File name: Pandora154s1_SaltLakeCityUT_20240726_L2Fit_fwvt1c8d20240627p1-8.txt File generation date: 20250107T211836.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Jeffrey Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 154 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora154_OF_v3d20220401.txt Instrument calibration file used: Pandora154s1_CF_v8d20240627.txt Level 1 file used: Pandora154s1_SaltLakeCityUT_20240726_L1_smca1c8d20240627p1-8.txt Full location name: University of Utah, William Browning Building Short location name: SaltLakeCityUT Country of location: United States Location latitude [deg]: 40.7663 Location longitude [deg]: -111.8478 Location altitude [m]: 1455 Local noon date: 20240726 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: New AnaFld, based on Lab Session 1. First and last pixel inside fitting window: 1656 1805 Nominal wavelengths inside fitting window [nm]: 492.0745 492.1954 492.3163 492.4372 492.5581 492.6789 492.7998 492.9206 493.0414 493.1622 493.2830 493.4037 493.5244 493.6452 493.7659 493.8866 494.0072 494.1279 494.2485 494.3691 494.4897 494.6103 494.7309 494.8514 494.9720 495.0925 495.2130 495.3335 495.4540 495.5744 495.6948 495.8153 495.9357 496.0560 496.1764 496.2968 496.4171 496.5374 496.6577 496.7780 496.8982 497.0185 497.1387 497.2589 497.3791 497.4993 497.6195 497.7396 497.8598 497.9799 498.1000 498.2200 498.3401 498.4601 498.5802 498.7002 498.8202 498.9401 499.0601 499.1801 499.3000 499.4199 499.5398 499.6596 499.7795 499.8993 500.0192 500.1390 500.2588 500.3785 500.4983 500.6180 500.7377 500.8575 500.9771 501.0968 501.2165 501.3361 501.4557 501.5753 501.6949 501.8145 501.9340 502.0536 502.1731 502.2926 502.4121 502.5315 502.6510 502.7704 502.8898 503.0092 503.1286 503.2480 503.3673 503.4866 503.6059 503.7252 503.8445 503.9638 504.0830 504.2022 504.3214 504.4406 504.5598 504.6790 504.7981 504.9172 505.0363 505.1554 505.2745 505.3936 505.5126 505.6316 505.7506 505.8696 505.9886 506.1075 506.2265 506.3454 506.4643 506.5832 506.7020 506.8209 506.9397 507.0585 507.1773 507.2961 507.4149 507.5336 507.6523 507.7711 507.8898 508.0084 508.1271 508.2457 508.3644 508.4830 508.6016 508.7201 508.8387 508.9572 509.0758 509.1943 509.3128 509.4312 509.5497 509.6681 509.7865 509.9049 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240726T132155.3Z 8973.556890 212 1 50.14 2 79.77 73.35 40.51 214.06 0.00 1 0.00 1 0 22 3.360e-03 3.343e-03 1.431e-04 1.430e-04 6.114942e+03 9.910901e+00 4.115620e+02 -6.000000e+00 2.018754e+02 282.59 -2.00 20.00 -2.00 505.30 0.00e+00 1.098850e-03 4.077079e-06 6.846338e-05 -6.000000e+00 9.746614e-05 282.59 -2.00 20.00 -2.00 500.57 0.00e+00 3.284830e-01 2.940276e-03 4.731102e-02 -6.000000e+00 6.983954e-02 231.46 -2.00 3.47 -2.00 502.15 0.00e+00 5.405 0.003 489.00 513.00 1 3.8506e+00 2.2616e-04 7.8212e-03 -6.0000e+00 5.3773e-03 -1.6679e-02 5.6640e-05 1.1499e-03 -6.0000e+00 1.3666e-03 2.0697e-02 -3.5504e-04 1.7808e-05 4.5037e-05 -6.0000e+00 4.4209e-04 1.1074e-02 -1.3827e-04 10 0 0 10 0 0 49.63 20.17 1.35 0.01107 0.00861 432 85 1 4 0 116.040 25.68 20.01 20.17 26.52 12.2 854.32 -564 -355 -27 111 106 302 608 685 485 256 169 156 -118 -278 -307 -311 -184 162 301 100 63 168 267 406 410 291 292 253 -224 -615 -506 -423 -239 243 296 -61 -218 -87 -89 -73 -42 50 139 242 342 312 197 112 51 -231 -526 -673 -708 -608 -224 -34 -44 -39 12 104 292 483 473 401 280 81 0 9 -72 -330 -419 -338 -261 -68 -1 -234 -530 -468 -382 -378 -372 -394 -435 -427 -147 -148 -227 -204 -135 -100 -40 222 497 394 181 127 140 0 -251 -522 -791 -786 -489 -132 -163 -341 -405 -372 -248 8 171 155 224 339 414 504 734 787 603 430 265 155 247 447 378 280 207 129 190 367 192 -69 -116 -219 -286 -102 25 -108 -98 17 131 162 226 239 268 217 -59 -398 -539 -529 -541 -344 -26 109 106 301 614 696 494 259 169 160 -119 -279 -307 -312 -181 162 306 103 65 175 279 425 430 305 304 260 -227 -614 -499 -417 -239 248 308 -63 -223 -88 -90 -76 -43 50 141 247 352 322 202 114 51 -233 -521 -657 -686 -592 -222 -34 -43 -39 12 106 297 491 481 408 284 82 0 9 -72 -327 -413 -334 -259 -68 -1 -234 -527 -459 -371 -366 -361 -384 -427 -423 -143 -144 -222 -200 -133 -98 -40 221 497 394 180 124 138 0 -237 -490 -744 -750 -477 -128 -162 -342 -408 -372 -248 8 172 153 223 341 420 513 749 804 614 435 265 154 243 438 372 276 204 128 187 360 187 -69 -115 -215 -281 -101 24 -107 -98 17 134 163 228 242 270 218 -61 -403 -540 -527 SQ 20240726T132727.0Z 8973.560729 215 1 50.12 2 78.77 74.20 41.08 215.93 0.00 1 0.00 1 0 22 3.296e-03 3.283e-03 1.351e-04 1.350e-04 5.597957e+03 9.285669e+00 3.759538e+02 -6.000000e+00 1.980412e+02 282.59 -2.00 20.00 -2.00 505.30 0.00e+00 1.013574e-03 3.844928e-06 6.307060e-05 -6.000000e+00 9.561679e-05 282.59 -2.00 20.00 -2.00 500.58 0.00e+00 2.837014e-01 2.773859e-03 4.413522e-02 -6.000000e+00 6.851694e-02 231.46 -2.00 3.47 -2.00 502.15 0.00e+00 4.961 0.002 489.00 513.00 1 3.7953e+00 2.1320e-04 7.2043e-03 -6.0000e+00 5.2754e-03 -1.6477e-02 5.3481e-05 1.0647e-03 -6.0000e+00 1.3408e-03 2.3201e-02 -3.0367e-04 1.6883e-05 3.9767e-05 -6.0000e+00 4.3370e-04 1.1003e-02 -1.4336e-04 10 0 0 10 0 0 35.73 20.22 1.33 0.01100 0.00890 480 94 1 4 0 104.400 25.68 20.02 20.22 27.24 12.2 856.88 -595 -333 -35 78 72 289 573 639 503 225 183 125 -100 -255 -281 -328 -187 142 300 119 39 186 287 417 454 312 301 230 -236 -618 -507 -395 -228 237 280 -46 -184 -77 -82 -91 -59 55 136 252 384 313 198 126 26 -195 -511 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-228 -283 -90 26 -103 -90 3 93 102 195 241 251 222 -44 -389 -537 -506 SQ 20240726T133308.9Z 8973.564686 218 1 50.14 2 77.73 75.07 41.69 217.82 0.00 1 0.00 1 0 15 3.240e-03 3.234e-03 1.285e-04 1.284e-04 5.064929e+03 8.734064e+00 3.416036e+02 -6.000000e+00 1.946929e+02 282.59 -2.00 20.00 -2.00 505.29 0.00e+00 8.495702e-04 3.666557e-06 5.406229e-05 -6.000000e+00 9.399932e-05 282.59 -2.00 20.00 -2.00 500.58 0.00e+00 2.560939e-01 2.642610e-03 4.007516e-02 -6.000000e+00 6.735670e-02 231.46 -2.00 3.47 -2.00 502.15 0.00e+00 4.571 0.002 489.00 513.00 1 3.7491e+00 2.0325e-04 6.5922e-03 -6.0000e+00 5.1861e-03 -1.6419e-02 5.0995e-05 9.6822e-04 -6.0000e+00 1.3180e-03 2.5602e-02 -3.3443e-04 1.6121e-05 3.5947e-05 -6.0000e+00 4.2636e-04 1.1013e-02 -1.4087e-04 10 0 0 10 0 0 39.85 20.27 1.32 0.01101 0.00869 528 104 1 4 0 94.950 25.79 20.01 20.27 28.03 12.1 860.16 -568 -339 -42 91 51 282 585 640 457 211 166 165 -97 -278 -267 -312 -197 156 292 109 19 209 265 417 432 276 287 238 -209 -595 -450 -396 -201 239 269 -56 -202 -83 -54 -97 -20 28 114 222 365 312 184 108 44 -192 -499 -664 -738 -564 -211 -33 -26 -64 0 76 311 460 474 383 263 80 3 38 -95 -292 -393 -332 -243 -83 5 -263 -467 -459 -325 -402 -380 -351 -455 -408 -180 -157 -252 -205 -130 -104 -31 206 451 356 184 110 115 -16 -249 -474 -729 -756 -475 -122 -140 -348 -418 -387 -238 11 185 151 220 338 383 533 702 751 558 438 289 147 252 440 388 257 159 100 174 361 170 -31 -115 -176 -284 -79 30 -109 -92 -6 119 94 201 237 243 209 -48 -373 -540 -512 -552 -321 -40 91 51 284 597 658 471 217 168 165 -96 -273 -261 -307 -196 158 301 114 19 214 272 428 444 283 293 248 -215 -600 -448 -394 -204 246 274 -58 -208 -85 -55 -98 -20 29 116 229 378 324 190 111 44 -190 -498 -652 -720 -553 -210 -32 -26 -65 0 78 318 470 485 391 267 81 3 37 -92 -291 -390 -330 -235 -81 5 -257 -452 -453 -317 -392 -371 -344 -437 -395 -175 -154 -249 -202 -129 -103 -31 208 456 359 185 109 111 -15 -239 -450 -695 -730 -455 -120 -140 -343 -412 -380 -239 11 182 151 221 343 391 546 722 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