File name: Pandora88s1_SanAntonioTX_20250419_L2Fit_fwvt1c2d20240901p1-8.txt File generation date: 20250504T103139.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 88 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora88_OF_v2d20240227.txt Instrument calibration file used: Pandora88s1_CF_v2d20240901.txt Level 1 file used: Pandora88s1_SanAntonioTX_20250419_L1_smca1c2d20240901p1-8.txt Full location name: University of Texas San Antonio Downtown Campus Short location name: SanAntonioTX Country of location: USA Location latitude [deg]: 29.4229 Location longitude [deg]: -98.5025 Location altitude [m]: 230 Local noon date: 20250419 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1621 1771 Nominal wavelengths inside fitting window [nm]: 492.0371 492.1579 492.2787 492.3995 492.5202 492.6409 492.7616 492.8823 493.0030 493.1237 493.2443 493.3649 493.4855 493.6061 493.7267 493.8473 493.9678 494.0883 494.2088 494.3293 494.4498 494.5703 494.6907 494.8111 494.9315 495.0519 495.1723 495.2926 495.4130 495.5333 495.6536 495.7739 495.8942 496.0144 496.1346 496.2549 496.3751 496.4953 496.6154 496.7356 496.8557 496.9758 497.0959 497.2160 497.3361 497.4561 497.5762 497.6962 497.8162 497.9362 498.0561 498.1761 498.2960 498.4159 498.5358 498.6557 498.7755 498.8954 499.0152 499.1350 499.2548 499.3746 499.4944 499.6141 499.7338 499.8535 499.9732 500.0929 500.2126 500.3322 500.4518 500.5714 500.6910 500.8106 500.9301 501.0497 501.1692 501.2887 501.4082 501.5277 501.6471 501.7665 501.8860 502.0054 502.1247 502.2441 502.3635 502.4828 502.6021 502.7214 502.8407 502.9599 503.0792 503.1984 503.3176 503.4368 503.5560 503.6752 503.7943 503.9134 504.0325 504.1516 504.2707 504.3898 504.5088 504.6278 504.7468 504.8658 504.9848 505.1037 505.2227 505.3416 505.4605 505.5794 505.6982 505.8171 505.9359 506.0547 506.1735 506.2923 506.4111 506.5298 506.6485 506.7672 506.8859 507.0046 507.1233 507.2419 507.3605 507.4791 507.5977 507.7163 507.8348 507.9534 508.0719 508.1904 508.3089 508.4273 508.5458 508.6642 508.7826 508.9010 509.0194 509.1378 509.2561 509.3745 509.4928 509.6111 509.7293 509.8476 509.9658 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250419T134015.8Z 9240.569628 256 1 9.27 2 69.90 88.00 65.29 210.07 0.00 1 0.00 1 0 15 3.123e-03 3.096e-03 9.372e-04 9.363e-04 3.814800e+03 5.649179e+01 2.718400e+02 -6.000000e+00 1.702276e+02 287.26 -2.00 20.00 -2.00 505.29 0.00e+00 7.475139e-04 2.564846e-05 4.533894e-05 -6.000000e+00 8.722966e-05 287.26 -2.00 20.00 -2.00 500.56 0.00e+00 2.349025e-01 1.798010e-02 2.584205e-02 -6.000000e+00 6.051489e-02 229.50 -2.00 3.23 -2.00 502.14 0.00e+00 2.879 0.000 489.00 513.00 1 5.8914e+00 1.3779e-03 4.7112e-03 -6.0000e+00 4.6406e-03 -1.4120e-02 3.5635e-04 6.5774e-04 -6.0000e+00 1.2096e-03 3.5071e-03 5.9409e-04 8.0379e-05 3.3868e-05 -6.0000e+00 2.7663e-04 1.1201e-02 -3.6817e-05 12 1 1 12 1 1 99.99 25.01 0.92 0.01120 0.01532 12 9 1 4 0 712.680 33.25 20.00 25.01 27.67 0.0 988.52 -762 -611 -481 53 329 454 689 688 227 402 222 139 -114 -321 -156 -374 -91 123 -91 84 109 201 31 238 415 281 346 255 8 -301 -584 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144 364 535 650 240 409 147 -84 40 57 284 274 358 313 320 134 69 127 -76 -290 -200 -134 -56 -96 53 145 153 287 129 284 306 230 -5 -298 -496 -560 -339 SQ 20250419T134410.0Z 9240.572338 259 1 1.57 2 69.05 88.47 65.71 210.87 0.00 1 0.00 1 0 22 3.367e-03 3.345e-03 1.696e-03 1.694e-03 3.543715e+03 1.016747e+02 2.532891e+02 -6.000000e+00 1.835682e+02 287.26 -2.00 20.00 -2.00 505.29 0.00e+00 6.494106e-04 4.640817e-05 4.016556e-05 -6.000000e+00 9.406920e-05 287.26 -2.00 20.00 -2.00 500.54 0.00e+00 2.044588e-01 3.259424e-02 2.404269e-02 -6.000000e+00 6.528313e-02 229.50 -2.00 3.23 -2.00 502.12 0.00e+00 2.770 0.000 489.00 513.00 1 3.9688e+00 2.4969e-03 4.4817e-03 -6.0000e+00 5.0059e-03 -1.2446e-02 6.4678e-04 6.1450e-04 -6.0000e+00 1.3054e-03 2.4452e-02 9.2292e-04 1.4551e-04 3.1667e-05 -6.0000e+00 2.9831e-04 1.3511e-02 -7.7652e-05 12 1 1 12 1 1 99.95 25.02 0.93 0.01351 0.01991 3 16 2 4 0 391.820 33.50 20.00 25.02 27.86 0.0 989.66 -285 -507 -181 -280 352 596 473 619 438 373 214 39 -83 -327 -51 -296 -366 -439 -8 -165 439 -272 -28 257 264 362 476 304 -331 -231 -396 -179 -4 218 267 522 -50 38 -140 -368 -151 -297 260 276 326 341 567 217 49 -293 -428 -1012 -508 -447 -485 -276 34 148 202 268 237 178 342 363 240 -71 23 -120 -226 -135 -656 -357 -355 282 54 -43 -170 -99 -633 -340 -242 -373 -241 -296 -499 -35 -320 133 -411 -64 337 391 218 209 233 193 277 23 -172 -720 -988 -397 -422 -164 -80 59 106 -342 -189 -424 -53 103 133 287 217 346 674 444 135 337 259 308 40 285 122 166 498 170 518 181 485 -12 -422 29 -177 -306 -67 -12 120 268 140 116 16 251 263 -7 37 89 -329 -684 -632 -275 -488 -176 -280 353 609 487 644 455 383 220 40 -83 -328 -51 -297 -367 -450 -8 -171 453 -283 -29 267 276 377 495 314 -340 -232 -390 -177 -4 221 278 540 -51 39 -143 -372 -155 -302 266 286 336 353 582 225 50 -298 -428 -989 -495 -437 -479 -277 35 152 207 274 242 180 347 369 242 -72 23 -120 -224 -131 -646 -352 -348 278 53 -43 -168 -95 -617 -328 -233 -360 -234 -289 -487 -34 -317 131 -407 -63 334 392 220 212 234 190 272 23 -165 -682 -931 -377 -405 -161 -80 59 107 -339 -185 -415 -52 102 133 291 218 349 682 453 137 338 260 303 40 283 121 164 490 168 508 178 475 -12 -408 28 -171 -297 -65 -12 120 267 141 117 16 253 265 -8 37 88 -321 -663 -616 SQ 20250419T135303.7Z 9240.578515 262 1 8.14 2 67.11 89.54 66.69 212.65 0.00 1 0.00 1 0 15 3.030e-03 3.001e-03 4.157e-04 4.153e-04 3.271706e+03 2.476666e+01 2.402971e+02 -6.000000e+00 1.651817e+02 287.26 -2.00 20.00 -2.00 505.29 0.00e+00 5.822749e-04 1.136909e-05 3.580781e-05 -6.000000e+00 8.464580e-05 287.26 -2.00 20.00 -2.00 500.56 0.00e+00 1.839938e-01 7.975858e-03 2.113138e-02 -6.000000e+00 5.873761e-02 229.50 -2.00 3.23 -2.00 502.13 0.00e+00 2.551 0.000 489.00 513.00 1 4.2697e+00 6.1100e-04 4.0906e-03 -6.0000e+00 4.5041e-03 -1.2416e-02 1.5841e-04 5.5608e-04 -6.0000e+00 1.1744e-03 1.8715e-02 8.5409e-04 3.5725e-05 2.9987e-05 -6.0000e+00 2.6843e-04 1.3264e-02 -6.8669e-05 12 1 1 12 1 1 99.99 25.03 0.91 0.01326 0.01919 64 48 1 4 0 125.150 33.50 20.00 25.03 28.45 0.0 992.23 -711 -480 -199 122 380 414 488 576 495 367 210 126 -87 -214 -401 -295 -111 -63 124 237 161 117 179 253 339 335 370 252 15 -361 -536 -482 -231 46 180 233 47 -71 -250 -188 -187 -127 -5 177 216 266 279 196 56 -139 -387 -779 -748 -750 -322 -182 -3 25 143 108 147 288 215 365 255 185 82 -30 -155 -272 -387 -311 -115 1 17 -44 -57 -166 -295 -416 -391 -294 -262 -179 -153 -126 -40 -141 -104 -142 -71 139 361 390 364 298 215 -21 -317 -596 -774 -620 -353 -127 73 85 -38 -237 -339 -386 -229 -48 142 170 285 441 488 417 375 309 125 34 50 155 144 328 208 204 248 345 200 76 -48 -206 -294 -246 -139 13 230 148 211 210 239 281 374 225 53 -212 -372 -619 -466 -686 -459 -196 121 387 423 500 597 513 376 215 128 -87 -214 -399 -295 -111 -64 127 244 166 121 185 261 352 349 384 260 15 -362 -536 -475 -231 47 187 241 49 -73 -255 -193 -191 -128 -5 183 222 275 287 202 57 -141 -385 -756 -727 -732 -316 -181 -3 25 147 110 149 294 218 370 260 187 82 -30 -152 -268 -378 -305 -112 1 16 -44 -55 -163 -285 -400 -377 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