File name: Pandora84s1_Rotterdam-Haven_20240919_L2Fit_fout2c5d20240501p1-8.txt File generation date: 20250501T141349.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 84 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora84_OF_v3d20231130.txt Instrument calibration file used: Pandora84s1_CF_v5d20240501.txt Level 1 file used: Pandora84s1_Rotterdam-Haven_20240919_L1_smca1c5d20240501p1-8.txt Full location name: De Slufter Visitor Centre Short location name: Rotterdam-Haven Country of location: Netherlands Location latitude [deg]: 51.9335 Location longitude [deg]: 3.9998 Location altitude [m]: 0 Local noon date: 20240919 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on OoB session 2 for fieldcal First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2233 305.3642 305.5050 305.6459 305.7867 305.9276 306.0684 306.2092 306.3500 306.4908 306.6316 306.7724 306.9131 307.0539 307.1946 307.3353 307.4760 307.6167 307.7574 307.8981 308.0388 308.1794 308.3201 308.4607 308.6014 308.7420 308.8826 309.0232 309.1638 309.3043 309.4449 309.5854 309.7260 309.8665 310.0070 310.1475 310.2880 310.4285 310.5690 310.7095 310.8499 310.9904 311.1308 311.2712 311.4116 311.5520 311.6924 311.8328 311.9731 312.1135 312.2538 312.3942 312.5345 312.6748 312.8151 312.9554 313.0957 313.2359 313.3762 313.5164 313.6567 313.7969 313.9371 314.0773 314.2175 314.3577 314.4978 314.6380 314.7781 314.9183 315.0584 315.1985 315.3386 315.4787 315.6188 315.7588 315.8989 316.0389 316.1790 316.3190 316.4590 316.5990 316.7390 316.8790 317.0189 317.1589 317.2988 317.4388 317.5787 317.7186 317.8585 317.9984 318.1383 318.2781 318.4180 318.5578 318.6977 318.8375 318.9773 319.1171 319.2569 319.3967 319.5364 319.6762 319.8159 319.9556 320.0954 320.2351 320.3748 320.5145 320.6541 320.7938 320.9335 321.0731 321.2127 321.3524 321.4920 321.6316 321.7711 321.9107 322.0503 322.1898 322.3294 322.4689 322.6084 322.7479 322.8874 323.0269 323.1664 323.3058 323.4453 323.5847 323.7242 323.8636 324.0030 324.1424 324.2818 324.4211 324.5605 324.6998 324.8392 324.9785 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240919T065022.2Z 9028.284979 253 1 54.15 2 77.91 103.72 88.27 276.04 0.00 1 0.00 1 0 17 2.376e-01 8.750e-03 7.923e-02 2.193e-03 5.755122e-01 1.137160e-03 7.136120e-03 -6.000000e+00 1.369084e-01 228.08 -2.00 3.84 -2.00 320.29 0.00e+00 2.032331e-03 4.120457e-04 1.025415e-03 -6.000000e+00 5.988824e-03 279.84 -2.00 20.00 -2.00 319.69 0.00e+00 4.631 0.002 302.00 328.00 3 2.6019e+00 3.3919e-03 5.6678e-02 -6.0000e+00 3.4050e-01 -7.7052e-03 4.2285e-03 3.3081e-02 -6.0000e+00 3.7050e-01 -4.7829e-02 3.9347e-03 1.6894e-02 -6.0000e+00 2.2031e-01 1.2138e-02 1.9888e-03 5.2765e-03 -6.0000e+00 9.2092e-02 2.2168e-04 -4.6754e-04 6.2372e-05 