File name: Pandora196s1_Sapporo_20220325_L2Fit_fout2c10d20220307p1-8.txt File generation date: 20250121T095113.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v10d20220307.txt Level 1 file used: Pandora196s1_Sapporo_20220325_L1_smca1c10d20220307p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20220325 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0528 305.1941 305.3353 305.4766 305.6178 305.7590 305.9003 306.0415 306.1826 306.3238 306.4650 306.6062 306.7473 306.8884 307.0296 307.1707 307.3118 307.4529 307.5940 307.7350 307.8761 308.0172 308.1582 308.2992 308.4402 308.5813 308.7223 308.8632 309.0042 309.1452 309.2861 309.4271 309.5680 309.7089 309.8498 309.9907 310.1316 310.2725 310.4134 310.5542 310.6951 310.8359 310.9767 311.1176 311.2584 311.3992 311.5399 311.6807 311.8215 311.9622 312.1030 312.2437 312.3844 312.5251 312.6658 312.8065 312.9472 313.0878 313.2285 313.3691 313.5097 313.6504 313.7910 313.9316 314.0721 314.2127 314.3533 314.4938 314.6344 314.7749 314.9154 315.0559 315.1964 315.3369 315.4774 315.6179 315.7583 315.8987 316.0392 316.1796 316.3200 316.4604 316.6008 316.7412 316.8815 317.0219 317.1622 317.3026 317.4429 317.5832 317.7235 317.8638 318.0040 318.1443 318.2846 318.4248 318.5650 318.7053 318.8455 318.9857 319.1258 319.2660 319.4062 319.5463 319.6865 319.8266 319.9667 320.1068 320.2469 320.3870 320.5271 320.6672 320.8072 320.9472 321.0873 321.2273 321.3673 321.5073 321.6473 321.7873 321.9272 322.0672 322.2071 322.3470 322.4870 322.6269 322.7667 322.9066 323.0465 323.1864 323.3262 323.4660 323.6059 323.7457 323.8855 324.0253 324.1651 324.3048 324.4446 324.5843 324.7241 324.8638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220324T224645.7Z 8118.949140 240 1 47.33 2 66.32 111.45 77.56 211.71 0.00 1 0.00 1 0 17 7.442e-02 6.890e-03 8.338e-02 5.135e-03 4.438413e-01 2.683608e-03 5.345833e-03 -6.000000e+00 4.302785e-02 226.62 -2.00 3.56 -2.00 319.88 0.00e+00 3.144813e-03 8.017870e-04 1.268699e-03 -6.000000e+00 1.849950e-03 276.27 -2.00 20.00 -2.00 319.33 0.00e+00 2.471 0.000 302.00 328.00 3 4.8909e+00 7.6500e-03 3.4156e-02 -6.0000e+00 1.0693e-01 4.2691e-02 9.1098e-03 2.3547e-02 -6.0000e+00 1.1588e-01 -2.0077e-02 7.7622e-03 1.3115e-02 -6.0000e+00 6.8802e-02 -1.2803e-03 4.0625e-03 5.0975e-03 -6.0000e+00 2.9544e-02 1.8545e-04 -1.6143e-04 1.4988e-04 5.5478e-05 -6.0000e+00 1.9722e-03 1.7096e-03 1.9927e-05 11 8 0 10 0 0 99.98 17.18 0.25 0.00171 0.00050 56 14 1 5 0 844.940 20.77 15.03 17.18 10.78 12.5 1021.61 1354 -24673 -13719 -32084 -31814 -37184 -25734 -20379 -15050 -13069 -29072 -12450 -6499 -7976 -2312 5298 -4953 -10360 -195 -1524 9715 -6459 -3920 -1277 -5107 110 47 -4620 -3468 -1695 -6105 1663 -2968 -40 -4600 -7024 -5808 -1937 539 1360 -381 -490 -492 -662 1382 -2283 -303 -1615 235 -586 3572 3556 2906 3921 542 -73 -773 -252 -1423 35 88 1397 2629 2325 1364 -106 1844 489 1588 1228 816 985 146 -7 -215 -796 -1597 -1997 -1682 -1280 -1310 -2154 -2081 -1111 -503 -169 298 733 679 779 784 541 38 -488 -256 350 565 208 247 -429 -531 -1351 -914 -733 -1643 -1072 -64 -657 636 569 648 566 198 -438 -291 -79 388 32 527 172 238 527 786 579 640 -121 -749 -233 -52 -358 -302 -824 -383 -101 119 250 702 164 195 -277 45 -696 18 -486 -262 -705 -631 -755 -499 -422 -330 -302 -787 -310 -185 -278 -92 228 -252 -601 -11 -91 539 -413 -252 -87 -383 8 4 -348 -254 -126 -539 154 -318 -4 -503 -783 -706 -266 88 254 -80 -109 -114 -159 327 -572 -74 -405 59 -153 970 1062 930 1336 198 -28 -300 -96 -544 13 34 590 1211 1174 708 -52 861 232 815 728 523 653 96 -5 -125 -417 -786 -990 -901 -795 -920 -1685 -1743 -964 -468 -166 307 765 704 770 724 465 31 -405 -234 355 641 261 328 -563 -649 -1527 -971 -815 -1973 -1327 -83 -904 931 896 1089 966 328 -697 -429 -111 556 48 843 287 394 840 1217 868 919 -168 -1015 -328 -80 -596 -536 -1514 -727 -198 250 542 1540 363 433 -590 92 -1376 SS 20220324T230824.1Z 8118.964168 260 1 16.61 2 62.69 115.90 79.69 215.94 0.00 1 0.00 1 0 17 4.340e-02 6.865e-03 2.685e-02 3.132e-03 3.929962e-01 1.606043e-03 4.721852e-03 -6.000000e+00 2.508938e-02 226.63 -2.00 3.56 -2.00 318.74 0.00e+00 1.383088e-03 3.466130e-04 4.516383e-04 -6.000000e+00 1.078910e-03 276.27 -2.00 20.00 -2.00 318.17 0.00e+00 2.168 0.000 302.00 328.00 3 4.3841e+00 4.3510e-03 2.9899e-02 -6.0000e+00 6.2347e-02 3.6258e-02 4.9777e-03 2.0425e-02 -6.0000e+00 6.7575e-02 -2.8048e-03 3.6343e-03 1.0400e-02 -6.0000e+00 4.0121e-02 -7.1554e-03 1.9355e-03 3.2830e-03 -6.0000e+00 1.7223e-02 4.4228e-04 -2.1127e-04 8.8642e-05 3.2507e-05 -6.0000e+00 1.1508e-03 2.2299e-03 -3.5614e-05 12 9 1 12 1 1 99.88 17.18 0.23 0.00223 0.00064 12 10 1 5 0 1263.470 20.77 15.01 17.18 11.39 12.5 1026.67 -21193 -8218 -14927 4967 -19175 -10055 -5363 -15596 4479 -13712 -1217 -20761 2843 -9652 2747 -1483 1549 -2274 738 2039 -2464 4426 -2352 1346 -2869 3004 -3654 -1858 -6579 1006 -1060 2121 3224 -1003 1764 -6455 -3209 -2054 822 -2739 460 -2068 216 -688 1279 960 568 666 -892 1121 327 1849 -124 1741 -476 689 -146 640 -335 1143 2455 2077 2226 1488 1231 -1078 -86 -617 1540 549 761 308 409 163 -171 -361 -1532 -993 -1730 -1086 -2216 -1403 -2162 -1331 -559 -354 529 1168 1042 97 837 273 -277 -584 