File name: Pandora86s1_SantaCruz_20250803_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20250804T042534.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 86 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora86_OF_v3d20231204.txt Instrument calibration file used: Pandora86s1_CF_v2d20240531.txt Level 1 file used: Pandora86s1_SantaCruz_20250803_L1_smca1c2d20240531p1-8.txt Full location name: Santa Cruz de la Sierra Short location name: SantaCruz Country of location: Bolivia Location latitude [deg]: -17.7604 Location longitude [deg]: -63.1994 Location altitude [m]: 408 Local noon date: 20250803 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0112 305.1522 305.2931 305.4340 305.5750 305.7159 305.8568 305.9977 306.1386 306.2794 306.4203 306.5611 306.7020 306.8428 306.9836 307.1244 307.2652 307.4060 307.5468 307.6875 307.8283 307.9690 308.1098 308.2505 308.3912 308.5319 308.6726 308.8133 308.9539 309.0946 309.2352 309.3759 309.5165 309.6571 309.7977 309.9383 310.0789 310.2194 310.3600 310.5005 310.6411 310.7816 310.9221 311.0626 311.2031 311.3436 311.4840 311.6245 311.7650 311.9054 312.0458 312.1862 312.3266 312.4670 312.6074 312.7478 312.8881 313.0285 313.1688 313.3091 313.4495 313.5898 313.7301 313.8703 314.0106 314.1509 314.2911 314.4314 314.5716 314.7118 314.8520 314.9922 315.1324 315.2726 315.4127 315.5529 315.6930 315.8331 315.9732 316.1133 316.2534 316.3935 316.5336 316.6736 316.8137 316.9537 317.0938 317.2338 317.3738 317.5138 317.6537 317.7937 317.9337 318.0736 318.2136 318.3535 318.4934 318.6333 318.7732 318.9131 319.0529 319.1928 319.3326 319.4725 319.6123 319.7521 319.8919 320.0317 320.1715 320.3112 320.4510 320.5907 320.7305 320.8702 321.0099 321.1496 321.2893 321.4290 321.5686 321.7083 321.8479 321.9876 322.1272 322.2668 322.4064 322.5460 322.6855 322.8251 322.9647 323.1042 323.2437 323.3832 323.5228 323.6622 323.8017 323.9412 324.0807 324.2201 324.3595 324.4990 324.6384 324.7778 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250803T121336.7Z 9346.509452 127 1 13.16 2 69.83 63.17 135.54 163.95 0.00 1 0.00 1 0 17 2.031e-02 7.621e-03 6.125e-03 1.877e-03 3.247784e-01 9.310522e-04 3.389414e-03 -6.000000e+00 1.130766e-02 226.62 -2.00 3.04 -2.00 317.35 0.00e+00 9.879914e-04 1.385473e-04 3.110611e-04 -6.000000e+00 5.134814e-04 288.46 -2.00 20.00 -2.00 316.52 0.00e+00 2.869 0.000 302.00 328.00 3 2.9516e+00 2.4531e-03 3.0767e-02 -6.0000e+00 2.7991e-02 2.8434e-03 2.7639e-03 1.4436e-02 -6.0000e+00 3.0367e-02 -9.1814e-03 1.6854e-03 7.0825e-03 -6.0000e+00 1.8156e-02 9.3466e-04 8.5863e-04 2.0555e-03 -6.0000e+00 7.9358e-03 1.2389e-03 -7.1348e-05 4.9574e-05 1.9988e-05 -6.0000e+00 5.0867e-04 -1.5116e-02 0.0000e+00 12 9 1 12 1 1 93.67 25.41 0.36 -0.01512 -0.01565 18 8 1 5 0 692.100 34.00 20.00 25.41 27.52 4.4 982.30 900000 -2437 -5795 -1860 -8664 -6833 -5505 -364 -4872 -3581 -9577 -7493 -3167 431 1469 2625 114 1703 2775 1069 1836 221 776 2642 1399 1010 69 -1428 -2030 -1675 -629 -206 2139 -1546 -2306 -4898 -3658 -2535 -279 214 601 62 63 109 610 288 -309 -82 420 -1071 404 481 1040 1696 1438 1183 1189 344 27 -259 516 1236 1866 2409 1274 -7 368 -1449 398 269 133 729 262 563 82 -298 -1110 -2170 -1842 -1237 -1476 -819 -1838 -1853 -1353 -583 253 450 648 703 624 101 -511 -255 -438 -482 -274 836 305 -106 -314 -1213 -870 -885 -604 -1348 -617 -561 247 548 1181 998 958 514 158 -24 7 -62 276 190 152 344 460 479 632 361 -442 291 186 -198 -104 -376 -252 -463 33 31 -77 521 410 -212 -122 -541 -521 900000 -259 -618 -208 -923 -649 -530 -37 -591 -428 -1232 -935 -422 65 259 528 25 358 611 250 443 54 188 666 382 291 21 -420 -556 -440 -173 -63 700 -531 -769 -1675 -1202 -944 -114 105 312 35 34 60 335 160 -173 -45 241 -623 227 295 679 1102 986 831 859 239 20 -184 368 881 1453 1939 1090 -6 291 -1123 310 226 120 664 244 533 74 -255 -904 -1664 -1423 -1019 -1327 -782 -1853 -1951 -1439 -666 292 541 790 841 728 108 -528 -259 -463 -541 -315 1027 399 -141 -413 -1480 -1048 -1054 -754 -1748 -795 -761 337 799 1782 1518 1436 757 223 -32 10 -85 388 279 230 514 671 701 875 499 -606 384 254 -286 -155 -587 -386 -733 54 52 -132 911 709 -373 -206 -911 -842 SS 20250803T122649.5Z 9346.518629 133 1 10.05 2 67.04 61.59 134.59 160.15 0.00 1 0.00 1 0 41 1.781e-01 1.273e-01 8.967e-03 3.207e-03 2.726494e-01 1.574980e-03 3.967939e-03 -6.000000e+00 9.909599e-02 226.62 -2.00 3.04 -2.00 316.85 0.00e+00 -1.984126e-04 2.203030e-04 1.214151e-03 -6.000000e+00 4.501903e-03 288.46 -2.00 20.00 -2.00 316.04 0.00e+00 2.543 0.000 302.00 328.00 3 3.9557e+00 4.1368e-03 2.7678e-02 -6.0000e+00 2.4530e-01 6.7583e-02 4.6712e-03 1.4179e-02 -6.0000e+00 2.6616e-01 -6.9900e-02 2.7740e-03 7.6270e-03 -6.0000e+00 1.5913e-01 5.7380e-03 1.3770e-03 4.9973e-03 -6.0000e+00 6.9521e-02 6.6637e-04 8.8200e-03 8.3743e-05 4.2872e-05 -6.0000e+00 4.4594e-03 -1.2123e-02 0.0000e+00 12 9 9 12 1 1 87.82 25.43 0.18 -0.01212 0.05415 5 3 1 5 0 1673.650 34.00 20.00 25.43 28.09 4.4 986.14 900000 35780 27369 23071 19551 33055 30485 41825 35850 28358 23257 22661 38392 32519 35074 33271 22677 24017 24595 19617 23062 18516 23003 26067 22776 20649 19386 12591 13287 14636 21559 16631 21639 12712 6559 7867 16120 -128824 22072 20356 14441 12640 11911 10580 10344 9103 6355 7084 7873 7077 11199 9612 9393 8998 7252 8249 7766 3949 4422 4245 6520 9444 10636 8681 2489 -2160 -415 703 7295 8662 5326 4286 328 -1151 -2836 -4747 -4649 -3004 3367 5983 4221 4375 717 -455 2579 3193 1864 807 -141 -2351 -4304 -5140 -5228 -1310 