6.4142e-05 -6.0000e+00 6.6863e-03 1.0500e-02 0.0000e+00 11 8 0 10 0 0 90.80 24.55 0.50 0.01050 0.00699 69 7 1 5 0 784.690 33.00 20.00 24.55 22.89 1.4 954.09 -63392 -12933 -14511 -58199 -55503 -139883 -87228 -49326 -78490 -80395 11400 -108766 -24991 -23615 -51234 -7330 25831 -60086 -11109 4357 -25985 -10447 -11325 -9820 -14140 -9762 -5391 -21145 -21763 -20030 -3971 1225 3510 -5745 -14939 -7876 8936 -4494 5690 822 -5234 6912 322 1003 1621 -1090 7515 2614 2794 -1396 4059 3307 751 188 2069 1717 -1119 614 -85 -716 -1078 733 3302 2478 1428 980 1072 2128 1255 1440 1757 -324 2054 1460 -729 -70 1329 -2194 -158 -1718 -1111 -1766 -2469 -741 -948 595 627 652 861 748 910 -319 -315 -616 276 -438 339 95 -92 -165 -1368 -1078 -553 -677 -1092 -1890 -927 -732 -345 593 521 486 68 -247 -66 395 232 480 148 -109 -284 691 757 627 544 -58 291 1655 74 -294 349 -266 237 -198 118 -533 408 89 -5 -155 -325 -246 -393 -481 -68 -82 -487 -463 -2502 -1119 -496 -1192 -1341 80 -2954 -369 -434 -1534 -166 470 -2840 -347 123 -1017 -355 -414 -386 -626 -436 -233 -1036 -1070 -1062 -211 73 231 -432 -1189 -598 648 -448 628 113 -848 1061 55 175 286 -202 1305 491 547 -307 939 778 198 54 615 533 -366 196 -27 -226 -360 267 1323 1102 656 439 475 972 592 774 1026 -200 1214 818 -381 -36 636 -1118 -82 -1061 -789 -1314 -2004 -629 -866 529 584 622 813 675 821 -273 -261 -535 267 -455 375 119 -114 -215 -1678 -1198 -617 -782 -1271 -2340 -1206 -956 -492 874 834 805 112 -387 -98 597 336 731 240 -183 -473 1105 1171 935 828 -85 420 2502 120 -499 637 -489 455 -384 244 -1157 854 190 -11 -330 -657 -499 -790 SS 20240919T070208.1Z 9028.293149 256 1 54.15 2 76.16 106.14 89.97 278.31 0.00 1 0.00 1 0 17 1.177e-01 6.727e-03 2.456e-02 1.360e-03 5.138466e-01 6.968456e-04 6.442275e-03 -6.000000e+00 6.785113e-02 228.08 -2.00 3.84 -2.00 319.61 0.00e+00 1.802805e-03 2.024377e-04 6.119562e-04 -6.000000e+00 2.967627e-03 279.84 -2.00 20.00 -2.00 318.97 0.00e+00 4.084 0.001 302.00 328.00 3 2.3391e+00 1.9842e-03 5.0071e-02 -6.0000e+00 1.6875e-01 -2.2950e-02 2.3483e-03 2.9140e-02 -6.0000e+00 1.8361e-01 -2.6585e-02 1.9475e-03 1.4600e-02 -6.0000e+00 1.0918e-01 5.6391e-03 1.0172e-03 4.5306e-03 -6.0000e+00 4.5645e-02 5.1511e-04 -2.9842e-04 3.9056e-05 5.1772e-05 -6.0000e+00 3.3133e-03 9.6942e-03 0.0000e+00 11 8 0 10 0 0 80.57 24.60 0.36 0.00969 0.00745 114 12 1 5 0 474.920 33.00 20.00 24.60 23.22 1.4 957.06 -43832 -27694 -20231 -25160 -57813 -59037 -38494 -35035 -24789 -31086 -28343 -41383 -20061 -6055 -5711 -205 323 -18363 -8470 3337 -5569 -1672 -2043 -3058 -6838 -5847 -3236 -7386 -9308 -5557 -203 -1342 -486 -4772 -9169 -7144 -3557 -3945 1438 -1107 -3052 931 502 715 729 308 2726 392 1398 -304 1347 1280 1320 1061 1306 1682 305 1002 -297 -325 585 1371 2825 2217 475 -14 520 