File name: Pandora147s1_SWDetroitMI_20231111_L2Fit_fout2c1d20210609p1-8.txt File generation date: 20231112T062816.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v1d20210609.txt Level 1 file used: Pandora147s1_SWDetroitMI_20231111_L1_smca1c1d20210609p1-8.txt Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20231111 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 235 377 Nominal wavelengths inside fitting window [nm]: 305.0003 305.1412 305.2821 305.4229 305.5638 305.7046 305.8454 305.9863 306.1271 306.2679 306.4086 306.5494 306.6902 306.8309 306.9716 307.1124 307.2531 307.3938 307.5345 307.6752 307.8158 307.9565 308.0971 308.2378 308.3784 308.5190 308.6596 308.8002 308.9408 309.0813 309.2219 309.3624 309.5029 309.6435 309.7840 309.9245 310.0649 310.2054 310.3459 310.4863 310.6268 310.7672 310.9076 311.0480 311.1884 311.3288 311.4692 311.6095 311.7499 311.8902 312.0305 312.1708 312.3111 312.4514 312.5917 312.7320 312.8722 313.0124 313.1527 313.2929 313.4331 313.5733 313.7135 313.8537 313.9938 314.1340 314.2741 314.4142 314.5543 314.6944 314.8345 314.9746 315.1147 315.2547 315.3948 315.5348 315.6748 315.8149 315.9549 316.0948 316.2348 316.3748 316.5147 316.6547 316.7946 316.9345 317.0744 317.2143 317.3542 317.4941 317.6339 317.7738 317.9136 318.0534 318.1932 318.3330 318.4728 318.6126 318.7524 318.8921 319.0319 319.1716 319.3113 319.4510 319.5907 319.7304 319.8701 320.0097 320.1494 320.2890 320.4287 320.5683 320.7079 320.8475 320.9870 321.1266 321.2662 321.4057 321.5452 321.6848 321.8243 321.9638 322.1033 322.2427 322.3822 322.5216 322.6611 322.8005 322.9399 323.0793 323.2187 323.3581 323.4975 323.6368 323.7762 323.9155 324.0548 324.1941 324.3334 324.4727 324.6120 324.7512 324.8905 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231111T125304.3Z 8715.536856 99 1 49.69 2 85.00 119.09 67.53 131.48 0.00 1 0.00 1 0 25 6.857e-01 5.479e-02 4.545e-01 4.895e-02 9.325549e-01 2.803997e-02 1.076203e-02 -6.000000e+00 3.897029e-01 223.23 -2.00 3.54 -2.00 321.95 0.00e+00 -2.415537e-02 9.846098e-03 6.896632e-03 -6.000000e+00 1.796373e-02 278.88 -2.00 20.00 -2.00 321.39 0.00e+00 9.837 0.018 302.00 328.00 3 -3.3324e-01 9.1237e-02 1.2282e-01 -6.0000e+00 9.6258e-01 1.7697e+00 1.0851e-01 1.0207e-01 -6.0000e+00 1.0480e+00 -2.0322e+00 7.2617e-02 2.8099e-02 -6.0000e+00 6.2208e-01 7.2876e-01 3.9687e-02 2.1030e-02 -6.0000e+00 2.7257e-01 2.0174e-05 4.8747e-04 1.3102e-03 2.4650e-04 -6.0000e+00 1.8358e-02 -4.3218e-02 7.8080e-05 12 9 8 11 8 0 -3.19 16.19 1.05 -0.04322 -0.03956 25 6 1 5 0 1987.410 22.29 15.00 16.19 9.24 29.3 873.05 900000 42837 900000 56945 9965 -27000 21876 47021 -55040 335912 229349 900000 -31957 18453 9556 33952 -5091 196352 -533 45539 34204 -9015 -42717 -56287 -387 -44215 -11910 -20821 -54724 -35840 -48682 51646 332339 -13180 900000 324331 56428 39991 21506 7261 144417 48112 91784 14275 76103 -5434 45268 24634 7436 68007 169402 213565 -36555 65731 49542 55619 2601 74953 -3260 34169 55265 48815 -30091 24188 -11623 -6777 -9738 37022 -9973 215 56266 28124 52052 42944 34305 -13230 32157 -26660 1559 -610 -16446 -12740 -13692 -1545 7508 5489 17291 17075 4643 11966 12916 -12471 -14862 5337 12928 759 -5748 8655 -11093 9584 -11052 4449 -8489 3751 -18639 7188 -14151 494 -2684 5636 1878 2681 -1889 -69 1214 1358 -3931 496 1320 -796 5940 -1744 4892 -755 -1224 2001 2785 1973 -3433 4177 1138 -850 -482 -461 -497 -1970 -490 1867 1809 1076 -2729 822 -1385 900000 3005 900000 2876 643 -2045 1043 2243 -6949 16022 10939 900000 -3676 1430 855 2530 -577 9365 -56 2851 2243 -833 -5221 -8558 -39 -7645 -1491 -2545 -7667 -3526 -5370 2463 15852 -1336 900000 15470 2691 2146 1667 801 6888 4446 5837 1745 4840 -664 3311 2115 757 3892 8080 10186 -7301 5434 5199 5836 457 6912 -583 4020 4745 4346 -6315 3307 -2513 -1422 -2044 4944 -2283 50 8588 6081 8938 7647 6000 -3239 4397 -6273 293 -136 -5125 -4497 -5617 -614 2889 2287 6708 6841 2111 4909 4928 -5710 -6711 2002 4974 386 -3674 5587 -9392 7085 -9851 3324 -6371 2290 -14698 4731 -12150 391 -2407 5322 2015 3253 -2584 -95 1622 1745 -5214 646 1798 -1167 8783 -2673 6642 -1051 -1674 2583 3463 2459 -5033 6735 2192 -1754 -1075 -1108 -1297 -5632 -1440 5443 5329 3129 -7720 2204 -3520 SS 20231111T130441.7Z 8715.544927 102 1 48.75 2 83.15 121.16 66.03 134.04 0.00 1 0.00 1 0 17 4.677e-01 2.166e-02 3.672e-01 1.057e-02 8.582671e-01 6.047698e-03 9.675539e-03 -6.000000e+00 2.646529e-01 223.23 -2.00 3.54 -2.00 322.09 0.00e+00 1.386832e-03 3.347654e-03 2.556738e-03 -6.000000e+00 1.156820e-02 278.88 -2.00 20.00 -2.00 321.67 0.00e+00 7.669 0.008 302.00 328.00 3 -2.7940e-01 2.3031e-02 8.9374e-02 -6.0000e+00 6.5348e-01 7.9554e-01 3.2149e-02 5.1878e-02 -6.0000e+00 7.1003e-01 -1.1297e+00 3.0713e-02 2.8260e-02 -6.0000e+00 4.2126e-01 4.7244e-01 1.4282e-02 9.0375e-03 -6.0000e+00 1.8391e-01 1.7309e-04 -2.1002e-03 2.9133e-04 1.1933e-04 -6.0000e+00 1.2460e-02 -4.3324e-02 4.1552e-05 12 8 8 10 0 0 0.94 16.18 0.31 -0.04332 -0.05911 95 22 1 5 0 513.050 22.29 14.99 16.18 9.73 29.3 877.59 900000 90896 -39274 -10934 2394 -141057 35579 -174843 900000 -186640 -13919 -173536 13407 -129929 6099 -38455 81884 -57096 21549 -38857 36535 -29993 -19823 5864 -53932 -6011 -39524 79399 -56195 104236 -72345 133794 6162 111013 -11545 174722 -4957 40841 3487 50525 20483 