File name: Pandora147s1_SWDetroitMI_20231019_L2Fit_fout2c1d20210609p1-8.txt File generation date: 20231022T172102.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v1d20210609.txt Level 1 file used: Pandora147s1_SWDetroitMI_20231019_L1_smca1c1d20210609p1-8.txt Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20231019 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 235 377 Nominal wavelengths inside fitting window [nm]: 305.0003 305.1412 305.2821 305.4229 305.5638 305.7046 305.8454 305.9863 306.1271 306.2679 306.4086 306.5494 306.6902 306.8309 306.9716 307.1124 307.2531 307.3938 307.5345 307.6752 307.8158 307.9565 308.0971 308.2378 308.3784 308.5190 308.6596 308.8002 308.9408 309.0813 309.2219 309.3624 309.5029 309.6435 309.7840 309.9245 310.0649 310.2054 310.3459 310.4863 310.6268 310.7672 310.9076 311.0480 311.1884 311.3288 311.4692 311.6095 311.7499 311.8902 312.0305 312.1708 312.3111 312.4514 312.5917 312.7320 312.8722 313.0124 313.1527 313.2929 313.4331 313.5733 313.7135 313.8537 313.9938 314.1340 314.2741 314.4142 314.5543 314.6944 314.8345 314.9746 315.1147 315.2547 315.3948 315.5348 315.6748 315.8149 315.9549 316.0948 316.2348 316.3748 316.5147 316.6547 316.7946 316.9345 317.0744 317.2143 317.3542 317.4941 317.6339 317.7738 317.9136 318.0534 318.1932 318.3330 318.4728 318.6126 318.7524 318.8921 319.0319 319.1716 319.3113 319.4510 319.5907 319.7304 319.8701 320.0097 320.1494 320.2890 320.4287 320.5683 320.7079 320.8475 320.9870 321.1266 321.2662 321.4057 321.5452 321.6848 321.8243 321.9638 322.1033 322.2427 322.3822 322.5216 322.6611 322.8005 322.9399 323.0793 323.2187 323.3581 323.4975 323.6368 323.7762 323.9155 324.0548 324.1941 324.3334 324.4727 324.6120 324.7512 324.8905 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231019T130027.6Z 8692.541987 72 1 50.29 2 78.49 115.15 132.11 92.08 0.00 1 0.00 1 0 25 4.067e-01 2.223e-02 4.077e-01 2.380e-02 5.892908e-01 1.306456e-02 7.018730e-03 -6.000000e+00 2.342101e-01 225.29 -2.00 3.54 -2.00 321.13 0.00e+00 5.221400e-03 5.682342e-03 9.528929e-04 -6.000000e+00 1.067146e-02 281.78 -2.00 20.00 -2.00 320.59 0.00e+00 4.847 0.002 302.00 328.00 3 4.0478e+00 4.2858e-02 5.6684e-02 -6.0000e+00 5.8187e-01 2.1261e-01 5.4100e-02 3.1683e-02 -6.0000e+00 6.3232e-01 -3.5054e-01 4.8461e-02 1.7038e-02 -6.0000e+00 3.7191e-01 1.6291e-01 2.4048e-02 6.6350e-03 -6.0000e+00 1.6217e-01 4.2259e-05 -2.3304e-03 6.9222e-04 8.2676e-05 -6.0000e+00 1.0970e-02 -3.9627e-02 -1.3109e-04 12 8 8 10 0 0 99.91 16.16 0.40 -0.03963 -0.05714 15 3 1 5 0 3351.990 22.29 14.99 16.16 18.97 30.4 940.56 900000 -138058 900000 -16894 -83466 14656 900000 