File name: Pandora88s1_SanAntonioTX_20250814_L2Fit_fout2c2d20240901p1-8.txt File generation date: 20250815T064625.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Alberto Mestas-Nunez Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 88 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora88_OF_v3d20240227.txt Instrument calibration file used: Pandora88s1_CF_v2d20240901.txt Level 1 file used: Pandora88s1_SanAntonioTX_20250814_L1_smca1c2d20240901p1-8.txt Full location name: Durango Building, UTSA Downtown Campus, San Antonio, TX Short location name: SanAntonioTX Country of location: United States Location latitude [deg]: 29.4230 Location longitude [deg]: -98.5025 Location altitude [m]: 222 Local noon date: 20250814 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0435 305.1841 305.3247 305.4653 305.6059 305.7464 305.8870 306.0275 306.1680 306.3086 306.4491 306.5895 306.7300 306.8705 307.0110 307.1514 307.2918 307.4323 307.5727 307.7131 307.8535 307.9939 308.1342 308.2746 308.4150 308.5553 308.6956 308.8359 308.9762 309.1165 309.2568 309.3971 309.5373 309.6776 309.8178 309.9581 310.0983 310.2385 310.3787 310.5189 310.6590 310.7992 310.9393 311.0795 311.2196 311.3597 311.4998 311.6399 311.7800 311.9201 312.0601 312.2002 312.3402 312.4803 312.6203 312.7603 312.9003 313.0403 313.1802 313.3202 313.4601 313.6001 313.7400 313.8799 314.0198 314.1597 314.2996 314.4395 314.5793 314.7192 314.8590 314.9988 315.1386 315.2785 315.4182 315.5580 315.6978 315.8376 315.9773 316.1170 316.2568 316.3965 316.5362 316.6759 316.8155 316.9552 317.0949 317.2345 317.3741 317.5138 317.6534 317.7930 317.9326 318.0721 318.2117 318.3513 318.4908 318.6303 318.7699 318.9094 319.0489 319.1884 319.3278 319.4673 319.6067 319.7462 319.8856 320.0250 320.1644 320.3038 320.4432 320.5826 320.7220 320.8613 321.0006 321.1400 321.2793 321.4186 321.5579 321.6972 321.8364 321.9757 322.1149 322.2542 322.3934 322.5326 322.6718 322.8110 322.9502 323.0893 323.2285 323.3676 323.5068 323.6459 323.7850 323.9241 324.0632 324.2023 324.3413 324.4804 324.6194 324.7585 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250814T125921.0Z 9357.541216 228 1 53.68 2 78.68 80.00 34.44 251.35 0.00 1 0.00 1 0 17 4.356e-01 1.513e-02 2.264e-01 4.089e-03 5.759104e-01 2.142851e-03 6.582903e-03 -6.000000e+00 2.476349e-01 229.27 -2.00 3.23 -2.00 320.58 0.00e+00 2.233147e-03 8.926669e-04 3.830396e-03 -6.000000e+00 1.202738e-02 293.55 -2.00 20.00 -2.00 319.82 0.00e+00 4.917 0.001 302.00 328.00 3 3.3961e+00 6.9088e-03 5.7960e-02 -6.0000e+00 6.1614e-01 3.1536e-02 8.9940e-03 3.6764e-02 -6.0000e+00 6.6802e-01 -9.4639e-02 8.3164e-03 1.5725e-02 -6.0000e+00 3.9863e-01 3.2122e-02 4.1825e-03 4.0497e-03 -6.0000e+00 1.7226e-01 8.3121e-05 -2.1596e-04 