File name: Pandora72s1_SaltLakeCityUT-Hawthorne_20240306_L2Fit_fwvt1c40d20221201p1-8.txt File generation date: 20240307T074931.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 72 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora72_OF_v3d20210409.txt Instrument calibration file used: Pandora72s1_CF_v40d20221201.txt Level 1 file used: Pandora72s1_SaltLakeCityUT-Hawthorne_20240306_L1_smca1c40d20221201p1-8.txt Full location name: SLC - Hawthorne, UT - UTDEQ (AQS Site ID 49-035-3006) Short location name: SaltLakeCityUT-Hawthorne Country of location: United States Location latitude [deg]: 40.7344 Location longitude [deg]: -111.8722 Location altitude [m]: 1306 Local noon date: 20240306 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: initial FieldCal based on Session4 First and last pixel inside fitting window: 1680 1830 Nominal wavelengths inside fitting window [nm]: 492.0047 492.1258 492.2468 492.3679 492.4889 492.6099 492.7309 492.8519 492.9728 493.0938 493.2147 493.3356 493.4565 493.5774 493.6983 493.8191 493.9399 494.0607 494.1815 494.3023 494.4231 494.5438 494.6645 494.7853 494.9060 495.0266 495.1473 495.2679 495.3886 495.5092 495.6298 495.7503 495.8709 495.9914 496.1120 496.2325 496.3530 496.4734 496.5939 496.7143 496.8348 496.9552 497.0756 497.1959 497.3163 497.4366 497.5570 497.6773 497.7976 497.9178 498.0381 498.1583 498.2785 498.3987 498.5189 498.6391 498.7593 498.8794 498.9995 499.1196 499.2397 499.3598 499.4798 499.5999 499.7199 499.8399 499.9599 500.0798 500.1998 500.3197 500.4396 500.5595 500.6794 500.7993 500.9191 501.0390 501.1588 501.2786 501.3984 501.5181 501.6379 501.7576 501.8773 501.9970 502.1167 502.2364 502.3560 502.4756 502.5952 502.7148 502.8344 502.9540 503.0735 503.1930 503.3125 503.4320 503.5515 503.6710 503.7904 503.9098 504.0292 504.1486 504.2680 504.3873 504.5067 504.6260 504.7453 504.8646 504.9839 505.1031 505.2223 505.3416 505.4608 505.5799 505.6991 505.8183 505.9374 506.0565 506.1756 506.2947 506.4137 506.5328 506.6518 506.7708 506.8898 507.0088 507.1278 507.2467 507.3656 507.4845 507.6034 507.7223 507.8412 507.9600 508.0788 508.1976 508.3164 508.4352 508.5539 508.6727 508.7914 508.9101 509.0288 509.1474 509.2661 509.3847 509.5033 509.6219 509.7405 509.8591 509.9776 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240306T144533.9Z 8831.614975 113 1 4.90 2 80.98 105.10 71.25 158.53 0.00 1 0.00 1 0 15 2.196e-03 2.185e-03 5.184e-04 5.179e-04 3.243960e+03 3.260660e+01 2.338406e+02 -6.000000e+00 1.255065e+02 268.99 -2.00 20.00 -2.00 505.28 0.00e+00 1.774667e-03 1.431725e-05 9.719130e-05 -6.000000e+00 6.174160e-05 268.99 -2.00 20.00 -2.00 500.57 0.00e+00 6.993155e-01 1.066427e-02 3.204275e-02 -6.000000e+00 4.555494e-02 225.19 -2.00 3.47 -2.00 502.14 0.00e+00 6.059 0.004 489.00 513.00 1 3.8410e+00 8.1840e-04 8.2026e-03 -6.0000e+00 3.4977e-03 -3.1502e-03 2.0442e-04 8.0230e-04 -6.0000e+00 8.8280e-04 1.8605e-02 6.4775e-04 6.7426e-05 5.4893e-05 -6.0000e+00 2.9738e-04 8.3316e-03 -8.5604e-05 12 1 1 12 1 1 43.82 23.52 2.05 0.00833 0.01282 23 48 1 4 0 204.030 26.83 20.01 23.52 14.78 24.7 872.67 900000 -268 -21 25 26 -88 222 193 212 35 106 65 -23 -113 -60 -122 -209 55 193 88 -52 0 97 234 425 349 133 194 -71 -225 -248 -140 -292 229 296 -79 -294 -101 57 79 158 95 94 177 107 247 13 -12 -14 64 -46 -372 -355 -351 -187 -83 -88 -137 -149 -28 154 303 262 238 193 132 -29 59 -81 -61 -18 -114 -283 -253 13 -202 -432 -502 -391 -62 -31 -36 -174 -177 -20 -127 -309 -278 -124 -115 -181 99 344 260 5 1 12 17 2 -140 -248 -660 -367 -276 -139 -368 -319 -344 -103 153 271 273 155 180 49 107 445 558 472 422 364 164 221 377 412 204 103 -20 -52 99 260 69 65 