File name: Pandora88s1_SanAntonioTX_20250212_L2Fit_fout2c2d20240901p1-8.txt File generation date: 20250213T065303.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 88 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora88_OF_v2d20240227.txt Instrument calibration file used: Pandora88s1_CF_v2d20240901.txt Level 1 file used: Pandora88s1_SanAntonioTX_20250212_L1_smca1c2d20240901p1-8.txt Full location name: University of Texas San Antonio Downtown Campus Short location name: SanAntonioTX Country of location: USA Location latitude [deg]: 29.4229 Location longitude [deg]: -98.5025 Location altitude [m]: 230 Local noon date: 20250212 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0435 305.1841 305.3247 305.4653 305.6059 305.7464 305.8870 306.0275 306.1680 306.3086 306.4491 306.5895 306.7300 306.8705 307.0110 307.1514 307.2918 307.4323 307.5727 307.7131 307.8535 307.9939 308.1342 308.2746 308.4150 308.5553 308.6956 308.8359 308.9762 309.1165 309.2568 309.3971 309.5373 309.6776 309.8178 309.9581 310.0983 310.2385 310.3787 310.5189 310.6590 310.7992 310.9393 311.0795 311.2196 311.3597 311.4998 311.6399 311.7800 311.9201 312.0601 312.2002 312.3402 312.4803 312.6203 312.7603 312.9003 313.0403 313.1802 313.3202 313.4601 313.6001 313.7400 313.8799 314.0198 314.1597 314.2996 314.4395 314.5793 314.7192 314.8590 314.9988 315.1386 315.2785 315.4182 315.5580 315.6978 315.8376 315.9773 316.1170 316.2568 316.3965 316.5362 316.6759 316.8155 316.9552 317.0949 317.2345 317.3741 317.5138 317.6534 317.7930 317.9326 318.0721 318.2117 318.3513 318.4908 318.6303 318.7699 318.9094 319.0489 319.1884 319.3278 319.4673 319.6067 319.7462 319.8856 320.0250 320.1644 320.3038 320.4432 320.5826 320.7220 320.8613 321.0006 321.1400 321.2793 321.4186 321.5579 321.6972 321.8364 321.9757 322.1149 322.2542 322.3934 322.5326 322.6718 322.8110 322.9502 323.0893 323.2285 323.3676 323.5068 323.6459 323.7850 323.9241 324.0632 324.2023 324.3413 324.4804 324.6194 324.7585 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250212T175326.6Z 9174.745447 409 1 53.66 2 44.84 160.94 133.17 338.17 0.00 1 0.00 1 0 17 8.884e-03 6.748e-03 1.569e-03 1.057e-03 1.782368e-01 5.255162e-04 2.005356e-03 -6.000000e+00 4.912868e-03 225.00 -2.00 3.23 -2.00 314.96 0.00e+00 3.750708e-04 4.571575e-05 2.777216e-05 -6.000000e+00 2.194186e-04 283.82 -2.00 20.00 -2.00 314.38 0.00e+00 1.408 0.000 302.00 328.00 3 4.9501e+00 1.3393e-03 1.5985e-02 -6.0000e+00 1.2137e-02 3.6634e-02 1.4908e-03 8.3039e-03 -6.0000e+00 1.3191e-02 4.2531e-03 8.5680e-04 4.0945e-03 -6.0000e+00 7.8754e-03 -5.0888e-03 3.8917e-04 1.1800e-03 -6.0000e+00 3.4211e-03 7.9099e-04 1.1033e-04 2.7623e-05 1.3675e-05 -6.0000e+00 2.2014e-04 8.9243e-03 0.0000e+00 11 8 0 10 