1.0867e-04 5.4463e-05 -6.0000e+00 1.1040e-02 2.0774e-02 0.0000e+00 12 8 8 10 0 0 93.46 25.83 0.75 0.02077 0.01915 30 3 1 5 0 1789.130 34.00 19.99 25.83 32.05 0.0 1001.14 -123378 -50369 -18634 900000 -118798 900000 -72295 63679 271550 -88202 103387 900000 -41836 -77693 -42446 102852 29281 900000 7476 -62222 146235 24650 3489 223036 25076 34614 83411 40276 248 -3996 -10866 65289 4287 8555 -27931 -6920 -4319 18176 16466 25338 4519 3718 973 -38307 -6582 -25366 5361 2947 77 2510 11960 2730 6251 6541 1554 8896 -466 9449 6721 -2186 5213 -1724 1202 5031 4425 4620 10160 -2285 -1519 637 -180 -2759 1183 2895 680 -3365 -3622 -3604 -578 1878 -2245 977 -1459 755 1871 741 694 -395 449 -18 2501 513 -1329 -700 -1238 154 189 -161 178 -1753 -1101 -1457 -2168 -1966 102 -2230 -499 -622 -961 1632 -56 -465 466 2471 -925 -569 -348 982 696 425 -482 945 542 1158 1654 592 -183 -185 90 -465 -409 -175 -572 -309 -1011 233 744 982 564 172 -704 -863 -239 -1520 -347 -101 900000 -1506 900000 -629 254 1082 -1278 412 900000 -600 -2012 -964 656 432 900000 164 -2901 874 491 90 889 620 828 1263 899 8 -142 -494 1613 227 474 -2081 -408 -279 1101 1253 2151 533 471 134 -8029 -1012 -4831 763 439 12 410 1983 556 1335 1525 405 2230 -133 2451 1738 -607 1383 -539 413 1886 1763 1751 3563 -923 -599 288 -92 -1513 623 1424 315 -1447 -1582 -1557 -266 911 -1323 639 -1079 573 1510 598 589 -351 400 -16 2136 415 -1039 -544 -1068 139 195 -192 217 -2178 -1280 -1682 -2264 -2040 114 -2698 -575 -769 -1289 2365 -86 -755 750 3753 -1367 -849 -518 1507 1063 690 -795 1481 832 1835 2485 870 -260 -264 144 -778 -750 -319 -1093 -616 -2192 497 1618 2172 1275 375 -1563 -1825 -480 SS 20250814T130508.3Z 9357.545235 231 1 53.63 2 77.44 80.66 35.60 252.62 0.00 1 0.00 1 0 17 1.555e-01 7.665e-03 5.199e-02 1.952e-03 5.346168e-01 9.964495e-04 5.803809e-03 -6.000000e+00 8.791567e-02 229.27 -2.00 3.23 -2.00 319.97 0.00e+00 1.214540e-03 3.360256e-04 1.492347e-03 -6.000000e+00 4.068799e-03 293.55 -2.00 20.00 -2.00 319.14 0.00e+00 4.467 0.001 302.00 328.00 3 2.6706e+00 2.9810e-03 5.0769e-02 -6.0000e+00 2.1831e-01 -2.5046e-02 3.6963e-03 2.7136e-02 -6.0000e+00 2.3628e-01 -3.6892e-02 3.1519e-03 1.3191e-02 -6.0000e+00 1.4111e-01 1.1583e-02 1.6356e-03 3.5879e-03 -6.0000e+00 6.1036e-02 2.7615e-04 5.6838e-05 5.1296e-05 3.9621e-05 -6.0000e+00 3.8672e-03 2.0635e-02 0.0000e+00 11 8 0 10 0 0 86.98 25.83 0.36 0.02063 0.02106 76 9 1 5 0 705.630 33.75 20.00 25.83 32.16 0.0 1001.50 -50055 1360 -62731 12937 -103063 900000 -68577 -9594 -21158 -36840 -26662 -30083 -16288 -47690 -25404 -15650 -24079 22543 -3170 -26350 18896 -11605 6071 18239 -4137 -1157 4325 -4483 -15312 -11689 -4652 14777 -1755 2652 -11449 -3658 -3579 1785 5433 3222 771 81 -585 -9747 -1287 -6994 -311 539 -639 -1151 1115 1380 1008 2495 1408 2884 942 1683 1412 -1069 2195 -188 2051 2675 2662 1992 1772 -1082 169 834 882 459 1077 1243 492 -1247 -2776 -2145 -932 -1407 -999 21 -1645 -1120 -737 -107 340 173 952 992 906 104 -50 -1088 -826 -125 -205 623 413 -637 -667 -1230 -1398 -775 -747 -1365 -761 -508 -190 720 474 476 362 963 -252 -295 -220 196 345 230 -173 318 399 543 565 452 12 362 458 -263 43 -322 -221 -360 -257 90 4 548 474 -30 -230 -413 -480 -502 10 -979 91 -2059 900000 -1070 -95 -270 -603 -401 -515 -304 -1515 -798 -530 -976 631 -124 -1374 647 -534 247 729 -222 -64 235 -253 -918 -714 -312 942 -153 240 -1113 -322 -355 197 716 529 146 16 -115 -2148 -262 -1545 -65 113 -141 -266 280 386 307 817 495 1033 358 636 520 -397 812 -78 939 1257 1312 937 812 -517 86 493 537 295 688 818 301 -693 -1439 -1087 -508 -912 -690 16 -1336 -948 -669 -104 346 171 942 1019 862 92 -42 -920 -764 -123 -231 752 548 -853 -842 -1428 -1563 -862 -859 -1666 -969 -689 -260 1079 744 790 599 1518 -376 -439 -327 285 537 381 -290 514 629 824 862 667 17 514 687 -442 75 -596 -403 -687 -502 185 8 1126 992 -64 -464 -833 -929 SS 20250814T131028.6Z 9357.548942 234 1 53.84 2 76.29 81.28 36.68 253.74 0.00 1 0.00 1 0 17 1.774e-01 7.163e-03 7.267e-02 1.715e-03 4.958724e-01 8.699000e-04 5.381598e-03 -6.000000e+00 9.961900e-02 229.27 -2.00 3.23 -2.00 319.61 0.00e+00 1.639566e-03 2.619764e-04 1.238347e-03 -6.000000e+00 4.570816e-03 293.55 -2.00 20.00 -2.00 318.76 0.00e+00 4.118 0.001 302.00 328.00 3 2.7966e+00 2.5123e-03 4.6736e-02 -6.0000e+00 2.4768e-01 -2.4790e-02 3.0232e-03 2.4559e-02 -6.0000e+00 2.6804e-01 -2.1944e-02 2.4471e-03 1.2073e-02 -6.0000e+00 1.6045e-01 3.6648e-03 1.2937e-03 3.3917e-03 -6.0000e+00 6.9598e-02 3.4808e-04 7.8346e-05 4.5047e-05 3.5735e-05 -6.0000e+00 4.4042e-03 2.0603e-02 0.0000e+00 11 8 0 10 0 0 96.87 25.83 0.42 0.02060 0.02119 87 10 1 5 0 618.720 34.00 19.99 25.83 32.32 0.0 1002.61 -37549 -22698 -47813 8710 -67263 160092 -60883 -31238 -14206 -19530 -9982 -9038 -23418 -27732 -21999 -7689 -9632 -27 -112 -12501 11875 -4145 1590 12600 -3569 -2191 1082 525 -7667 -1748 -4479 6387 -1181 -1478 -8520 -7577 -2350 839 1532 3181 2433 461 882 -8109 -847 -5372 1575 -343 -1607 -347 2237 188 2439 325 675 2425 1003 1255 1726 -942 1725 1264 2065 2921 1076 1571 2121 -342 -11 452 1146 363 592 1013 486 -989 -2460 -2503 -1074 -1113 -1116 -557 -1760 -1075 -546 -16 25 -70 716 715 701 446 -132 -787 -274 110 236 509 461 -446 -606 -1080 -1047 -942 -540 -1155 -700 -674 -141 516 422 440 513 670 -389 -212 -150 310 282 122 -73 410 764 402 740 235 -156 226 377 -204 123 -351 -180 -479 -324 100 102 460 436 -56 -290 -380 -400 -565 -338 -984 98 -1429 348 -1324 -575 -252 -399 -187 -183 -678 -1035 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