File name: Pandora147s1_SWDetroitMI_20240424_L2Fit_fout2c9d20221206p1-8.txt File generation date: 20240429T122040.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v9d20221206.txt Level 1 file used: Pandora147s1_SWDetroitMI_20240424_L1_smca1c9d20221206p1-8.txt Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20240424 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 236 378 Nominal wavelengths inside fitting window [nm]: 305.0989 305.2398 305.3807 305.5215 305.6624 305.8032 305.9440 306.0848 306.2256 306.3664 306.5072 306.6479 306.7887 306.9294 307.0701 307.2108 307.3516 307.4922 307.6329 307.7736 307.9143 308.0549 308.1955 308.3362 308.4768 308.6174 308.7580 308.8985 309.0391 309.1797 309.3202 309.4607 309.6013 309.7418 309.8823 310.0227 310.1632 310.3037 310.4441 310.5846 310.7250 310.8654 311.0058 311.1462 311.2866 311.4270 311.5673 311.7077 311.8480 311.9883 312.1286 312.2689 312.4092 312.5495 312.6898 312.8300 312.9703 313.1105 313.2507 313.3909 313.5311 313.6713 313.8115 313.9517 314.0918 314.2319 314.3721 314.5122 314.6523 314.7924 314.9325 315.0725 315.2126 315.3526 315.4927 315.6327 315.7727 315.9127 316.0527 316.1927 316.3326 316.4726 316.6125 316.7525 316.8924 317.0323 317.1722 317.3121 317.4519 317.5918 317.7317 317.8715 318.0113 318.1511 318.2909 318.4307 318.5705 318.7103 318.8500 318.9898 319.1295 319.2692 319.4089 319.5486 319.6883 319.8280 319.9677 320.1073 320.2469 320.3866 320.5262 320.6658 320.8054 320.9450 321.0845 321.2241 321.3636 321.5032 321.6427 321.7822 321.9217 322.0612 322.2007 322.3401 322.4796 322.6190 322.7584 322.8979 323.0373 323.1767 323.3160 323.4554 323.5948 323.7341 323.8734 324.0128 324.1521 324.2914 324.4307 324.5699 324.7092 324.8485 324.9877 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240424T131040.0Z 8880.549074 268 1 48.92 2 62.75 97.06 116.80 269.75 0.00 1 0.00 1 0 17 1.027e-01 8.285e-03 5.798e-02 4.230e-03 4.128664e-01 2.140622e-03 4.801631e-03 -6.000000e+00 5.822108e-02 229.20 -2.00 3.54 -2.00 319.59 0.00e+00 2.009552e-04 5.847028e-04 3.154776e-04 -6.000000e+00 2.529217e-03 279.57 -2.00 20.00 -2.00 318.93 0.00e+00 2.173 0.000 302.00 328.00 3 4.4914e+00 6.0575e-03 3.0588e-02 -6.0000e+00 1.4535e-01 2.9343e-02 7.1232e-03 2.1540e-02 -6.0000e+00 1.5793e-01 2.2857e-02 5.5703e-03 1.0730e-02 -6.0000e+00 9.3780e-02 -1.6169e-02 2.9109e-03 3.0686e-03 -6.0000e+00 3.9591e-02 3.9376e-04 -3.8679e-05 1.2141e-04 3.2187e-05 -6.0000e+00 2.6936e-03 -2.5633e-02 7.2734e-05 11 8 0 10 0 0 99.99 16.16 0.48 -0.02563 -0.02592 121 28 1 5 0 404.230 22.29 15.00 16.16 11.50 32.0 957.28 -27103 22506 -31672 16422 -29478 41188 -41379 32385 -38858 28529 -37835 26198 -20015 1057 -5781 -523 -9245 -6974 4852 2169 7040 -8048 18234 -9473 8266 -6429 3318 -6037 9498 -12790 11685 -6370 10674 -6314 1933 -3484 -597 -1393 376 758 -1909 269 -1452 2594 -1224 1373 -3412 3816 -2607 2005 -2493 4345 -802 2254 327 2900 -220 654 292 2112 1224 1293 2113 1153 1574 -1924 1261 -1751 1773 -330 851 64 1757 -319 1329 -1718 510 -1581 -92 -1445 -683 -1631 -2230 -1278 -922 -272 -940 1332 226 1426 -452 963 -1277 738 -210 337 268 1411 356 185 -847 -650 -1009 -680 -655 -1312 -590 -1199 245 -89 933 177 454 -371 151 -735 378 -265 491 -437 162 375 388 642 265 132 354 815 36 533 -260 79 -615 640 -276 -5 -376 554 -153 48 -411 138 -485 -729 416 -1004 319 -816 578 -1374 621 -1566 656 -1632 669 -959 49 -328 -32 -666 -524 344 166 524 -694 1258 -934 735 -696 327 -618 791 -1360 1084 -800 1265 -923 245 -459 -85 -236 73 174 -497 72 -412 715 -351 387 -1003 1041 -763 579 -815 1451 -303 881 136 1210 -97 284 124 869 525 603 1082 648 891 -1056 635 -907 967 -211 587 46 1236 -218 822 -1023 271 -838 -52 -955 -489 -1314 -1941 -1156 -889 -279 -1020 1450 248 1479 -441 849 -1121 632 -197 339 305 1771 481 246 -1058 -733 -1068 -740 -774 -1640 -767 -1651 355 -140 1563 306 760 -588 220 -1020 520 -384 754 -714 264 595 596 984 388 184 470 1102 53 864 -433 135 -1093 1178 -546 -10 -796 1186 -329 101 -815 260 -932 SS 20240424T131618.0Z 8880.552986 271 1 49.02 2 61.72 98.08 117.81 270.66 0.00 1 0.00 1 0 17 4.240e-02 6.353e-03 4.902e-02 4.353e-03 4.032501e-01 2.188810e-03 4.739834e-03 -6.000000e+00 2.403632e-02 229.20 -2.00 3.54 -2.00 319.38 0.00e+00 -8.254256e-05 5.647936e-04 3.622631e-04 -6.000000e+00 1.044182e-03 279.57 -2.00 20.00 -2.00 318.72 0.00e+00 2.100 0.000 302.00 328.00 3 4.9436e+00 6.1376e-03 2.9806e-02 -6.0000e+00 6.0006e-02 4.4621e-02 7.1647e-03 2.1178e-02 -6.0000e+00 6.5204e-02 5.6432e-03 5.4649e-03 1.0468e-02 -6.0000e+00 3.8718e-02 -5.9393e-03 2.8701e-03 2.9410e-03 -6.0000e+00 1.6344e-02 2.7089e-04 -1.9310e-04 1.2409e-04 3.0975e-05 -6.0000e+00 1.1123e-03 -2.5505e-02 4.8416e-05 11 1 0 11 8 0 99.97 16.17 0.33 -0.02550 -0.02696 48 11 1 5 0 1021.070 22.29 15.00 16.17 11.68 32.1 959.51 -8502 6061 9339 -17460 7911 -2452 -2214 -21066 17355 -11917 -10518 -17856 10048 -2352 4268 -9552 -559 -4290 -1471 961 -2105 -3474 -4025 -4144 1952 -3114 4484 593 -5846 -3419 1590 4700 -1027 126 -5600 -1777 -4865 3852 -4261 289 -871 791 -827 -650 -1366 940 -1993 662 398 -335 742 374 2868 -407 884 392 574 962 821 -50 477 1653 2873 1353 631 -524 -541 827 34 809 442 1088 1157 493 303 -477 -732 -299 -1847 -379 -987 -1015 -2315 -1170 -1198 63 -769 553 505 982 499 197 -469 -57 -47 -230 597 