File name: Pandora88s1_SanAntonioTX_20250219_L2Fit_fout2c2d20240901p1-8.txt File generation date: 20250220T065321.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 88 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora88_OF_v2d20240227.txt Instrument calibration file used: Pandora88s1_CF_v2d20240901.txt Level 1 file used: Pandora88s1_SanAntonioTX_20250219_L1_smca1c2d20240901p1-8.txt Full location name: University of Texas San Antonio Downtown Campus Short location name: SanAntonioTX Country of location: USA Location latitude [deg]: 29.4229 Location longitude [deg]: -98.5025 Location altitude [m]: 230 Local noon date: 20250219 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0435 305.1841 305.3247 305.4653 305.6059 305.7464 305.8870 306.0275 306.1680 306.3086 306.4491 306.5895 306.7300 306.8705 307.0110 307.1514 307.2918 307.4323 307.5727 307.7131 307.8535 307.9939 308.1342 308.2746 308.4150 308.5553 308.6956 308.8359 308.9762 309.1165 309.2568 309.3971 309.5373 309.6776 309.8178 309.9581 310.0983 310.2385 310.3787 310.5189 310.6590 310.7992 310.9393 311.0795 311.2196 311.3597 311.4998 311.6399 311.7800 311.9201 312.0601 312.2002 312.3402 312.4803 312.6203 312.7603 312.9003 313.0403 313.1802 313.3202 313.4601 313.6001 313.7400 313.8799 314.0198 314.1597 314.2996 314.4395 314.5793 314.7192 314.8590 314.9988 315.1386 315.2785 315.4182 315.5580 315.6978 315.8376 315.9773 316.1170 316.2568 316.3965 316.5362 316.6759 316.8155 316.9552 317.0949 317.2345 317.3741 317.5138 317.6534 317.7930 317.9326 318.0721 318.2117 318.3513 318.4908 318.6303 318.7699 318.9094 319.0489 319.1884 319.3278 319.4673 319.6067 319.7462 319.8856 320.0250 320.1644 320.3038 320.4432 320.5826 320.7220 320.8613 321.0006 321.1400 321.2793 321.4186 321.5579 321.6972 321.8364 321.9757 322.1149 322.2542 322.3934 322.5326 322.6718 322.8110 322.9502 323.0893 323.2285 323.3676 323.5068 323.6459 323.7850 323.9241 324.0632 324.2023 324.3413 324.4804 324.6194 324.7585 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250219T150755.0Z 9181.630498 300 1 53.08 2 66.63 118.89 72.77 231.27 0.00 1 0.00 1 0 17 6.204e-02 1.039e-02 1.214e-02 2.520e-03 3.262491e-01 1.237510e-03 3.624219e-03 -6.000000e+00 3.429809e-02 225.38 -2.00 3.23 -2.00 317.81 0.00e+00 1.533648e-03 2.086560e-04 3.387224e-04 -6.000000e+00 1.534198e-03 284.01 -2.00 20.00 -2.00 317.07 0.00e+00 2.502 0.000 302.00 328.00 3 5.1408e+00 3.2809e-03 2.8718e-02 -6.0000e+00 8.4786e-02 6.8135e-02 3.7210e-03 1.5344e-02 -6.0000e+00 9.2193e-02 -7.4251e-03 2.3752e-03 7.6572e-03 -6.0000e+00 5.5036e-02 -3.6776e-03 1.2370e-03 2.3736e-03 -6.0000e+00 2.3830e-02 1.7603e-04 -5.6967e-04 6.7364e-05 2.2098e-05 -6.0000e+00 1.5387e-03 2.4774e-02 0.0000e+00 12 9 8 11 