3488 4007 3470 4262 384 -4534 -6217 -7261 -4353 2248 2818 -706 1195 703 2110 2973 2333 -1048 -3266 -5322 -5852 -4092 -14 1089 2628 1671 -919 -1858 -1278 -2665 -1998 -2812 -3757 1969 3760 2450 1822 -191 211 1536 3222 2121 1035 2191 353 -1876 -1089 -1440 738 900000 4643 3587 3210 2445 3463 3508 4865 4966 4452 3731 3727 6123 5741 6909 7349 5750 6233 6593 5722 6608 5432 6611 7758 6772 6527 6178 3980 4185 4485 6619 5309 7195 4757 2374 2739 5713 -136619 9663 10635 8073 7467 7300 6591 6411 5715 4004 4315 4662 4236 6866 6015 6213 6320 5332 6118 5549 2905 3152 3202 4652 7077 8593 7221 2182 -1799 -335 548 5734 7288 4774 4033 319 -1090 -2676 -4060 -3812 -2306 2576 5105 3879 4203 719 -481 2853 3583 2232 959 -169 -2764 -4972 -5745 -5632 -1324 3617 4360 4017 5211 494 -5942 -8086 -9157 -5018 2561 3516 -910 1584 938 2922 4196 3512 -1578 -4810 -7740 -8172 -5544 -18 1488 3652 2398 -1375 -2752 -1839 -3882 -2745 -3903 -4962 2505 5118 3462 2614 -287 321 2406 5106 3429 1727 3719 589 -3224 -1792 -2384 1172 SS 20250803T124133.6Z 9346.528861 138 1 5.02 2 63.98 59.69 133.32 156.11 0.00 1 0.00 1 0 17 1.688e-02 9.332e-03 4.463e-03 2.252e-03 2.617266e-01 1.121275e-03 2.737304e-03 -6.000000e+00 9.396577e-03 226.62 -2.00 3.04 -2.00 316.18 0.00e+00 6.591492e-04 1.251666e-04 8.540030e-05 -6.000000e+00 4.266154e-04 288.46 -2.00 20.00 -2.00 315.40 0.00e+00 2.266 0.000 302.00 328.00 3 2.9718e+00 2.8996e-03 2.4388e-02 -6.0000e+00 2.3261e-02 1.5202e-02 3.2432e-03 1.1575e-02 -6.0000e+00 2.5233e-02 -4.7039e-03 1.8840e-03 5.6631e-03 -6.0000e+00 1.5086e-02 -1.4092e-03 9.0043e-04 1.6402e-03 -6.0000e+00 6.5959e-03 2.3135e-03 -5.2803e-05 5.9304e-05 1.7114e-05 -6.0000e+00 4.2261e-04 -1.6689e-02 0.0000e+00 12 9 9 12 9 1 54.94 25.47 0.34 -0.01669 -0.01709 8 9 1 5 0 556.830 34.00 20.00 25.47 28.47 4.4 989.06 900000 -2933 -1872 -3462 -3370 -2220 385 -169 2024 326 -5914 -3923 -1099 -1310 -387 724 -688 2375 887 1071 523 275 1121 2227 15 935 109 -384 -690 -116 -402 -545 2191 -142 -3608 -3453 -3850 12704 -1019 -555 236 -643 -110 -819 300 342 -200 -702 -377 -337 688 106 281 1007 1046 674 785 855 132 4 44 1055 1230 2169 931 -155 161 -1369 194 261 48 256 256 527 20 -404 -773 -2609 -1233 -1460 -1809 -1303 -1954 -2066 -1029 -958 726 376 1057 1101 601 787 -162 -306 68 -497 60 668 576 -225 -22 -928 -1161 -1025 -835 -1133 -766 -725 359 293 945 1049 673 750 398 -7 219 -87 117 213 198 -49 488 312 461 314 196 528 233 -324 89 -329 -257 -611 124 109 -277 547 579 -333 -263 -553 -588 900000 -611 -408 -754 -647 -379 71 -32 424 76 -1473 -934 -277 -353 -119 232 -238 822 326 380 193 101 406 840 6 397 48 -163 -270 -43 -154 -227 966 -65 -1643 -1536 -1692 5757 -560 -327 156 -429 -76 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