0 0 99.97 23.92 0.36 0.00892 0.00975 65 7 1 5 0 825.510 32.75 20.00 23.92 26.01 0.0 984.73 -1546 -488 -1453 -1582 -2420 665 -536 -401 875 -660 -416 -1748 -1348 -1176 533 1237 -68 1183 829 476 1731 774 1540 1072 603 54 843 260 127 238 1264 1704 1900 -219 -2478 -3104 -2044 -928 -451 -73 -489 -826 -473 -533 -640 -923 -628 -640 -788 -360 570 700 1060 613 611 761 682 671 652 256 546 1118 1242 1612 706 -233 -354 -1286 -267 37 324 357 248 938 386 -381 -690 -1878 -975 -624 -1266 -930 -1501 -1713 -784 -469 -6 99 725 674 581 376 -219 -594 -141 275 172 1068 608 86 -242 -729 -1043 -750 -486 -833 -602 -569 -250 354 564 590 566 410 -206 -72 -284 44 214 473 -38 173 583 319 822 397 -153 4 281 192 37 -146 -241 -232 -260 261 -110 328 351 -126 -266 -500 -596 -495 -167 -512 -519 -682 187 -161 -122 294 -238 -144 -603 -512 -499 230 581 -33 576 417 247 906 399 796 546 319 30 465 134 64 115 632 885 1057 -121 -1370 -1633 -1168 -555 -300 -53 -394 -688 -381 -433 -514 -743 -522 -510 -608 -270 440 576 907 522 536 670 612 602 571 222 484 1052 1190 1644 730 -219 -321 -1121 -235 35 340 372 261 951 392 -370 -598 -1612 -833 -559 -1205 -974 -1606 -1893 -873 -563 -7 124 911 824 688 427 -239 -603 -146 295 203 1320 775 109 -304 -854 -1192 -863 -587 -1021 -766 -758 -330 486 782 831 804 541 -261 -87 -339 54 269 642 -52 233 808 426 1077 498 -182 5 341 247 48 -195 -323 -317 -359 380 -158 481 527 -187 -399 -730 -841 SS 20250212T175800.2Z 9174.748614 412 1 8.27 2 44.53 162.46 133.53 339.53 0.00 1 0.00 1 0 17 1.067e-02 8.122e-03 5.515e-03 3.752e-03 1.814191e-01 1.869237e-03 2.038310e-03 -6.000000e+00 5.900748e-03 225.00 -2.00 3.23 -2.00 314.91 0.00e+00 3.459084e-04 1.607310e-04 1.807101e-05 -6.000000e+00 2.635177e-04 283.82 -2.00 20.00 -2.00 314.33 0.00e+00 1.401 0.000 302.00 328.00 3 5.2175e+00 4.7589e-03 1.6004e-02 -6.0000e+00 1.4577e-02 5.1841e-02 5.2994e-03 8.4477e-03 -6.0000e+00 1.5843e-02 -3.2653e-03 3.0453e-03 4.1702e-03 -6.0000e+00 9.4587e-03 -1.7246e-03 1.3786e-03 1.2038e-03 -6.0000e+00 4.1093e-03 6.0370e-04 1.0315e-04 9.8146e-05 1.4132e-05 -6.0000e+00 2.6439e-04 8.2260e-03 0.0000e+00 12 9 1 12 1 1 999.00 23.93 0.24 0.00823 0.00900 2 2 1 5 0 2753.290 32.75 20.00 23.93 26.43 0.0 985.73 -2210 -677 580 -1834 -2009 2674 -981 -2237 157 -228 -1369 -2126 -302 -1015 733 2485 -129 433 1870 1488 1566 366 1368 2243 681 329 513 -474 201 -519 587 1222 1053 405 -2674 -3372 -2656 -193 -2027 -192 -479 -687 -332 -1042 -702 -1143 -1456 -359 -1119 701 445 764 1260 439 720 179 1367 436 1441 258 776 543 1267 2046 299 -460 -151 -1520 -209 -105 515 861 533 1545 1279 151 -299 -844 -1473 -686 -2090 -941 -1989 -2192 -712 -35 -343 -62 1027 515 759 10 -1475 -313 -305 901 -215 993 1095 -345 -584 -697 -489 -921 50 -1074 63 -659 -302 