File name: Pandora88s1_SanAntonioTX_20250301_L2Fit_fout2c2d20240901p1-8.txt File generation date: 20250504T101641.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 88 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora88_OF_v2d20240227.txt Instrument calibration file used: Pandora88s1_CF_v2d20240901.txt Level 1 file used: Pandora88s1_SanAntonioTX_20250301_L1_smca1c2d20240901p1-8.txt Full location name: University of Texas San Antonio Downtown Campus Short location name: SanAntonioTX Country of location: USA Location latitude [deg]: 29.4229 Location longitude [deg]: -98.5025 Location altitude [m]: 230 Local noon date: 20250301 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0435 305.1841 305.3247 305.4653 305.6059 305.7464 305.8870 306.0275 306.1680 306.3086 306.4491 306.5895 306.7300 306.8705 307.0110 307.1514 307.2918 307.4323 307.5727 307.7131 307.8535 307.9939 308.1342 308.2746 308.4150 308.5553 308.6956 308.8359 308.9762 309.1165 309.2568 309.3971 309.5373 309.6776 309.8178 309.9581 310.0983 310.2385 310.3787 310.5189 310.6590 310.7992 310.9393 311.0795 311.2196 311.3597 311.4998 311.6399 311.7800 311.9201 312.0601 312.2002 312.3402 312.4803 312.6203 312.7603 312.9003 313.0403 313.1802 313.3202 313.4601 313.6001 313.7400 313.8799 314.0198 314.1597 314.2996 314.4395 314.5793 314.7192 314.8590 314.9988 315.1386 315.2785 315.4182 315.5580 315.6978 315.8376 315.9773 316.1170 316.2568 316.3965 316.5362 316.6759 316.8155 316.9552 317.0949 317.2345 317.3741 317.5138 317.6534 317.7930 317.9326 318.0721 318.2117 318.3513 318.4908 318.6303 318.7699 318.9094 319.0489 319.1884 319.3278 319.4673 319.6067 319.7462 319.8856 320.0250 320.1644 320.3038 320.4432 320.5826 320.7220 320.8613 321.0006 321.1400 321.2793 321.4186 321.5579 321.6972 321.8364 321.9757 322.1149 322.2542 322.3934 322.5326 322.6718 322.8110 322.9502 323.0893 323.2285 323.3676 323.5068 323.6459 323.7850 323.9241 324.0632 324.2023 324.3413 324.4804 324.6194 324.7585 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250301T143413.0Z 9191.607095 82 1 53.93 2 70.78 110.61 83.89 92.13 0.00 1 0.00 1 0 17 2.502e-02 6.190e-03 1.225e-03 2.739e-04 3.830942e-01 1.350487e-04 4.196402e-03 -6.000000e+00 1.388214e-02 226.04 -2.00 3.23 -2.00 317.79 0.00e+00 7.572592e-04 2.257804e-05 1.618726e-04 -6.000000e+00 6.195712e-04 284.41 -2.00 20.00 -2.00 317.04 0.00e+00 3.002 0.000 302.00 328.00 3 5.3195e-01 3.5928e-04 3.4247e-02 -6.0000e+00 3.4367e-02 -1.4469e-02 4.0690e-04 1.7997e-02 -6.0000e+00 3.7330e-02 -4.7449e-03 2.5848e-04 8.8889e-03 -6.0000e+00 2.2278e-02 7.5156e-04 1.3438e-04 2.6102e-03 -6.0000e+00 9.6528e-03 1.0683e-02 1.1168e-04 7.1472e-06 2.5044e-05 -6.0000e+00 6.2017e-04 1.4123e-02 0.0000e+00 10 0 0 10 0 