File name: Pandora88s1_SanAntonioTX_20250416_L2Fit_fout2c2d20240901p1-8.txt File generation date: 20250504T102529.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 88 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora88_OF_v2d20240227.txt Instrument calibration file used: Pandora88s1_CF_v2d20240901.txt Level 1 file used: Pandora88s1_SanAntonioTX_20250416_L1_smca1c2d20240901p1-8.txt Full location name: University of Texas San Antonio Downtown Campus Short location name: SanAntonioTX Country of location: USA Location latitude [deg]: 29.4229 Location longitude [deg]: -98.5025 Location altitude [m]: 230 Local noon date: 20250416 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0435 305.1841 305.3247 305.4653 305.6059 305.7464 305.8870 306.0275 306.1680 306.3086 306.4491 306.5895 306.7300 306.8705 307.0110 307.1514 307.2918 307.4323 307.5727 307.7131 307.8535 307.9939 308.1342 308.2746 308.4150 308.5553 308.6956 308.8359 308.9762 309.1165 309.2568 309.3971 309.5373 309.6776 309.8178 309.9581 310.0983 310.2385 310.3787 310.5189 310.6590 310.7992 310.9393 311.0795 311.2196 311.3597 311.4998 311.6399 311.7800 311.9201 312.0601 312.2002 312.3402 312.4803 312.6203 312.7603 312.9003 313.0403 313.1802 313.3202 313.4601 313.6001 313.7400 313.8799 314.0198 314.1597 314.2996 314.4395 314.5793 314.7192 314.8590 314.9988 315.1386 315.2785 315.4182 315.5580 315.6978 315.8376 315.9773 316.1170 316.2568 316.3965 316.5362 316.6759 316.8155 316.9552 317.0949 317.2345 317.3741 317.5138 317.6534 317.7930 317.9326 318.0721 318.2117 318.3513 318.4908 318.6303 318.7699 318.9094 319.0489 319.1884 319.3278 319.4673 319.6067 319.7462 319.8856 320.0250 320.1644 320.3038 320.4432 320.5826 320.7220 320.8613 321.0006 321.1400 321.2793 321.4186 321.5579 321.6972 321.8364 321.9757 322.1149 322.2542 322.3934 322.5326 322.6718 322.8110 322.9502 323.0893 323.2285 323.3676 323.5068 323.6459 323.7850 323.9241 324.0632 324.2023 324.3413 324.4804 324.6194 324.7585 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250416T151947.6Z 9237.638745 321 1 53.61 2 48.99 102.52 105.73 248.02 0.00 1 0.00 1 0 17 2.287e-02 1.161e-02 6.423e-03 3.159e-03 1.975544e-01 1.580848e-03 2.186272e-03 -6.000000e+00 1.284838e-02 229.35 -2.00 3.23 -2.00 316.15 0.00e+00 8.709594e-04 1.742642e-04 9.601814e-05 -6.000000e+00 5.727797e-04 287.05 -2.00 20.00 -2.00 315.39 0.00e+00 1.521 0.000 302.00 328.00 3 6.5053e+00 4.1158e-03 1.7546e-02 -6.0000e+00 3.2026e-02 5.6047e-02 4.5989e-03 9.3724e-03 -6.0000e+00 3.4687e-02 1.5550e-03 2.6585e-03 4.5642e-03 -6.0000e+00 2.0678e-02 -7.1907e-03 1.2489e-03 1.3514e-03 -6.0000e+00 8.9190e-03 1.4223e-04 -1.2914e-04 8.4103e-05 1.3454e-05 -6.0000e+00 5.6735e-04 1.4023e-02 0.0000e+00 12 8 8 10 