8 0 99.99 22.81 0.21 0.02477 0.02049 22 2 1 5 0 2412.310 32.00 20.40 22.81 2.68 1.0 879.34 -17906 -7296 -15329 4015 -395 53022 8210 -20200 -519 -11229 11261 -9417 -12732 -9576 -1479 11668 3008 6160 1522 -5166 7873 8899 4043 -487 1114 -1926 5089 4341 6346 2212 636 3900 2575 424 -5372 -7695 -2129 -942 -3487 1296 -1070 279 -1601 -930 -3725 -3109 -1069 9 -2237 1889 1021 -161 2195 -308 165 1043 242 1403 1740 678 1058 1756 1736 2652 1293 242 2515 -1296 -1598 -997 364 118 256 2358 488 -1624 -438 -2222 -606 1147 -1366 -488 -1883 -1316 16 -1399 86 -280 592 572 860 65 -1145 -843 -478 1582 726 1073 183 -653 -843 -967 -712 -1053 -854 -1419 -728 -558 -584 725 1283 -117 364 421 -389 644 -491 -66 295 1106 -144 33 537 1097 1377 403 -108 -534 179 -156 -128 48 -751 -106 -649 713 -38 623 645 -310 -472 -824 -277 -1461 -594 -1409 285 -25 1942 504 -1842 -44 -1120 877 -935 -1530 -1309 -218 1709 504 1055 287 -1083 1480 1621 794 -107 252 -471 1176 948 1257 459 148 955 709 115 -1549 -2190 -636 -292 -1340 566 -526 141 -787 -461 -1889 -1582 -575 5 -1186 965 564 -90 1260 -194 107 681 163 933 1123 436 696 1240 1347 2052 1032 179 1846 -964 -1253 -826 330 112 243 2102 412 -1251 -326 -1595 -447 953 -1218 -482 -1891 -1362 17 -1673 100 -336 713 666 985 69 -1124 -850 -473 1714 886 1372 256 -908 -1103 -1166 -838 -1258 -1050 -1850 -983 -793 -819 1076 2038 -182 551 634 -543 879 -672 -94 417 1662 -225 51 799 1560 1963 556 -141 -693 250 -222 -194 76 -1214 -175 -1083 1243 -69 1138 1134 -564 -825 -1391 -447 SS 20250219T151406.8Z 9181.634801 304 1 53.18 2 65.45 119.95 73.81 232.25 0.00 1 0.00 1 0 17 6.825e-02 1.215e-02 1.391e-02 2.979e-03 3.134327e-01 1.463175e-03 3.481044e-03 -6.000000e+00 3.773891e-02 225.38 -2.00 3.23 -2.00 317.77 0.00e+00 1.400272e-03 2.455420e-04 4.325347e-04 -6.000000e+00 1.687790e-03 284.01 -2.00 20.00 -2.00 317.02 0.00e+00 2.391 0.000 302.00 328.00 3 5.4827e+00 3.8781e-03 2.7468e-02 -6.0000e+00 9.3293e-02 7.7580e-02 4.3980e-03 1.4703e-02 -6.0000e+00 1.0143e-01 -6.8160e-03 2.7906e-03 7.3539e-03 -6.0000e+00 6.0553e-02 -6.3695e-03 1.4455e-03 2.2282e-03 -6.0000e+00 2.6226e-02 1.4105e-04 -3.8706e-04 7.9629e-05 2.1098e-05 -6.0000e+00 1.6925e-03 2.3207e-02 0.0000e+00 12 8 8 10 0 0 99.94 22.81 0.45 0.02321 0.02030 29 3 1 5 0 1833.510 32.00 20.37 22.81 2.75 1.0 879.54 -21477 -2291 -16159 8321 -636 55749 7411 -20625 -1613 -13396 18881 -13241 -9431 -11714 -3591 7992 713 9472 3957 -1709 13831 10814 5220 -2523 701 -2215 8334 5694 6003 2951 -848 4359 2056 113 -5987 -8782 -2712 -953 -4215 902 -264 959 -749 -1075 -4549 -2755 -1637 -817 -756 159 2767 -1024 1841 -813 -1196 1105 663 1943 883 63 1526 1624 1934 2835 2823 146 2913 -989 -1633 -1177 151 -53 -74 2780 811 -1471 -1576 -2751 -84 1626 -1349 -325 -1949 -743 5 -1105 67 -508 -72 834 1224 685 -1586 -1022 -483 1913 840 929 255 -603 -1035 -1561 -1305 -1565 -2 -1255 -1146 -475 -980 1278 1234 -500 482 551 -567 743 -585 402 -99 1347 -363 339 1087 839 1620 534 94 -773 85 -432 -534 -23 -612 -98 -662 978 3 866 421 81 -325 -1070 -615 -1928 -188 -1582 597 -43 2089 482 -1983 -144 -1432 1426 -1423 -1137 -1688 -556 1244 125 1598 739 -351 2487 1960 1027 -574 161 -548 1881 1235 1200 609 -199 1055 564 33 -1715 -2492 -804 -320 -1605 389 -126 472 -390 -569 -2479 -1487 -862 -418 -383 80 1449 -603 1112 -538 -755 754 427 1343 600 42 1044 1098 1429 2257 2283 111 2014 -692 -1206 -996 139 -52 -72 2517 697 -1154 -1116 -2032 -63 1256 -1213 -323 -1961 -765 5 -1319 82 -608 -86 1038 1397 718 -1560 -1034 -475 2046 1013 1170 350 -822 -1330 -2000 -1526 -1856 -3 -1605 -1526 -663 -1443 1838 1908 -809 750 803 -822 984 -778 548 -145 2093 -550 499 1671 1241 2242 716 129 -1051 115 -635 -835 -35 -947 -156 -1125 1733 5 1507 749 140 -578 -1848 -1018 SS 20250219T152800.3Z 9181.644448 313 1 53.41 2 62.86 122.41 76.20 234.37 0.00 1 0.00 1 0 17 1.851e-02 7.265e-03 4.314e-03 1.528e-03 2.871440e-01 7.519971e-04 3.177111e-03 -6.000000e+00 1.024204e-02 225.38 -2.00 3.23 -2.00 316.91 0.00e+00 7.030486e-04 9.999101e-05 1.336963e-04 -6.000000e+00 4.578489e-04 284.01 -2.00 20.00 -2.00 316.18 0.00e+00 2.181 0.000 302.00 328.00 3 4.6820e+00 1.9633e-03 2.5057e-02 -6.0000e+00 2.5320e-02 5.3205e-02 2.2095e-03 1.3401e-02 -6.0000e+00 2.7525e-02 -6.0400e-03 1.3208e-03 6.6248e-03 -6.0000e+00 1.6431e-02 -2.7243e-03 6.5623e-04 1.9322e-03 -6.0000e+00 7.1203e-03 4.0489e-04 4.8967e-05 4.0347e-05 1.9311e-05 -6.0000e+00 4.5905e-04 1.9855e-02 0.0000e+00 11 8 0 10 0 0 99.97 22.81 0.30 0.01986 0.02022 40 4 1 5 0 1335.180 32.00 19.60 22.81 3.23 0.9 881.82 -7379 -801 -7194 -1824 -2132 9470 -494 -4861 1883 -5612 1334 -2901 -4222 -3304 -69 3758 697 2058 896 587 4488 2802 1760 424 529 -625 1542 1217 845 267 572 2244 1421 -415 -3508 -4420 -2396 -809 -804 -281 -723 -708 -436 -906 -1454 -1239 -719 -532 -1094 3 1218 -93 1581 313 760 1168 344 1396 724 569 1562 1452 1596 2226 1024 -364 440 -988 -622 -339 322 251 349 1350 438 -525 -880 -1582 -1322 87 -1345 -892 -1711 -1610 -521 -1097 152 -16 580 253 611 216 -584 -637 -252 775 134 897 419 -227 -476 -906 -716 -842 -416 -747 -641 -439 -290 558 854 317 512 367 -171 267 -323 0 471 506 -75 -55 466 345 766 318 -53 -183 528 47 -110 132 -397 -179 -166 165 -210 486 363 4 -232 -833 -365 -969 -108 -1071 -240 -243 930 -57 -660 268 -918 198 -459 -780 -635 -15 870 173 526 242 165 1239 769 501 131 170 -213 519 384 246 78 180 745 524 -164 -1303 -1595 -940 -329 -396 -151 -428 -435 -278 -586 -938 -802 -455 -328 -668 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