0 98.08 23.89 0.29 0.01412 0.01496 1398 157 1 5 0 38.570 32.75 20.00 23.89 22.09 0.0 967.60 -7472 -5842 -6284 -7146 -11930 -7637 -11418 -7468 -4139 -6318 -7002 -7578 -4415 -3009 -1253 -154 -815 561 1020 1296 1604 377 1250 1476 735 992 221 146 -1188 314 1468 2026 2246 72 -2230 -2652 -1874 -1034 -512 37 -226 -466 -85 -312 288 -83 -163 -268 -726 -286 753 738 1004 1186 862 1010 886 448 277 209 688 1285 1606 2231 1009 -34 -335 -854 64 401 565 496 144 460 -31 -497 -982 -1777 -1302 -1170 -1221 -1027 -1916 -1791 -1136 -569 32 131 793 762 654 368 -69 -297 25 64 154 879 570 -54 -291 -780 -1048 -602 -601 -799 -706 -515 -119 324 583 582 514 274 9 -149 24 -64 162 269 -57 19 482 330 539 300 27 430 477 271 225 -150 -149 -244 -78 60 -120 210 268 -138 -176 -452 -585 -496 -429 -490 -534 -817 -488 -821 -583 -355 -599 -663 -756 -460 -369 -179 -25 -142 103 197 240 304 71 242 310 165 234 54 34 -257 68 351 533 611 22 -629 -784 -565 -358 -200 16 -110 -224 -42 -160 146 -43 -84 -137 -374 -149 419 423 612 733 561 671 608 309 187 139 465 886 1160 1765 794 -27 -246 -622 49 335 502 443 129 413 -27 -393 -742 -1362 -992 -980 -1116 -1008 -1983 -1849 -1250 -647 36 156 946 883 728 392 -72 -297 27 71 184 1099 754 -71 -376 -966 -1228 -704 -749 -1019 -939 -701 -166 468 886 892 799 415 13 -208 33 -89 232 401 -88 28 725 480 763 422 36 586 685 399 346 -235 -240 -395 -131 105 -213 380 482 -248 -310 -767 -985 SS 20250301T143924.3Z 9191.610698 85 1 53.94 2 69.72 111.39 82.78 92.73 0.00 1 0.00 1 0 17 2.082e-02 6.165e-03 9.092e-04 2.385e-04 3.656270e-01 1.177301e-04 4.022801e-03 -6.000000e+00 1.155310e-02 226.04 -2.00 3.23 -2.00 317.52 0.00e+00 6.748489e-04 1.836391e-05 1.371896e-04 -6.000000e+00 5.156148e-04 284.41 -2.00 20.00 -2.00 316.77 0.00e+00 2.856 0.000 302.00 328.00 3 4.3206e-01 3.1122e-04 3.2608e-02 -6.0000e+00 2.8601e-02 -1.4890e-02 3.5126e-04 1.7174e-02 -6.0000e+00 3.1067e-02 -2.6866e-03 2.1760e-04 8.4593e-03 -6.0000e+00 1.8540e-02 1.4237e-04 1.1173e-04 2.4564e-03 -6.0000e+00 8.0334e-03 1.3855e-02 1.1673e-04 6.2455e-06 2.4211e-05 -6.0000e+00 5.1611e-04 1.4000e-02 0.0000e+00 10 0 0 10 0 0 98.25 23.90 0.30 0.01400 0.01488 1509 170 1 5 0 35.740 32.75 20.00 23.90 22.65 0.0 970.74 -5156 -4493 -4879 -7338 -9344 -9111 -6480 -5771 -4184 -4744 -5831 -5693 -3500 -2503 71 47 -181 736 1156 1892 1491 880 1704 1463 936 872 824 89 -956 429 1407 1053 1867 -31 -2525 -3140 -2530 -1600 -436 10 -367 -407 -98 -381 213 56 40 -194 -536 -258 891 852 1108 1139 902 932 749 430 238 104 597 1183 1471 2106 921 -71 -336 -875 -9 390 508 583 143 430 83 -465 -890 -1659 -1181 -1132 -1225 -1014 -1878 -1804 -1082 -567 43 176 740 736 570 399 -75 -178 24 -15 111 864 463 -72 -309 -733 -1075 -627 -557 -789 -731 -489 -177 346 585 601 574 272 -27 -135 11 -47 182 248 -3 9 488 332 488 288 -16 372 520 271 244 -98 -98 -248 -66 86 -110 208 237 -145 -189 -477 -593 -429 -378 -434 -634 -790 -748 -560 -559 -411 -506 -622 -632 -449 -376 12 9 -35 150 247 421 342 200 396 370 232 228 220 23 -246 110 366 303 597 -10 -833 -1003 -829 -602 -184 5 -183 -213 -53 -211 117 31 22 -106 -296 -144 499 522 682 753 595 627 520 300 162 70 409 872 1136 1695 772 -56 -261 -671 -7 328 456 548 136 391 74 -388 -706 -1263 -937 -946 -1120 -997 -1949 -1874 -1196 -650 49 211 894 864 640 427 -77 -177 26 -16 132 1084 616 -96 -399 -906 -1257 -733 -695 -1010 -946 -668 -247 503 893 925 867 401 -38 -186 15 -65 260 369 -5 13 733 481 688 403 -21 501 716 395 370 -152 -155 -395 -110 147 -190 364 423 -253 -322 -805 -990 SS 20250301T144442.7Z 9191.614383 88 1 53.93 2 68.65 112.20 81.65 93.34 0.00 1 0.00 1 0 17 1.646e-02 6.165e-03 8.131e-04 2.434e-04 3.489638e-01 1.201073e-04 3.839677e-03 -6.000000e+00 9.135505e-03 226.04 -2.00 3.23 -2.00 317.30 0.00e+00 6.038761e-04 1.751877e-05 1.186882e-04 -6.000000e+00 4.077019e-04 284.41 -2.00 20.00 -2.00 316.55 0.00e+00 2.721 0.000 302.00 328.00 3 6.2440e-01 3.1582e-04 3.1067e-02 -6.0000e+00 2.2616e-02 -1.4488e-02 3.5586e-04 1.6345e-02 -6.0000e+00 2.4565e-02 -2.0889e-03 2.1667e-04 8.0596e-03 -6.0000e+00 1.4660e-02 1.1576e-04 1.0979e-04 2.3357e-03 -6.0000e+00 6.3526e-03 1.3262e-02 1.2769e-04 6.3662e-06 2.3220e-05 -6.0000e+00 4.0809e-04 1.3731e-02 0.0000e+00 10 0 0 10 0 0 98.94 23.92 0.29 0.01373 0.01469 1286 144 1 5 0 41.930 32.75 20.00 23.92 23.35 0.0 973.73 -4225 -2645 -3605 -5358 -7396 -6401 -5502 -3832 -2616 -3103 -4677 -4485 -2371 -1691 489 386 417 977 1553 1749 1651 1013 1556 1153 619 605 500 -396 -1205 -242 864 615 1709 -242 -2816 -3323 -2506 -1528 -408 150 -335 -445 -110 -173 235 -62 -34 -224 -582 -320 811 785 1083 1093 915 939 752 476 357 193 652 1206 1536 2058 834 -80 -402 -890 29 424 558 574 225 530 95 -435 -804 -1747 -1191 -1099 -1188 -1059 -1897 -1777 -1095 -562 -59 117 737 712 501 368 -61 -228 -11 67 180 855 472 -48 -271 -744 -971 -518 -595 -793 -724 -539 -157 344 608 572 552 248 -52 -136 15 -44 163 264 36 41 495 319 480 306 46 373 520 259 279 -96 -107 -255 -75 77 -105 198 274 -187 -180 -512 -588 -389 -268 -386 -553 -678 -621 -571 -400 -306 -393 -593 -589 -357 -298 91 82 94 231 385 417 405 246 387 312 177 182 154 -116 -329 -66 257 186 571 -88 -969 -1105 -918 -598 -180 75 -175 -244 -62 -100 135 -36 -20 -128 -333 -184 469 496 689 744 622 651 538 342 250 134 460 914 1219 1705 717 -64 -318 -694 24 362 510 550 209 490 85 -368 -646 -1345 -952 -965 -1094 -1050 -1987 -1862 -1222 -650 -69 137 873 846 570 398 -63 -236 -11 74 214 1073 627 -63 -350 -917 -1133 -604 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