1001 722 1429 1664 528 1010 685 -581 -378 319 -1734 -1124 -1044 -1147 -1730 -1879 -1235 -1038 -58 121 811 842 736 637 -16 -239 -390 -50 -554 414 423 51 -230 -892 -1097 -267 -332 -1142 -1445 -991 -571 233 628 524 466 289 -159 -192 44 -47 363 289 -43 -168 504 494 501 472 -159 482 1227 256 30 -162 -208 64 -30 -62 -119 222 286 118 -260 -364 -412 -386 -674 -411 -292 -364 -1073 -1119 -653 -655 -470 -672 -624 -1180 -569 -185 -212 -8 14 -1079 -483 178 -332 -97 -126 -207 -515 -458 -248 -569 -722 -448 -18 -139 -56 -595 -1146 -894 -484 -645 247 -230 -715 223 126 183 189 82 715 107 392 -92 443 465 477 414 533 709 133 432 -127 -139 261 670 1407 1212 268 -8 276 546 439 913 1154 383 717 461 -390 -229 180 -1018 -734 -737 -932 -1481 -1738 -1129 -1017 -60 123 841 866 768 619 -15 -224 -354 -50 -602 480 522 66 -295 -1132 -1272 -308 -398 -1401 -1875 -1284 -787 329 926 834 761 463 -243 -289 64 -69 562 453 -70 -273 791 751 768 694 -226 701 1775 395 48 -284 -366 118 -56 -122 -236 449 588 242 -512 -711 -769 -713 SS 20240919T071300.5Z 9028.300700 259 1 54.41 2 74.56 108.42 91.52 280.40 0.00 1 0.00 1 0 17 8.061e-02 6.544e-03 1.085e-02 9.737e-04 4.678707e-01 4.955966e-04 5.909825e-03 -6.000000e+00 4.646432e-02 228.08 -2.00 3.84 -2.00 319.08 0.00e+00 1.425914e-03 1.209561e-04 3.913619e-04 -6.000000e+00 2.032023e-03 279.84 -2.00 20.00 -2.00 318.41 0.00e+00 3.687 0.001 302.00 328.00 3 2.1589e+00 1.3745e-03 4.5289e-02 -6.0000e+00 1.1556e-01 -2.8798e-02 1.5903e-03 2.6400e-02 -6.0000e+00 1.2573e-01 -2.0916e-02 1.1928e-03 1.3066e-02 -6.0000e+00 7.4764e-02 5.5508e-03 6.2665e-04 3.9141e-03 -6.0000e+00 3.1260e-02 9.4607e-04 -2.9387e-04 2.8008e-05 4.3007e-05 -6.0000e+00 2.2687e-03 9.0576e-03 0.0000e+00 11 8 0 10 0 0 78.11 24.65 0.34 0.00906 0.00685 170 18 1 5 0 320.010 33.00 20.01 24.65 23.66 1.4 959.80 -32343 -26406 -24442 -23498 -34909 -32360 -29260 -22037 -13864 -20231 -19625 -27768 -13715 -4649 -8917 -2955 1531 -9245 -3298 1369 -1463 1259 -719 488 -3371 -1332 -1352 -4562 -4353 -1711 -416 -145 197 -2062 -5621 -3675 -1275 -1611 244 -157 -878 -37 251 1186 867 311 1016 583 -6 426 1518 1032 1226 874 1460 1301 -62 531 -220 202 906 1412 2397 2017 283 -176 -32 319 1059 974 1227 668 859 227 -569 -573 -762 -1578 -1086 -1332 -1307 -1869 -2109 -1400 -1015 -151 230 601 859 655 641 59 -224 -103 56 -499 397 634 131 -288 -874 -969 -376 -370 -972 -1188 -936 -614 181 585 537 469 218 -91 -264 102 24 315 284 -89 23 345 551 582 413 12 322 961 350 99 59 -197 -79 -58 -83 -182 319 313 1 -104 -366 -460 -490 -823 -712 -673 -607 -931 -845 -811 -647 -420 -695 -695 -1194 -621 -235 -566 -202 109 -796 -285 119 -133 112 -69 50 -384 -156 -159 -529 -493 -201 -55 -22 30 -331 -894 -584 -222 -336 61 -42 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