File name: Pandora84s1_Rotterdam-Haven_20240817_L2Fit_fout2c5d20240501p1-8.txt File generation date: 20250501T140051.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 84 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora84_OF_v3d20231130.txt Instrument calibration file used: Pandora84s1_CF_v5d20240501.txt Level 1 file used: Pandora84s1_Rotterdam-Haven_20240817_L1_smca1c5d20240501p1-8.txt Full location name: De Slufter Visitor Centre Short location name: Rotterdam-Haven Country of location: Netherlands Location latitude [deg]: 51.9335 Location longitude [deg]: 3.9998 Location altitude [m]: 0 Local noon date: 20240817 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on OoB session 2 for fieldcal First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2233 305.3642 305.5050 305.6459 305.7867 305.9276 306.0684 306.2092 306.3500 306.4908 306.6316 306.7724 306.9131 307.0539 307.1946 307.3353 307.4760 307.6167 307.7574 307.8981 308.0388 308.1794 308.3201 308.4607 308.6014 308.7420 308.8826 309.0232 309.1638 309.3043 309.4449 309.5854 309.7260 309.8665 310.0070 310.1475 310.2880 310.4285 310.5690 310.7095 310.8499 310.9904 311.1308 311.2712 311.4116 311.5520 311.6924 311.8328 311.9731 312.1135 312.2538 312.3942 312.5345 312.6748 312.8151 312.9554 313.0957 313.2359 313.3762 313.5164 313.6567 313.7969 313.9371 314.0773 314.2175 314.3577 314.4978 314.6380 314.7781 314.9183 315.0584 315.1985 315.3386 315.4787 315.6188 315.7588 315.8989 316.0389 316.1790 316.3190 316.4590 316.5990 316.7390 316.8790 317.0189 317.1589 317.2988 317.4388 317.5787 317.7186 317.8585 317.9984 318.1383 318.2781 318.4180 318.5578 318.6977 318.8375 318.9773 319.1171 319.2569 319.3967 319.5364 319.6762 319.8159 319.9556 320.0954 320.2351 320.3748 320.5145 320.6541 320.7938 320.9335 321.0731 321.2127 321.3524 321.4920 321.6316 321.7711 321.9107 322.0503 322.1898 322.3294 322.4689 322.6084 322.7479 322.8874 323.0269 323.1664 323.3058 323.4453 323.5847 323.7242 323.8636 324.0030 324.1424 324.2818 324.4211 324.5605 324.6998 324.8392 324.9785 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240817T053421.8Z 8995.232196 101 1 54.52 2 81.69 79.10 130.32 276.00 0.00 1 0.00 1 0 17 5.883e-01 2.217e-02 2.958e-01 6.394e-03 7.884082e-01 3.677915e-03 9.472067e-03 -6.000000e+00 3.554734e-01 232.23 -2.00 3.84 -2.00 321.66 0.00e+00 1.176564e-03 2.025218e-03 3.586357e-03 -6.000000e+00 1.711129e-02 283.28 -2.00 20.00 -2.00 321.13 0.00e+00 6.493 0.006 302.00 328.00 3 2.2769e+00 1.3500e-02 8.2174e-02 -6.0000e+00 8.9625e-01 3.5009e-01 2.0116e-02 5.3937e-02 -6.0000e+00 9.7776e-01 -4.7051e-01 2.0506e-02 2.7592e-02 -6.0000e+00 5.7078e-01 1.8326e-01 9.2526e-03 7.5559e-03 -6.0000e+00 2.3921e-01 3.9343e-05 -1.1088e-03 1.8224e-04 