895 834 -778 -8 -1056 -644 -632 -901 -1090 -813 -601 81 261 925 581 186 -5 -434 -99 -445 445 -179 200 -386 389 203 705 178 389 -136 715 415 493 -133 11 -544 -168 44 -87 221 129 477 -319 34 -398 -479 -225 156 242 -558 176 -59 -58 -762 484 -475 -417 -812 406 -129 259 -719 -41 -349 -123 82 -190 -316 -382 -426 203 -357 478 62 -617 -375 176 567 -146 18 -814 -245 -763 658 -964 74 -248 233 -256 -203 -430 291 -631 203 123 -107 254 140 1125 -176 392 180 269 447 371 -23 221 821 1558 808 383 -301 -294 441 20 539 323 821 863 352 200 -283 -398 -157 -1065 -248 -740 -850 -2104 -1103 -1209 67 -831 606 551 1067 503 182 -406 -49 -43 -241 698 1116 1108 -1032 -10 -1235 -702 -711 -1101 -1406 -1094 -849 116 404 1524 983 307 -8 -651 -140 -632 655 -283 318 -621 633 319 1059 256 531 -177 946 601 779 -226 19 -981 -302 84 -175 452 269 989 -643 65 -760 -893 SS 20240424T132016.9Z 8880.555751 274 1 10.20 2 60.99 98.81 118.53 271.30 0.00 1 0.00 1 0 25 3.411e-02 6.471e-03 1.236e-02 2.041e-03 3.874054e-01 1.020071e-03 4.592509e-03 -6.000000e+00 1.933522e-02 229.20 -2.00 3.54 -2.00 318.28 0.00e+00 6.241805e-04 1.922580e-04 2.312626e-04 -6.000000e+00 8.399505e-04 279.57 -2.00 20.00 -2.00 317.60 0.00e+00 2.053 0.000 302.00 328.00 3 3.1288e+00 2.7600e-03 2.8758e-02 -6.0000e+00 4.8270e-02 3.1352e-02 3.1373e-03 2.0099e-02 -6.0000e+00 5.2450e-02 -3.7298e-03 2.1014e-03 9.9172e-03 -6.0000e+00 3.1145e-02 -2.2470e-03 1.0987e-03 2.8143e-03 -6.0000e+00 1.3148e-02 1.8001e-03 -2.5655e-04 5.6136e-05 2.8244e-05 -6.0000e+00 8.9466e-04 -2.5794e-02 5.0818e-05 12 9 1 12 1 1 99.93 16.18 0.39 -0.02579 -0.02772 19 22 1 5 0 509.630 22.29 15.00 16.18 11.84 32.1 960.31 -16296 -4975 -9868 -8001 -16512 -12932 -11100 -6808 -7503 -8939 -7911 -11577 -5915 -899 230 -1569 2575 -1301 2310 -204 938 -2080 911 -1847 1911 -1650 -256 -3137 -2748 -1219 2291 1999 1231 -426 -3366 -2395 -3203 -1407 -1492 674 -472 1020 -640 -175 42 598 -651 335 -1157 290 889 1213 1227 1355 1290 942 1152 660 89 477 1066 1718 2546 1794 480 24 -125 -933 394 540 638 99 391 38 80 -131 -1122 -772 -1379 -1003 -1031 -1098 -2045 -1715 -1318 -824 -246 231 505 722 485 168 -310 -2 408 -108 790 900 428 -310 -410 -1170 -708 -410 -699 -896 -749 -673 59 151 421 462 399 127 81 -116 6 392 94 193 -84 241 451 584 762 -8 79 890 371 591 -23 -40 -368 -36 -157 -300 121 321 15 -53 -361 -354 -565 -799 -244 -528 -397 -877 -643 -585 -393 -491 -573 -554 -813 -460 -80 24 -186 314 -175 317 -30 139 -316 139 -311 332 -310 -48 -566 -468 -207 417 409 282 -103 -786 -545 -809 -413 -490 255 -199 445 -294 -81 19 277 -303 153 -537 136 448 613 663 778 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