196475 900000 900000 -90813 11966 -85181 900000 -15296 -49883 -51782 -98241 -34744 198471 63199 91739 74143 1002 -97104 52425 135309 -17235 3012 108434 57201 44149 -24724 21551 -33184 -4422 -30140 34039 -21679 4638 -20918 16546 39937 38940 22448 19474 30698 3829 23304 -4013 -5424 2773 8910 4478 17157 12270 6984 6121 15044 -5431 -1222 -5637 747 13361 4572 10024 1545 4362 4690 3776 5189 4369 8007 3846 -4859 4307 -403 -4336 -6459 -8931 -4979 -4133 3862 -1162 -1897 -2697 -64 -3163 1651 -156 441 968 5844 4097 1169 -5427 -2709 -3988 3585 -1051 760 -1282 -3697 -1981 -1832 -2821 341 -1101 -1035 1491 -1508 2313 689 1380 -559 -1575 -122 1297 -2130 1122 -884 739 2154 470 873 105 -757 -461 875 348 1538 792 1041 -193 540 -385 -706 -382 562 218 158 -722 -1276 900000 -4036 900000 -392 -1935 340 900000 4555 900000 900000 -2105 277 -2154 900000 -355 -1735 -2128 -6734 -1428 4601 1465 2127 1719 32 -8320 1215 3137 -745 102 2514 1326 1316 -1641 1022 -2676 -261 -2287 1507 -1901 379 -2572 1534 3241 3324 2195 1983 2976 471 2419 -566 -826 430 1437 817 2957 2313 1429 1283 2836 -1215 -260 -1312 181 3246 1346 2859 459 1235 1366 1241 1930 1779 3236 1582 -2042 1498 -132 -1385 -2161 -3484 -2213 -2112 2059 -704 -1171 -1797 -45 -2368 1206 -115 322 653 3499 2399 735 -4119 -2316 -3979 3616 -1187 828 -1376 -3644 -1787 -1710 -2880 355 -1230 -1238 1910 -2224 3595 1132 2220 -873 -2333 -172 1830 -3279 1781 -1484 1204 3330 716 1275 149 -1035 -609 1208 546 2660 1494 2061 -404 1189 -916 -1756 -964 1427 549 381 -1651 -2763 SS 20231019T133806.3Z 8692.568129 91 1 8.47 2 72.40 122.37 125.53 97.77 0.00 1 0.00 1 0 25 2.259e-01 1.343e-02 1.706e-01 8.967e-03 4.356463e-01 4.563200e-03 5.376402e-03 -6.000000e+00 1.281244e-01 225.29 -2.00 3.54 -2.00 319.42 0.00e+00 9.431946e-04 1.224077e-03 1.222518e-03 -6.000000e+00 5.644623e-03 281.78 -2.00 20.00 -2.00 318.78 0.00e+00 3.260 0.001 302.00 328.00 3 3.7018e+00 1.2736e-02 3.9396e-02 -6.0000e+00 3.1688e-01 2.3716e-02 1.4976e-02 2.3653e-02 -6.0000e+00 3.4340e-01 -2.8798e-02 1.1891e-02 1.1802e-02 -6.0000e+00 2.0470e-01 7.7630e-03 6.3203e-03 3.3846e-03 -6.0000e+00 8.9521e-02 3.1858e-04 -6.3041e-04 2.5176e-04 3.7568e-05 -6.0000e+00 5.9379e-03 -4.3124e-02 1.1286e-05 12 9 9 12 1 1 99.46 16.16 0.50 -0.04312 -0.04786 3 5 1 5 0 2116.050 22.29 15.00 16.16 19.55 30.5 945.04 900000 -54327 26931 -60057 62559 -55039 79551 -30931 172125 -33061 50174 -64863 56897 -19561 -24621 -24482 16576 -10004 2366 17315 -2750 8699 3278 17552 -21110 17302 -22969 25916 -19032 13261 -18718 16329 -10015 2859 -5661 884 -17756 -2851 -3043 7865 3342 2679 -1605 -1250 4225 2295 6744 -2870 7515 852 4880 -2195 