55 -215 8 302 11 -95 -133 -54 -151 -104 89 207 57 -104 -188 -294 -329 -130 900000 -260 -20 24 26 -89 227 199 220 37 108 66 -23 -113 -60 -123 -209 56 196 90 -54 0 101 243 443 364 139 200 -72 -227 -251 -140 -292 233 302 -81 -303 -104 58 81 162 98 96 182 111 257 13 -13 -14 64 -46 -367 -351 -347 -185 -84 -90 -139 -153 -29 157 311 269 241 198 133 -29 59 -81 -61 -18 -112 -280 -248 13 -199 -423 -494 -381 -60 -30 -34 -169 -174 -20 -124 -306 -276 -123 -113 -179 99 344 258 5 1 12 17 2 -132 -237 -628 -355 -269 -137 -361 -313 -342 -102 151 266 271 154 181 49 107 448 562 474 427 364 163 218 370 405 201 102 -19 -51 98 253 67 64 53 -207 8 291 11 -94 -131 -54 -151 -105 90 208 57 -104 -186 -292 -323 -128 SQ 20240306T145251.0Z 8831.620034 115 1 49.54 2 79.65 106.36 70.77 160.12 0.00 1 0.00 1 0 15 2.204e-03 2.191e-03 8.033e-04 8.022e-04 3.169186e+03 5.065513e+01 2.267702e+02 -6.000000e+00 1.259865e+02 268.99 -2.00 20.00 -2.00 505.28 0.00e+00 1.596931e-03 2.214590e-05 8.972793e-05 -6.000000e+00 6.196909e-05 268.99 -2.00 20.00 -2.00 500.49 0.00e+00 6.307054e-01 1.650822e-02 3.102943e-02 -6.000000e+00 4.560270e-02 225.19 -2.00 3.47 -2.00 502.08 0.00e+00 5.351 0.003 489.00 513.00 1 7.1198e+00 1.2675e-03 7.3347e-03 -6.0000e+00 3.5045e-03 -1.3879e-03 3.1521e-04 7.6142e-04 -6.0000e+00 8.7905e-04 7.6918e-04 -2.6833e-04 1.0429e-04 4.8247e-05 -6.0000e+00 2.9728e-04 9.4754e-04 -1.7780e-05 11 1 0 11 32 0 99.74 23.51 2.06 0.00095 -0.00091 22 4 1 4 0 2251.490 26.73 19.99 23.51 14.77 24.7 872.50 -158 63 3 99 -15 37 19 152 343 15 -93 120 171 -90 -92 -284 -179 60 -5 -13 -25 -109 -31 118 412 97 101 169 152 -14 -103 -106 -88 189 265 117 -283 -473 70 310 8 230 109 69 315 9 109 -87 -4 142 139 -17 -211 -389 -53 11 -63 -14 -246 -55 250 287 126 59 -94 166 7 -245 -514 -222 -154 -73 -278 -181 -190 -87 -408 -355 -163 -57 20 72 -7 -91 -125 -102 -199 -151 -92 -211 -182 103 114 317 -60 41 -147 -96 63 36 -198 -814 -311 -312 -159 -214 -557 -296 274 256 134 192 292 -30 59 110 498 297 310 373 435 340 0 342 460 285 35 3 77 163 273 126 187 223 -219 234 93 8 -140 52 -134 -161 9 205 143 -66 -176 -565 -184 -367 -90 -155 62 3 99 -15 38 19 157 355 16 -95 123 174 -91 -92 -285 -181 62 -5 -14 -26 -114 -33 122 425 101 104 177 156 -14 -105 -107 -88 191 274 120 -293 -488 71 320 8 239 111 71 327 9 113 -90 -4 145 139 -17 -209 -385 -52 11 -64 -14 -252 -56 256 294 129 61 -97 168 7 -242 -516 -220 -152 -72 -274 -179 -189 -86 -403 -347 -157 -54 19 69 -7 -89 -123 -101 -194 -148 -90 -207 -180 102 115 318 -60 41 -143 -94 60 34 -186 -770 -299 -300 -156 -212 -556 -294 270 252 133 189 291 -30 60 112 499 298 310 378 435 336 0 336 452 281 35 3 75 160 267 122 179 217 -209 223 90 8 -137 51 -134 -159 9 207 144 -67 -176 -557 -182 -361 -89 SQ 20240306T153409.0Z 8831.648715 140 1 19.17 2 72.29 113.77 68.70 169.38 0.00 1 0.00 1 0 15 2.766e-03 2.742e-03 1.050e-03 1.048e-03 1.627676e+03 6.322280e+01 1.101151e+02 -6.000000e+00 1.581045e+02 268.99 -2.00 20.00 -2.00 505.27 0.00e+00 5.702730e-04 2.891441e-05 3.253126e-05 -6.000000e+00 7.777646e-05 268.99 -2.00 20.00 -2.00 500.50 0.00e+00 3.528686e-01 2.163077e-02 1.747245e-02 -6.000000e+00 5.737856e-02 225.19 -2.00 3.47 -2.00 502.08 0.00e+00 3.245 0.001 489.00 513.00 1 6.8909e+00 1.6610e-03 4.2793e-03 -6.0000e+00 4.4056e-03 3.2749e-03 4.1706e-04 4.3352e-04 -6.0000e+00 1.1118e-03 1.2981e-03 8.6721e-04 1.3772e-04 1.8429e-05 -6.0000e+00 3.7460e-04 7.1355e-03 -7.1312e-05 12 1 1 12 1 1 99.60 23.53 2.06 0.00714 0.01315 7 4 1 4 0 2395.610 26.83 19.98 23.53 14.32 24.8 871.15 900000 -275 -11 345 -114 87 1 162 139 16 -113 -76 -98 -102 -96 75 -198 127 155 -103 24 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