File name: Pandora147s1_SWDetroitMI_20231124_L2Fit_fout2c1d20210609p1-8.txt File generation date: 20231125T071617.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v1d20210609.txt Level 1 file used: Pandora147s1_SWDetroitMI_20231124_L1_smca1c1d20210609p1-8.txt Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20231124 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 235 377 Nominal wavelengths inside fitting window [nm]: 305.0003 305.1412 305.2821 305.4229 305.5638 305.7046 305.8454 305.9863 306.1271 306.2679 306.4086 306.5494 306.6902 306.8309 306.9716 307.1124 307.2531 307.3938 307.5345 307.6752 307.8158 307.9565 308.0971 308.2378 308.3784 308.5190 308.6596 308.8002 308.9408 309.0813 309.2219 309.3624 309.5029 309.6435 309.7840 309.9245 310.0649 310.2054 310.3459 310.4863 310.6268 310.7672 310.9076 311.0480 311.1884 311.3288 311.4692 311.6095 311.7499 311.8902 312.0305 312.1708 312.3111 312.4514 312.5917 312.7320 312.8722 313.0124 313.1527 313.2929 313.4331 313.5733 313.7135 313.8537 313.9938 314.1340 314.2741 314.4142 314.5543 314.6944 314.8345 314.9746 315.1147 315.2547 315.3948 315.5348 315.6748 315.8149 315.9549 316.0948 316.2348 316.3748 316.5147 316.6547 316.7946 316.9345 317.0744 317.2143 317.3542 317.4941 317.6339 317.7738 317.9136 318.0534 318.1932 318.3330 318.4728 318.6126 318.7524 318.8921 319.0319 319.1716 319.3113 319.4510 319.5907 319.7304 319.8701 320.0097 320.1494 320.2890 320.4287 320.5683 320.7079 320.8475 320.9870 321.1266 321.2662 321.4057 321.5452 321.6848 321.8243 321.9638 322.1033 322.2427 322.3822 322.5216 322.6611 322.8005 322.9399 323.0793 323.2187 323.3581 323.4975 323.6368 323.7762 323.9155 324.0548 324.1941 324.3334 324.4727 324.6120 324.7512 324.8905 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231124T130948.2Z 8728.548475 194 1 36.21 2 85.10 123.68 123.24 328.96 0.00 1 0.00 1 0 33 5.147e-01 5.907e-02 4.692e-01 5.992e-02 1.002220e+00 3.503140e-02 1.149108e-02 -6.000000e+00 2.964473e-01 222.75 -2.00 3.54 -2.00 321.83 0.00e+00 -2.311408e-02 1.152821e-02 7.161547e-03 -6.000000e+00 1.437064e-02 277.38 -2.00 20.00 -2.00 321.32 0.00e+00 9.988 0.019 302.00 328.00 3 -4.0827e-01 1.1266e-01 1.2483e-01 -6.0000e+00 7.3440e-01 2.0737e+00 1.2907e-01 9.7976e-02 -6.0000e+00 8.0208e-01 -2.2935e+00 7.7930e-02 2.5836e-02 -6.0000e+00 4.7253e-01 8.3295e-01 4.4259e-02 2.3382e-02 -6.0000e+00 2.0588e-01 1.5501e-05 1.3052e-03 1.5527e-03 2.3010e-04 -6.0000e+00 1.4123e-02 -4.9328e-02 1.1064e-04 12 9 9 12 1 1 59.53 15.89 1.04 -0.04933 -0.03952 12 4 1 5 0 2783.870 21.98 15.00 15.89 4.10 28.8 837.89 900000 130766 900000 -21963 50826 -30309 -3311 -54661 900000 38114 900000 106409 32917 57459 49579 171826 78674 263833 73339 900000 84654 900000 -40258 32403 -12499 900000 52938 900000 -43033 900000 8735 53145 4355 120857 900000 -30578 21038 -4198 141021 58113 117349 -58858 163652 10541 900000 5911 2922 -37495 13490 -27535 64120 -10259 171153 9784 24718 30267 10006 17022 10617 90329 -25182 34962 -2515 9179 -13538 18324 -5877 40886 -31678 56410 -14165 52633 -4033 60903 35175 46975 -13868 79102 -6192 21528 9347 -4788 14866 -646 17163 -2036 21890 11271 -4160 -14389 12641 -8973 14928 -15361 15052 -7498 7270 -11183 -1319 3918 -732 1529 -13213 3985 -12595 10996 -14796 5583 -5884 14787 -4507 6860 -2909 5396 -7762 4885 -1360 4481 -4648 -224 3524 1679 -123 150 13336 -5205 1979 -6951 4437 -1625 4423 -798 -287 -3911 284 -323 425 -91 2079 841 1044 -982 -2420 900000 7625 900000 -3949 3772 -3682 -316 -8765 900000 3233 900000 6205 2966 4264 4205 10019 5422 15385 5054 900000 4936 900000 -6189 2577 -1789 900000 4209 900000 -6387 900000 648 3099 416 7047 900000 -3728 1450 -401 8223 4313 6843 -17472 9543 1453 900000 689 325 -5963 1287 -4087 4487 -1523 9980 1400 3276 4011 1697 2707 1688 6321 -4539 3670 -411 1499 -2799 3099 -1234 5483 -8564 7895 -4130 9207 -1133 9234 6153 6300 -2992 6458 -1264 3891 2289 -1591 4681 -260 6105 -842 8169 4798 -1874 -6941 4791 -3924 4962 -7076 5705 -4198 4155 -8181 -1007 3053 -586 1094 -9596 2440 -9327 6925 -11530 4167 -4929 12761 -5041 7855 -3978 6980 -11315 6060 -1759 5607 -6702 -325 4931 2279 -160 207 15708 -7193 2469 -9444 6029 -2805 7620 -1628 -633 -9682 730 -902 1227 -266 5997 2394 2761 -2422 -5568 SS 20231124T132129.5Z 8728.556591 197 1 48.52 2 83.33 125.77 124.21 332.07 0.00 1 0.00 1 0 25 5.339e-01 2.422e-02 3.536e-01 1.306e-02 8.769615e-01 7.629356e-03 9.934962e-03 -6.000000e+00 3.029714e-01 222.75 -2.00 3.54 -2.00 322.16 0.00e+00 4.571729e-03 4.022500e-03 1.894162e-03 -6.000000e+00 1.361593e-02 277.37 -2.00 20.00 -2.00 321.75 0.00e+00 7.844 0.009 302.00 328.00 3 -8.6254e-02 2.8306e-02 9.1073e-02 -6.0000e+00 7.4799e-01 1.0110e+00 3.6772e-02 5.1894e-02 -6.0000e+00 8.1454e-01 -1.3729e+00 3.2748e-02 2.6369e-02 -6.0000e+00 4.8370e-01 5.6150e-01 1.5760e-02 9.4497e-03 -6.0000e+00 2.1252e-01 1.1291e-04 -2.0916e-03 3.6434e-04 1.2333e-04 -6.0000e+00 1.4459e-02 -4.7794e-02 2.3314e-05 12 8 8 10 0 0 72.62 15.91 0.40 -0.04779 -0.06351 60 14 1 5 0 808.600 21.98 15.00 15.91 4.63 28.9 842.33 900000 -95909 900000 -99283 900000 -139420 75773 -99485 -30589 -78739 -135213 -94038 -98464 93569 -82788 58871 -20306 210892 -17236 148601 -45497 900000 -51133 900000 11627 87765 -26022 93145 -44632 45130 -6671 -18283 188138 39832 900000 17611 54920 -31428 92835 -15046 107428 19018 194491 26815 125816 17973 104093 29472 74965 36433 34031 20131 30663 49587 50390 38859 22096 72158 16535 36709 -6457 42930 9717 32336 11584 29052 13948 35451 -663 28838 12765 25637 10576 9355 10674 4121 1033 -8500 2520 -6224 5169 -4425 9635 -3655 5266 -917 4275 -3576 1167 -769 526 -6582 1919 -5340 -6042 -2553 -5557 -3019 -1947 945 -4517 50 -3798 1035 -4034 801 -6663 293 -3382 -601 -2916 330 -1025 -33 -370 -613 -432 -642 725 244 1678 -75 2392 1181 4674 439 3526 -220 2413 -1193 1636 91 1503 153 12 -612 -180 320 234 284 -384 -501 -2176 900000 -3253 900000 -3683 900000 -5615 964 -2646 -424 -1821 -5016 -2501 -3074 1190 -3542 749 -657 2682 -618 1890 -2157 900000 -2247 900000 282 1116 -933 1185 -1703 678 -185 -698 2393 1151 900000 591 1206 -1744 1717 -974 2360 1099 2474 1519 2880 1081 2648 1602 2687 2022 2085 1583 2411 3497 3787 3415 2350 4672 1797 3056 -791 3276 1146 3514 1768 3930 2161 4468 -126 4601 2745 5247 2568 2207 2271 829 190 -1641 463 -1468 1327 -1484 3242 -1414 1970 -388 1812 -1709 542 -359 231 -3158 803 -2396 -2962 -1299 -3481 -2182 -1622 837 -4213 41 -2874 673 -2792 570 -5395 236 -3087 -605 -3492 436 -1482 -48 -532 -848 -581 -885 1040 372 2580 -114 3339 1608 5975 568 4681 -297 3174 -1915 2964 188 3297 363 30 -1690 -516 928 684 820 -1052 -1264 -5158 SS 20231124T133223.2Z 8728.564157 200 1 48.81 2 81.72 127.76 125.03 335.03 0.00 1 0.00 1 0 17 5.349e-01 1.594e-02 2.718e-01 6.060e-03 7.739970e-01 3.404934e-03 8.954318e-03 -6.000000e+00 3.006363e-01 222.75 -2.00 3.54 -2.00 321.81 0.00e+00 6.800642e-03 1.750669e-03 2.266378e-03 -6.000000e+00 1.311733e-02 277.37 -2.00 20.00 -2.00 321.37 0.00e+00 6.522 0.005 302.00 328.00 3 1.5809e-01 1.2196e-02 7.6370e-02 -6.0000e+00 7.4054e-01 4.2852e-01 1.7249e-02 4.3883e-02 -6.0000e+00 8.0423e-01 -5.8938e-01 1.7991e-02 2.6054e-02 -6.0000e+00 4.7907e-01 2.4547e-01 8.4634e-03 1.0675e-02 -6.0000e+00 2.1009e-01 3.5528e-04 -1.5472e-03 1.6927e-04 1.4606e-04 -6.0000e+00 1.4042e-02 -4.8415e-02 8.9284e-05 12 8 8 10 0 0 91.50 15.92 0.32 -0.04841 -0.06004 120 28 1 5 0 406.680 22.09 15.00 15.92 5.18 28.9 846.88 900000 -6041 -218341 173576 -196988 154481 -213838 44466 -205924 -128850 -196634 -29902 -139608 -104531 -87246 -20316 36027 -53882 -22564 -40668 66906 -46423 55461 -73065 39318 -82747 22504 -66927 14213 -71925 4222 -44849 3106 -19361 18850 -1218 -10107 13641 7660 42247 -1205 53793 -5166 55792 -1901 46753 -6408 53737 263 30353 1747 21470 14450 23013 12261 19601 11639 11610 12879 12104 14605 5839 15612 6000 18580 6835 13751 4440 10724 3125 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