69404 43130 45283 13926 52187 45484 26477 40358 34416 37247 9563 60104 14376 71731 13342 54303 17238 34070 1395 29255 15193 21103 10973 32935 10177 11669 7007 8950 22790 9951 22924 10146 15990 2121 9557 -1200 5706 -9669 5955 1293 5524 -5444 -573 871 417 -1232 2689 2553 2053 240 -1745 3196 -5050 -1958 -7573 -675 -3545 376 -2908 -551 -4335 -2233 -5315 -2199 -4286 -1746 -1826 -2528 -1260 -1786 -47 261 933 -541 -99 -455 643 -942 1462 466 2599 856 2744 983 2340 414 1703 -238 435 798 59 350 -28 83 -124 559 -88 232 -433 241 -1708 -639 900000 937 -442 -113 25 -3305 367 -5571 900000 -7695 -143 -6505 138 -4505 69 -829 844 -1873 343 -1165 514 -787 -446 104 -1870 -135 -1259 818 -1896 1074 -3051 1379 173 1373 -454 1801 -163 1010 134 1614 941 2361 1819 1909 796 2005 1875 1340 1853 1774 2024 771 3267 1347 4100 1438 4020 1874 3033 162 2467 1509 2195 1460 4012 1640 1826 1162 1543 3865 2210 4855 2500 3581 501 1863 -232 984 -2066 1278 354 1719 -2183 -240 382 196 -622 1363 1321 1054 119 -827 1371 -2347 -958 -4584 -416 -2655 315 -2743 -504 -3817 -1701 -4133 -1685 -3623 -1520 -1553 -2365 -1319 -2177 -63 380 1375 -792 -138 -622 889 -1394 2235 735 3883 1233 3739 1445 3291 575 2291 -355 695 1469 122 778 -65 213 -342 1593 -256 679 -1259 657 -4370 -1497 SS 20231111T131531.4Z 8715.552446 105 1 48.70 2 81.45 123.13 64.69 136.49 0.00 1 0.00 1 0 25 5.795e-01 1.063e-02 1.707e-01 3.969e-03 7.441834e-01 2.191957e-03 8.487704e-03 -6.000000e+00 3.260860e-01 223.23 -2.00 3.54 -2.00 321.69 0.00e+00 2.860426e-03 1.159187e-03 1.539497e-03 -6.000000e+00 1.430202e-02 278.88 -2.00 20.00 -2.00 321.24 0.00e+00 6.344 0.005 302.00 328.00 3 -3.0621e-01 7.9105e-03 7.3931e-02 -6.0000e+00 8.0360e-01 2.3234e-01 1.1595e-02 4.2403e-02 -6.0000e+00 8.7248e-01 -3.3602e-01 1.2440e-02 2.4266e-02 -6.0000e+00 5.2000e-01 1.3678e-01 5.7929e-03 8.4707e-03 -6.0000e+00 2.2788e-01 7.2276e-04 -1.1655e-03 1.0951e-04 9.9697e-05 -6.0000e+00 1.5221e-02 -4.3713e-02 4.1730e-05 12 8 8 10 0 0 7.32 16.18 0.34 -0.04371 -0.05247 212 49 1 5 0 229.670 22.29 15.00 16.18 10.44 29.4 883.49 900000 -216595 -60529 -180171 -157077 -217839 -162363 -203336 -207014 -147075 -165859 -166544 -189176 -102560 -98449 -90522 -111105 -40683 -89988 -13416 -49505 -8266 -62018 28035 -48368 -23985 -50096 -27451 -42766 -44261 -45894 -27723 -12748 -5908 -6321 -21577 8272 -23976 17423 1072 12677 2514 16298 -582 11434 3697 24738 -1479 10026 4289 6508 10662 8480 10769 7087 11980 6985 10018 4730 7059 2855 6474 4723 11596 7278 8084 3017 4012 3024 6151 2782 5242 3503 3399 2394 185 -899 -4637 -2900 -2151 -716 -1534 -142 -2514 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