1.1617e-04 -6.0000e+00 1.7990e-02 8.6991e-03 0.0000e+00 12 8 8 10 0 0 38.53 24.58 0.74 0.00870 0.00037 26 3 1 5 0 2096.450 33.00 20.01 24.58 24.60 1.3 969.07 900000 900000 -56146 900000 900000 -165501 900000 900000 -125072 -245326 900000 -109622 -124952 -153295 -138416 -31671 900000 -149439 11175 48947 -107127 101137 -77142 -115155 -60411 8493 -13594 -154960 27673 -113568 37444 -5532 113358 65529 900000 50139 900000 1148 89349 515 -30840 297010 65153 52638 56973 28696 95997 38993 36930 29017 49673 16385 14053 5768 28035 19673 11659 30195 19913 -15319 -2704 23061 10905 8800 13796 3419 14147 20041 7022 1621 12944 3460 2575 7832 4568 1532 27878 -8001 2264 1190 -2194 -6969 -3820 4000 -2290 1152 -1085 1464 2614 5674 -1671 -105 -699 1922 1219 -5361 -2366 -993 -2875 439 -3544 -826 -2708 -1731 -767 -2361 -1743 -1077 -1445 929 -496 589 1173 -287 -862 1034 -1430 913 1074 578 127 2619 -227 597 1285 274 470 2419 -1314 100 1252 -619 1906 -243 945 -467 -268 -414 125 -973 -219 -136 -629 900000 900000 -349 900000 900000 -1217 900000 900000 -849 -5968 900000 -868 -1484 -3122 -3054 -287 900000 -5495 89 305 -2909 629 -1658 -3974 -1299 96 -192 -8679 250 -4754 424 -116 834 816 900000 780 900000 39 1557 26 -2380 1848 2149 1998 2092 1429 2509 1893 1953 1824 2875 1489 1443 704 2913 2326 1531 3251 2292 -2469 -400 2942 1805 1676 2619 715 2703 3841 1730 484 3770 1143 837 2247 1222 381 5118 -2221 658 420 -943 -3276 -1908 1971 -1288 665 -669 898 1572 3162 -937 -60 -403 1054 774 -4276 -2144 -1018 -3228 471 -3689 -752 -2326 -1500 -705 -2330 -1824 -1218 -1684 1202 -725 903 1801 -435 -1258 1444 -2093 1373 1702 940 202 3900 -336 845 1743 365 618 3377 -2185 173 2351 -1272 4065 -527 2170 -1134 -665 -1038 308 -2293 -478 -301 -1376 SS 20240817T055758.3Z 8995.248591 107 1 54.14 2 78.10 83.66 133.71 280.95 0.00 1 0.00 1 0 25 2.018e-01 7.514e-03 4.955e-02 1.483e-03 6.078483e-01 7.782482e-04 7.504067e-03 -6.000000e+00 1.181252e-01 232.22 -2.00 3.84 -2.00 320.13 0.00e+00 1.313910e-03 2.706302e-04 1.161282e-03 -6.000000e+00 5.160211e-03 283.28 -2.00 20.00 -2.00 319.46 0.00e+00 4.697 0.002 302.00 328.00 3 1.7566e+00 2.3152e-03 5.8923e-02 -6.0000e+00 2.9643e-01 3.7360e-02 2.8685e-03 3.5632e-02 -6.0000e+00 3.2129e-01 -5.4948e-02 2.5972e-03 1.7704e-02 -6.0000e+00 1.9078e-01 1.5460e-02 1.3166e-03 5.0678e-03 -6.0000e+00 7.9361e-02 4.4728e-04 -3.9332e-04 4.1230e-05 5.9585e-05 -6.0000e+00 5.6852e-03 7.4554e-03 0.0000e+00 11 8 0 10 0 0 54.93 24.70 0.39 0.00746 0.00450 117 12 1 5 0 462.630 33.00 20.01 24.70 26.10 1.2 979.74 -22081 -60650 -69810 -58505 -47362 -78571 -66633 -59427 -45396 -61219 -59075 -75459 -63694 -34512 -38941 -17953 13636 -30699 -8085 -10928 -15368 -11577 -12951 -16523 -10520 -13552 -8166 -27601 -15186 -18022 -2091 -4699 -1073 -4998 -16077 -12464 -2428 -2748 1456 -4255 -2771 895 1500 1973 311 523 3460 1428 372 432 2592 1165 2226 2489 1648 3108 977 1443 -323 -702 -821 1920 2502 2880 1504 13 -391 1907 1455 1796 1479 1118 551 1010 -477 -1219 -263 -2856 -1068 -1688 -1347 -1948 -2217 -977 -813 -26 710 1078 1028 863 641 349 -279 -381 -300 -516 420 660 61 -367 -1151 -939 -754 -826 -942 -1432 -1216 -627 192 679 593 639 316 21 -317 42 45 304 288 -58 43 604 506 391 588 -376 287 1060 159 211 -28 -320 -165 -178 -98 -167 293 281 52 -89 -287 -360 -260 -115 -535 -717 -516 -349 -807 -675 -645 -486 -832 -837 -1462 -1382 -709 -1036 -457 284 -1101 -250 -368 -556 -410 -498 -724 -470 -661 -381 -1517 -736 -988 -116 -315 -79 -401 -1393 -1067 -213 -291 182 -669 -480 145 254 340 55 95 624 272 75 94 615 312 647 783 553 1073 354 517 -115 -250 -308 712 1043 1321 718 6 -184 916 785 1020 919 722 351 604 -264 -665 -135 -1544 -592 -1110 -951 -1563 -1807 -836 -746 -26 672 1040 984 842 584 299 -233 -334 -295 -550 479 802 79 -470 -1463 -1081 -864 -920 -1128 -1817 -1542 -848 267 994 947 1007 519 33 -472 64 70 467 468 -93 71 964 783 582 881 -548 408 1589 256 359 -49 -599 -310 -355 -199 -355 610 593 108 -186 -568 -707 -504 SS 20240817T060858.9Z 8995.256238 110 1 54.46 2 76.41 85.79 135.27 283.38 0.00 1 0.00 1 0 25 1.341e-01 6.984e-03 1.826e-02 1.006e-03 5.434475e-01 5.234613e-04 6.770202e-03 -6.000000e+00 7.852552e-02 232.22 -2.00 3.84 -2.00 319.55 0.00e+00 1.649101e-03 1.497465e-04 6.658272e-04 -6.000000e+00 3.430076e-03 283.28 -2.00 20.00 -2.00 318.85 0.00e+00 4.153 0.001 302.00 328.00 3 1.6380e+00 1.4951e-03 5.2165e-02 -6.0000e+00 1.9705e-01 2.1742e-02 1.7643e-03 3.1358e-02 -6.0000e+00 2.1357e-01 -3.5636e-02 1.4265e-03 1.5481e-02 -6.0000e+00 1.2682e-01 9.4848e-03 7.4300e-04 4.5847e-03 -6.0000e+00 5.2762e-02 9.0049e-04 -3.4611e-04 2.8417e-05 5.0107e-05 -6.0000e+00 3.7788e-03 6.6514e-03 0.0000e+00 11 8 0 10 0 0 12.96 24.80 0.26 0.00665 0.00405 177 19 1 5 0 307.640 33.00 20.01 24.80 26.51 1.2 983.06 -28223 -39229 -35820 -45125 -43264 -63243 -43609 -37490 -36732 -41778 -36784 -47501 -33960 -21866 -19519 -12601 3323 -12633 -3926 -1634 -3217 -692 -6130 -7185 -4530 -3518 -2860 -11084 -8994 -4268 -56 -3312 -298 -2512 -7722 -5373 -2454 -3048 1200 -325 -317 -158 193 1277 1358 837 1157 -48 -400 244 1465 1626 2078 1801 1633 1630 768 769 -275 -384 974 1862 2345 2311 1067 -102 -460 333 843 1021 1356 708 743 788 -204 -812 -993 -2094 -1115 -1314 -1284 -1787 -2184 -1446 -765 -382 -12 795 1122 1002 733 127 -370 -288 -144 -299 405 678 88 -494 -902 -886 -541 -437 -1149 -1319 -1139 -582 327 762 725 479 260 -27 -239 126 159 223 209 1 -17 335 335 570 412 -192 310 899 386 124 -96 -231 -129 12 -96 -164 196 279 105 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