794 727 570 529 401 -235 -90 -637 245 -222 587 -57 -111 389 294 561 61 35 -248 557 -615 376 394 -284 199 -56 -4 -195 569 377 -264 -277 -324 -719 -736 -240 207 -622 -582 761 -280 -715 55 -85 -492 -757 -117 -408 324 1184 -64 218 956 730 782 180 726 1157 369 185 291 -252 103 -258 302 652 561 228 -1407 -1817 -1448 -117 -1395 -144 -371 -549 -272 -868 -575 -940 -1170 -291 -882 528 351 640 1031 381 642 162 1242 399 1274 228 697 493 1232 1998 299 -442 -139 -1349 -187 -101 519 906 568 1579 1303 140 -262 -727 -1281 -623 -2033 -946 -2169 -2468 -802 -42 -418 -78 1303 639 908 11 -1560 -320 -321 972 -245 1184 1407 -444 -708 -826 -562 -1073 60 -1334 81 -847 -402 1098 1018 812 727 534 -301 -110 -772 304 -282 767 -78 -151 520 396 708 77 42 -287 679 -767 487 526 -384 272 -78 -5 -284 840 571 -393 -399 -475 -1021 SS 20250212T180209.7Z 9174.751501 415 1 53.93 2 44.27 163.85 133.84 340.79 0.00 1 0.00 1 0 17 8.271e-03 6.441e-03 4.853e-04 3.516e-04 1.762405e-01 1.756625e-04 1.995667e-03 -6.000000e+00 4.574016e-03 225.00 -2.00 3.23 -2.00 314.62 0.00e+00 3.676519e-04 1.429218e-05 1.443517e-05 -6.000000e+00 2.042722e-04 283.82 -2.00 20.00 -2.00 314.06 0.00e+00 1.395 0.000 302.00 328.00 3 2.8786e+00 4.4609e-04 1.5834e-02 -6.0000e+00 1.1300e-02 2.4582e-02 4.9637e-04 8.2370e-03 -6.0000e+00 1.2281e-02 1.6054e-03 2.8529e-04 4.0613e-03 -6.0000e+00 7.3320e-03 -2.9847e-03 1.2778e-04 1.1752e-03 -6.0000e+00 3.1853e-03 6.4214e-03 1.3428e-04 9.1371e-06 1.4033e-05 -6.0000e+00 2.0495e-04 8.4043e-03 0.0000e+00 11 8 0 10 0 0 99.99 23.95 0.36 0.00840 0.00941 514 58 1 5 0 104.910 32.75 20.00 23.95 26.67 0.0 987.14 -109 -312 -233 -1978 -2971 -1437 -673 552 1004 -286 -1452 -1321 -536 -330 599 356 99 663 861 1376 951 678 1197 1096 537 694 318 87 -637 372 1255 1197 1889 -124 -2200 -2495 -2033 -1085 -488 -153 -537 -884 -523 -706 -216 -496 -399 -404 -783 -450 564 492 845 914 744 846 749 569 411 343 571 1026 1219 1706 679 -252 -571 -934 -54 277 423 469 135 542 219 -228 -530 -1447 -1026 -985 -1091 -1025 -1827 -1687 -1004 -607 -86 75 657 652 532 360 -16 -234 -6 158 227 891 627 117 -137 -566 -905 -587 -502 -756 -631 -578 -217 309 538 580 585 264 13 -123 -76 -138 87 325 86 -20 460 279 598 373 110 408 425 288 248 -149 -107 -286 -84 121 -143 200 232 -140 -182 -512 -695 -41 -118 -90 -772 -999 -484 -220 198 399 -114 -561 -537 -223 -153 289 177 50 341 455 746 528 368 652 632 304 406 189 51 -339 200 658 656 1102 -73 -1272 -1367 -1218 -692 -333 -117 -431 -734 -446 -608 -183 -421 -330 -320 -630 -352 454 404 721 785 659 753 681 518 366 302 513 939 1201 1715 693 -244 -526 -821 -48 269 437 489 142 575 220 -214 -487 -1235 -874 -898 -1067 -1060 -1967 -1869 -1138 -715 -103 92 822 794 619 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