0 0 99.99 24.76 0.49 0.01402 0.01305 41 5 1 5 0 1307.390 33.25 20.00 24.76 26.51 0.0 984.08 -5386 2101 -1889 -376 -5551 11074 124 -8054 -368 -5287 2299 -903 -4655 -5725 139 4931 2535 2919 873 -1889 4047 3732 3285 513 1402 332 3671 521 1658 680 72 3500 2085 -54 -6054 -7568 -870 1901 -958 873 429 96 121 -6003 -1555 -3756 151 -541 -624 226 -271 -250 1658 1517 481 1656 62 1223 2587 -317 696 907 1067 2306 1694 105 1196 -506 -1560 -943 694 -733 50 1565 1437 -1506 -25 -3346 -783 187 -2280 -1227 -838 -374 -201 -148 -160 457 -99 1267 470 -312 -863 -330 -929 1267 918 550 940 -159 -547 -617 -1528 -1688 -262 -1548 -308 9 -944 856 1276 381 355 819 -339 -539 -1602 115 332 793 -293 -108 1397 895 932 682 -749 393 -442 -363 -98 -307 -816 -830 -408 589 449 1008 553 -133 -865 -525 -169 -1137 446 -427 -78 -1033 1658 22 -1707 -80 -1285 497 -200 -1195 -1674 43 1609 864 1016 320 -735 1515 1367 1223 208 581 144 1554 212 605 243 27 1344 876 -24 -2621 -3160 -374 907 -512 542 292 68 88 -4680 -1147 -2835 107 -371 -416 146 -184 -182 1233 1191 393 1345 52 1016 2068 -258 575 800 930 2125 1578 90 1007 -413 -1325 -834 669 -750 51 1528 1320 -1393 -21 -2601 -599 160 -2226 -1200 -877 -402 -230 -183 -193 568 -126 1540 575 -349 -879 -339 -912 1335 1069 716 1213 -204 -720 -754 -1740 -1949 -331 -1933 -395 11 -1329 1246 1959 599 540 1150 -438 -695 -2051 150 427 1100 -428 -156 1957 1210 1282 897 -943 475 -571 -498 -130 -422 -1136 -1177 -613 928 729 1664 872 -222 -1404 -826 -256 SS 20250416T152412.2Z 9237.641808 324 1 43.07 2 48.05 103.25 106.59 248.44 0.00 1 0.00 1 0 17 2.045e-02 1.068e-02 5.915e-03 3.081e-03 1.947180e-01 1.546119e-03 2.142147e-03 -6.000000e+00 1.148751e-02 229.35 -2.00 3.23 -2.00 316.00 0.00e+00 9.273575e-04 1.658623e-04 1.386225e-04 -6.000000e+00 5.120751e-04 287.05 -2.00 20.00 -2.00 315.28 0.00e+00 1.493 0.000 302.00 328.00 3 6.3177e+00 4.0141e-03 1.7211e-02 -6.0000e+00 2.8634e-02 6.0679e-02 4.4751e-03 9.1714e-03 -6.0000e+00 3.1012e-02 -4.0985e-03 2.5842e-03 4.4534e-03 -6.0000e+00 1.8488e-02 -4.3003e-03 1.2095e-03 1.3038e-03 -6.0000e+00 7.9748e-03 1.7719e-04 1.5753e-04 8.2136e-05 1.3222e-05 -6.0000e+00 5.0721e-04 1.3502e-02 0.0000e+00 12 9 9 12 1 1 100.00 24.77 0.20 0.01350 0.01469 35 5 1 5 0 1196.330 33.25 19.99 24.77 26.66 0.0 984.55 -4183 1106 -1710 -405 -4673 11780 1093 -4539 1441 -5872 -695 -1612 -5391 -4281 495 2695 1376 2321 1856 -2115 4961 1496 3228 820 2560 -224 4060 348 -405 125 -77 3511 606 409 -5335 -5002 -2190 423 -725 1176 1055 -85 -371 -5181 -1584 -969 41 -141 -1913 17 654 -713 1400 936 568 1399 478 1033 1903 -920 879 1183 1368 2318 1400 330 45 -1241 -949 40 182 -38 239 1961 724 98 -754 -3520 -2086 -251 -1776 -1390 -1145 -624 -313 -521 -246 491 332 803 639 -441 -756 -790 -1095 808 640 559 1275 -195 -553 -689 -1632 -1742 -667 -1103 -230 -47 -327 624 1211 234 532 644 -227 -156 -515 58 629 585 -155 169 1209 1100 780 412 -880 116 -269 -272 -371 -798 -1013 -620 -532 697 359 1269 801 -315 -803 -558 -355 -962 261 -423 -92 -944 1919 209 -1016 338 -1565 -169 -392 -1516 -1340 166 974 467 879 662 -810 1804 604 1295 323 1025 -95 1669 152 -162 48 -31 1441 276 177 -2442 -2170 -1017 199 -412 775 758 -58 -263 -3896 -1137 -692 31 -102 -1366 12 466 -550 1103 715 449 1101 387 830 1479 -728 701 1005 1253 2250 1375 295 37 -983 -772 37 185 -40 257 2000 702 85 -648 -2872 -1696 -206 -1658 -1427 -1257 -703 -347 -626 -311 638 439 1025 752 -477 -803 -782 -1125 894 721 701 1711 -261 -700 -811 -1940 -1939 -814 -1431 -308 -66 -443 882 1801 356 779 874 -305 -192 -627 73 840 847 -219 236 1766 1545 1032 522 -1065 146 -334 -358 -513 -1143 -1468 -911 -771 1058 563 2014 1308 -507 -1255 -845 -518 SS 20250416T154922.8Z 9237.659292 337 1 0.41 2 42.76 107.79 111.55 250.78 0.00 1 0.00 1 0 17 8.965e-03 7.012e-03 2.346e-03 1.768e-03 1.708340e-01 8.992471e-04 1.915024e-03 -6.000000e+00 5.037795e-03 229.35 -2.00 3.23 -2.00 314.44 0.00e+00 3.641771e-04 7.043753e-05 1.745837e-05 -6.000000e+00 2.245085e-04 287.05 -2.00 20.00 -2.00 313.86 0.00e+00 1.360 0.000 302.00 328.00 3 1.1844e+00 2.2996e-03 1.5553e-02 -6.0000e+00 1.2558e-02 -1.9125e-03 2.5447e-03 8.1331e-03 -6.0000e+00 1.3599e-02 1.6395e-03 1.4623e-03 3.9539e-03 -6.0000e+00 8.1071e-03 -2.8440e-03 6.4601e-04 1.1274e-03 -6.0000e+00 3.4981e-03 3.6709e-02 3.3475e-04 4.5978e-05 1.3559e-05 -6.0000e+00 2.2237e-04 1.1690e-02 0.0000e+00 12 9 1 12 1 1 33.61 24.82 0.28 0.01169 0.01421 9 149 1 5 0 40.810 33.25 20.01 24.82 27.42 0.0 987.74 -984 -148 44 -2050 -2812 -1835 -935 -32 915 338 -1812 -1222 -161 -71 741 680 154 464 612 1960 1617 662 1084 802 324 756 795 -219 -447 346 1874 1111 1707 14 -2729 -2280 -1958 -907 -531 -69 -615 -842 -960 -764 -265 -433 -824 -871 -644 -665 894 678 1340 1207 662 991 1001 557 323 175 606 1060 1296 1915 535 -255 -811 -976 -178 253 314 479 244 405 468 20 -551 -1848 -1127 -1002 -1154 -780 -1931 -1662 -1275 -459 -132 11 514 797 237 575 233 -122 -113 -59 224 853 651 202 -292 -488 -1303 -642 -60 -639 -659 -383 -78 90 572 584 533 273 278 -380 -166 -269 103 309 -91 51 498 367 628 455 140 291 564 319 289 10 72 -329 -12 131 -86 297 111 -299 -155 -645 -768 -393 -63 19 -838 -1042 -677 -341 -13 384 143 -790 -522 -71 -33 370 355 82 251 340 1107 934 377 621 467 196 453 479 -129 -249 192 1024 638 1002 9 -1581 -1305 -1179 -592 -383 -54 -497 -703 -802 -642 -226 -370 -688 -720 -513 -534 713 559 1145 1053 597 896 896 500 293 157 540 975 1246 1897 537 -247 -739 -874 -162 247 320 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