848 78 -2522 323 -2527 986 -1400 1110 -618 -594 540 1234 -1015 2027 582 -462 2214 911 880 530 1364 2543 1671 -1223 -821 392 -144 654 255 1582 -130 653 1049 -47 190 -507 1286 1818 2636 1331 490 1525 1144 2697 770 1731 -353 60 922 291 477 2641 -946 465 -1295 -1874 877 -1945 -715 -3007 280 -680 -1920 977 957 -857 441 -163 -336 -1136 -1311 -1338 1403 -147 274 -2352 -863 -251 -572 -866 -2473 -1471 -606 -59 1008 1025 2076 -183 -1034 18 1112 -2169 1697 2486 -123 -434 2386 -556 1202 1308 -43 1339 1016 -1813 161 1177 -908 2001 -1188 -90 -707 415 111 376 -829 -1474 -577 304 SS 20240627T051342.9Z 8944.217858 194 1 54.44 2 76.76 68.99 62.33 193.97 0.00 1 0.00 1 0 17 2.486e-01 7.745e-03 1.327e-01 2.059e-03 5.925933e-01 1.097631e-03 7.285905e-03 -6.000000e+00 1.466388e-01 233.73 -2.00 3.84 -2.00 320.28 0.00e+00 1.281164e-03 3.963277e-04 1.494028e-03 -6.000000e+00 6.520145e-03 281.79 -2.00 20.00 -2.00 319.65 0.00e+00 4.257 0.002 302.00 328.00 3 2.8036e+00 3.3002e-03 5.5367e-02 -6.0000e+00 3.6923e-01 -3.5118e-02 4.1081e-03 3.5364e-02 -6.0000e+00 3.9987e-01 -2.7388e-02 3.7991e-03 1.7645e-02 -6.0000e+00 2.3677e-01 5.3102e-03 1.9124e-03 5.0388e-03 -6.0000e+00 9.8626e-02 2.4823e-04 -1.5131e-04 5.9063e-05 6.1648e-05 -6.0000e+00 7.0445e-03 4.9374e-03 0.0000e+00 11 8 0 10 0 0 77.55 24.51 0.43 0.00494 0.00380 72 8 1 5 0 755.950 33.00 20.01 24.51 25.44 1.2 976.49 82975 900000 -67071 87942 900000 -94063 -77622 -111609 -85593 -34009 -54365 -89860 -95133 -39533 -22334 3639 -2216 -10119 2661 -8758 -42967 -25642 -12478 -9331 -10839 -12398 -15720 -30678 -8777 -21004 -3951 -13288 2479 -13415 -6917 -9759 1855 -4648 5961 -5199 -4712 3622 1116 230 1706 -931 4473 2664 1896 -1899 1214 1856 1360 824 1750 1760 1443 2271 554 -743 393 2998 3587 3853 1745 -78 -80 787 1600 1399 1916 347 492 1233 -596 -345 1115 -1724 120 -1693 -861 -2510 -1668 -980 -1182 245 398 329 634 643 494 -312 -174 -139 -568 -336 -190 757 -43 -200 -1346 -803 -486 -471 -902 -1481 -1059 -513 90 614 754 785 72 -105 -425 82 118 367 444 -79 21 846 226 586 476 -283 351 817 -136 -12 64 -314 -4 -202 -22 -99 214 359 38 -77 -199 -455 -317 167 900000 -539 177 900000 -1001 -779 -1815 -1220 -314 -655 -1786 -2502 -754 -444 66 -48 -260 65 -255 -1812 -927 -423 -337 -431 -530 -704 -1546 -354 -1050 -197 -854 155 -1032 -482 -717 137 -443 630 -730 -735 557 185 39 292 -167 778 487 365 -409 283 435 351 232 516 542 458 712 173 -235 129 1061 1425 1684 799 -35 -36 366 754 757 1126 215 299 702 -315 -165 542 -884 62 -1056 -570 -1907 -1364 -847 -1021 222 379 321 613 593 425 -273 -147 -122 -523 -356 -215 900 -55 -250 -1588 -913 -518 -518 -1071 -1866 -1321 -683 122 924 1163 1254 114 -159 -647 120 176 574 696 -128 34 1308 360 896 697 -402 517 1196 -212 -21 114 -590 -8 -401 -45 -209 461 783 82 -160 -411 -899 -618 SS 20240627T052423.0Z 8944.225266 197 1 54.42 2 75.22 70.95 62.70 196.83 0.00 1 0.00 1 0 17 1.414e-01 7.141e-03 2.582e-02 1.213e-03 5.363072e-01 6.344943e-04 6.664017e-03 -6.000000e+00 8.321510e-02 233.73 -2.00 3.84 -2.00 319.66 0.00e+00 1.573547e-03 1.851851e-04 8.545579e-04 -6.000000e+00 3.592444e-03 281.79 -2.00 20.00 -2.00 318.97 0.00e+00 3.840 0.001 302.00 328.00 3 2.3011e+00 1.8241e-03 4.9766e-02 -6.0000e+00 2.0972e-01 -3.4105e-02 2.1595e-03 3.1243e-02 -6.0000e+00 2.2707e-01 -3.3012e-02 1.7806e-03 1.5433e-02 -6.0000e+00 1.3454e-01 1.0137e-02 9.2259e-04 4.5248e-03 -6.0000e+00 5.5743e-02 6.4550e-04 -2.0910e-04 3.4511e-05 5.2035e-05 -6.0000e+00 3.9828e-03 4.6663e-03 0.0000e+00 11 9 0 11 8 0 93.45 24.57 0.42 0.00467 0.00309 138 14 1 5 0 394.100 33.00 20.01 24.57 26.09 1.2 981.44 15328 -27871 -40162 -39829 -39739 -66006 -61504 -62121 -34751 -29416 -27004 -53081 -41870 -24311 -15848 -11262 -5768 -5401 -3005 -8473 -15399 -3310 -9396 -5955 -3857 -8589 -4552 -11870 -2546 -7916 700 -2923 577 -5100 -6862 -4336 -1916 -3455 821 -972 -511 759 1028 1223 909 797 1787 601 -266 -324 706 1704 1331 1558 1468 1830 742 836 -898 184 947 2548 2969 2978 1430 57 -513 453 724 1112 1092 800 378 616 -243 -514 -835 -1808 -846 -1649 -1224 -1859 -1876 -1426 -1030 -152 386 823 1006 771 226 -146 -562 -104 -339 -263 257 776 60 -328 -984 -924 -335 -455 -1262 -1450 -884 -669 -1 780 739 517 94 -15 -213 -73 76 339 360 -84 -11 631 412 559 676 -120 276 854 219 70 -59 -281 -189 -44 -186 -30 370 390 -32 -113 -278 -480 -422 112 -359 -618 -584 -541 -1179 -1157 -1345 -646 -557 -524 -1520 -1323 -803 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