File name: Pandora147s1_SWDetroitMI_20230912_L2Fit_fwvt1c1d20210609p1-8.txt File generation date: 20230914T154035.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v1d20210609.txt Level 1 file used: Pandora147s1_SWDetroitMI_20230912_L1_smca1c1d20210609p1-8.txt Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20230912 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1656 1805 Nominal wavelengths inside fitting window [nm]: 492.0314 492.1525 492.2736 492.3946 492.5157 492.6367 492.7577 492.8788 492.9997 493.1207 493.2417 493.3626 493.4836 493.6045 493.7254 493.8462 493.9671 494.0879 494.2088 494.3296 494.4504 494.5711 494.6919 494.8127 494.9334 495.0541 495.1748 495.2955 495.4161 495.5368 495.6574 495.7780 495.8986 496.0192 496.1398 496.2603 496.3808 496.5014 496.6218 496.7423 496.8628 496.9832 497.1037 497.2241 497.3445 497.4649 497.5852 497.7056 497.8259 497.9462 498.0665 498.1868 498.3071 498.4273 498.5476 498.6678 498.7880 498.9082 499.0283 499.1485 499.2686 499.3887 499.5088 499.6289 499.7490 499.8690 499.9891 500.1091 500.2291 500.3491 500.4690 500.5890 500.7089 500.8289 500.9488 501.0686 501.1885 501.3084 501.4282 501.5480 501.6678 501.7876 501.9074 502.0271 502.1469 502.2666 502.3863 502.5060 502.6256 502.7453 502.8649 502.9845 503.1041 503.2237 503.3433 503.4629 503.5824 503.7019 503.8214 503.9409 504.0604 504.1798 504.2993 504.4187 504.5381 504.6575 504.7768 504.8962 505.0155 505.1348 505.2542 505.3734 505.4927 505.6120 505.7312 505.8504 505.9696 506.0888 506.2080 506.3271 506.4463 506.5654 506.6845 506.8036 506.9226 507.0417 507.1607 507.2797 507.3988 507.5177 507.6367 507.7557 507.8746 507.9935 508.1124 508.2313 508.3502 508.4690 508.5879 508.7067 508.8255 508.9443 509.0630 509.1818 509.3005 509.4192 509.5379 509.6566 509.7753 509.8939 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230912T143827.5Z 8655.610040 231 1 48.79 2 53.74 123.17 29.32 140.58 0.00 1 0.00 1 0 15 3.270e-03 3.265e-03 5.272e-04 5.238e-04 2.648310e+03 3.147668e+01 1.908606e+02 -6.000000e+00 1.782983e+02 286.24 -2.00 20.00 -2.00 505.17 0.00e+00 5.365645e-04 1.430666e-05 3.467488e-05 -6.000000e+00 9.161219e-05 286.24 -2.00 20.00 -2.00 500.12 0.00e+00 3.696330e-02 1.039932e-02 1.742835e-02 -6.000000e+00 6.448526e-02 229.36 -2.00 3.54 -2.00 501.74 0.00e+00 1.686 0.000 489.00 513.00 1 5.2684e+00 7.9368e-04 2.9107e-03 -6.0000e+00 4.9276e-03 1.8973e-02 2.1144e-04 4.3038e-04 -6.0000e+00 1.3112e-03 7.8741e-03 4.4060e-04 4.5913e-05 2.5234e-05 -6.0000e+00 2.9616e-04 -2.6814e-02 -1.1634e-04 10 0 0 10 0 0 99.98 16.10 0.84 -0.02681 -0.02376 285 66 1 4 0 171.170 22.29 15.00 16.10 24.59 30.6 975.95 900000 -798 -440 -185 320 364 607 564 589 501 242 70 -103 -277 -389 -433 -276 -48 48 220 161 165 107 196 163 336 267 276 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-316 -77 151 331 363 485 512 473 507 382 178 153 129 70 114 370 198 180 397 177 112 47 27 -331 -286 -368 -150 -203 151 97 126 