4700 -1669 2791 -506 3031 1716 -221 53 -761 940 -565 4357 1719 3052 79 2026 -3545 2463 -1126 3017 -750 2755 -460 2086 -3090 1482 -2151 1361 -2235 -2107 -1194 -3427 283 -1519 403 -455 1384 392 -250 -574 995 -2466 264 -749 918 -310 1816 -765 -509 -2097 -1646 -855 -781 -1970 -1113 -1065 -538 481 129 1702 598 1235 105 1221 -817 322 -654 630 -66 509 -204 760 46 1515 738 -401 531 525 31 41 792 -668 916 -973 -90 -302 -86 32 -255 -612 -52 900000 -1797 460 -2420 721 -1778 729 -858 1505 -1206 877 -3477 1040 -885 -1423 -1684 857 -726 163 1086 -221 632 250 1221 -2246 1401 -2786 2000 -2178 1059 -2156 1502 -1363 383 -808 116 -2697 -419 -537 1519 790 699 -442 -356 1151 641 1897 -851 2102 258 1486 -753 1647 -670 1144 -223 1331 779 -101 23 -340 431 -278 2271 998 1751 44 1056 -1985 1442 -753 2101 -559 1950 -318 1335 -1865 823 -1236 804 -1590 -1645 -1031 -3120 261 -1535 412 -492 1505 427 -262 -575 905 -2267 240 -733 968 -374 2325 -1027 -685 -2654 -1943 -947 -906 -2424 -1427 -1435 -738 703 201 2793 980 2013 163 1789 -1167 461 -997 982 -108 830 -325 1201 70 2176 1054 -557 763 806 51 71 1376 -1217 1732 -1944 -180 -622 -180 66 -511 -1203 -100 SS 20231019T144317.6Z 8692.613398 137 1 12.05 2 63.10 136.53 114.36 107.01 0.00 1 0.00 1 0 17 1.609e-02 6.089e-03 7.602e-03 1.734e-03 3.000632e-01 8.701214e-04 3.676352e-03 -6.000000e+00 9.131991e-03 225.28 -2.00 3.54 -2.00 317.94 0.00e+00 1.427163e-03 1.480160e-04 1.558263e-04 -6.000000e+00 4.020279e-04 281.77 -2.00 20.00 -2.00 317.25 0.00e+00 2.198 0.000 302.00 328.00 3 2.3642e+00 2.3067e-03 2.6514e-02 -6.0000e+00 2.2586e-02 -1.2285e-02 2.6046e-03 1.5533e-02 -6.0000e+00 2.4472e-02 -1.7679e-03 1.6722e-03 7.7717e-03 -6.0000e+00 1.4588e-02 -3.3390e-03 8.7331e-04 2.4831e-03 -6.0000e+00 6.3830e-03 4.0238e-03 -4.0628e-04 4.8920e-05 2.5255e-05 -6.0000e+00 4.2296e-04 -4.4538e-02 9.2650e-05 12 1 1 12 1 1 99.99 16.16 0.22 -0.04454 -0.04759 49 47 1 5 0 240.880 22.29 15.00 16.16 20.46 30.6 953.01 900000 747 -3383 -587 -5812 -4994 -5201 -5007 -62 -2137 -3439 -8735 -1543 -4320 1191 -1583 1320 -958 613 -425 1422 -812 133 365 1227 -374 164 168 -892 -776 -446 2197 1365 1540 -2520 -2117 -3811 -2577 -1916 334 -868 -454 -834 369 -800 959 -193 143 -777 -683 197 971 831 1266 1262 403 1479 284 830 -79 1140 593 1936 1728 2061 123 -172 -1315 -460 743 742 573 234 549 286 216 -584 -922 -1381 -686 -1309 -1087 -1571 -1727 -1642 -800 -439 137 360 814 244 533 16 -348 10 22 117 506 692 331 30 -687 -952 -893 -357 -1089 -540 -754 -682 -116 448 561 591 263 94 -36 -122 27 281 338 164 -70 72 415 304 638 50 370 593 510 238 105 -261 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