122 151 219 304 166 -8 -131 -322 -495 SQ 20230912T150633.7Z 8655.629557 249 1 13.48 2 49.58 130.37 26.61 153.37 0.00 1 0.00 1 0 15 3.002e-03 2.979e-03 6.536e-04 6.516e-04 2.278154e+03 3.849313e+01 1.691962e+02 -6.000000e+00 1.637000e+02 286.24 -2.00 20.00 -2.00 505.22 0.00e+00 5.429684e-04 1.786223e-05 3.298778e-05 -6.000000e+00 8.411336e-05 286.24 -2.00 20.00 -2.00 500.28 0.00e+00 3.107684e-02 1.288788e-02 1.484727e-02 -6.000000e+00 5.920788e-02 229.36 -2.00 3.54 -2.00 501.89 0.00e+00 1.539 0.000 489.00 513.00 1 4.9581e+00 9.8536e-04 2.6259e-03 -6.0000e+00 4.5243e-03 1.8697e-02 2.6138e-04 3.7483e-04 -6.0000e+00 1.2039e-03 1.0972e-02 4.7152e-04 5.7226e-05 2.2352e-05 -6.0000e+00 2.7192e-04 -2.7368e-02 -1.1507e-04 12 1 1 12 1 1 99.99 16.11 0.87 -0.02737 -0.02410 51 44 1 4 0 259.170 22.29 15.00 16.11 25.47 30.6 982.59 900000 -589 -513 -33 120 327 405 643 495 412 223 79 -177 -205 -339 -293 -271 -143 1 125 266 172 203 115 293 238 305 131 -159 -231 -493 -627 -211 -117 87 308 242 110 -92 -115 -85 -121 -14 173 169 369 294 388 73 -53 -406 -630 -730 -636 -483 -128 105 35 200 163 176 157 298 323 280 85 207 103 -262 -273 -337 -365 -410 -86 -34 68 78 -229 -183 -414 -425 -406 -374 -142 -236 -251 15 -25 -40 -143 75 293 206 190 459 434 112 139 -339 -393 -718 -678 -330 -278 -24 10 33 -172 -306 -338 -266 -110 88 251 500 472 550 370 400 338 234 69 39 21 90 293 174 254 329 170 108 135 -29 -345 -286 -176 -220 -13 87 110 161 204 129 165 343 233 -33 -294 -506 -483 900000 -576 -514 -34 124 343 434 698 540 447 239 83 -184 -210 -343 -296 -276 -149 1 136 281 182 214 122 311 253 323 139 -171 -240 -497 -629 -213 -122 90 327 256 115 -95 -121 -89 -123 -14 180 177 389 310 404 75 -56 -412 -621 -705 -611 -472 -129 105 35 204 166 179 159 304 331 286 86 205 105 -263 -270 -329 -355 -403 -85 -34 66 77 -224 -175 -396 -406 -391 -364 -139 -233 -242 14 -25 -39 -139 73 287 206 192 461 428 108 132 -325 -368 -665 -632 -315 -267 -24 10 33 -168 -295 -325 -259 -109 88 245 491 466 545 369 397 332 226 68 37 20 88 286 171 248 319 165 105 129 -27 -320 -263 -163 -207 -13 83 106 155 198 126 161 336 227 -32 -276 -481 -453 SQ 20230912T151626.9Z 8655.636423 253 1 6.07 2 48.21 133.10 25.90 158.35 0.00 1 0.00 1 0 15 3.752e-03 3.735e-03 1.952e-03 1.946e-03 2.280490e+03 1.149012e+02 1.559901e+02 -6.000000e+00 2.046051e+02 286.24 -2.00 20.00 -2.00 505.22 0.00e+00 5.262800e-04 5.329634e-05 3.232699e-05 -6.000000e+00 1.050226e-04 286.24 -2.00 20.00 -2.00 500.25 0.00e+00 5.610511e-02 3.834679e-02 1.740756e-02 -6.000000e+00 7.362283e-02 229.36 -2.00 3.54 -2.00 501.87 0.00e+00 1.498 0.000 489.00 513.00 1 6.1691e+00 2.9336e-03 2.6675e-03 -6.0000e+00 5.6337e-03 1.7711e-02 7.7324e-04 4.0373e-04 -6.0000e+00 1.4854e-03 3.2812e-03 -3.6895e-03 1.7056e-04 2.0778e-05 -6.0000e+00 3.3910e-04 -3.5797e-02 1.4910e-04 12 1 1 12 1 1 89.45 16.10 0.92 -0.03580 -0.06139 3 7 1 4 0 1516.360 22.19 15.00 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