37 72 342 43 243 -222 -1043 -901 -489 179 -893 -1339 -535 -588 195 771 377 560 573 -72 101 76 733 61 449 77 182 53 557 -89 484 -43 -187 402 52 -220 -207 -516 -289 278 252 -162 98 148 95 -20 -112 -631 -779 -296 -606 162 -707 -329 -178 -650 174 -675 -54 -1164 152 -686 205 -132 143 -233 77 220 -288 483 -283 168 -397 409 -536 -254 -902 132 -158 336 561 -192 310 -1205 -640 -476 221 -879 157 -762 81 -263 480 367 215 253 -345 436 139 831 -60 875 -252 371 -81 350 -180 614 1345 1228 1417 1017 850 -717 -56 -397 1043 418 621 258 336 130 -128 -249 -992 -637 -1200 -837 -1912 -1299 -2121 -1354 -599 -397 608 1361 1206 109 890 274 -264 -565 38 82 419 57 334 -297 -1346 -1085 -566 214 -1134 -1771 -733 -833 286 1201 609 912 910 -111 148 108 1035 89 694 123 288 82 854 -132 694 -60 -254 563 79 -347 -342 -864 -493 490 467 -306 187 287 183 -37 -203 -1115 SS 20220324T231326.3Z 8118.967666 263 1 48.07 2 61.87 116.98 80.22 216.90 0.00 1 0.00 1 0 17 8.120e-02 8.496e-03 7.404e-02 6.582e-03 3.849209e-01 3.401112e-03 4.659021e-03 -6.000000e+00 4.692438e-02 226.63 -2.00 3.56 -2.00 319.32 0.00e+00 1.806161e-03 8.529646e-04 5.463188e-04 -6.000000e+00 2.018298e-03 276.27 -2.00 20.00 -2.00 318.75 0.00e+00 2.110 0.000 302.00 328.00 3 5.6804e+00 9.4178e-03 2.9312e-02 -6.0000e+00 1.1661e-01 5.4892e-02 1.0921e-02 2.0199e-02 -6.0000e+00 1.2640e-01 -1.5855e-03 8.4457e-03 1.0439e-02 -6.0000e+00 7.5047e-02 -7.9302e-03 4.4743e-03 3.4615e-03 -6.0000e+00 3.2201e-02 1.2765e-04 -6.7599e-04 1.9235e-04 3.6281e-05 -6.0000e+00 2.1546e-03 3.0776e-03 -1.1877e-04 11 8 0 10 0 0 99.96 17.20 0.37 0.00308 -0.00200 42 11 1 5 0 1144.280 20.77 15.00 17.20 11.48 12.5 1027.62 -19599 34526 -17589 29033 -33468 19422 -44774 -21148 -10775 10629 -14652 -4820 5930 -3886 6338 4943 14407 -4418 8038 -2719 11516 -15758 5867 -2927 3475 10792 3057 7438 -3792 15056 -5740 10430 -3099 7387 -9398 621 -6434 -2996 -2249 -541 -922 -1008 606 -2703 749 972 442 -1090 -1033 -3124 1669 1210 -561 3358 719 2183 -1404 1219 -2361 1366 -3786 2610 653 1997 447 376 572 180 1474 1333 1860 270 1037 -909 -247 -1703 326 -2541 -2000 -676 -658 -1572 -1888 -158 -523 448 -149 1184 344 1183 136 -14 -1267 -172 -233 889 136 231 749 -727 -61 -1427 -192 -515 -912 -1527 -413 -514 326 1240 344 1015 191 113 -900 -528 -610 146 302 207 -21 22 823 -100 1319 -162 709 -394 51 -888 -93 -816 268 -18 111 -62 242 19 143 601 -100 -883 -591 695 -610 625 -1160 397 -1788 -765 -393 340 -596 -187 246 -212 370 335 944 -374 634 -249 944 -1664 522 -305 360 1082 333 747 -408 1357 -712 1223 -461 1046 -1452 86 -1061 -560 -505 -140 -262 -301 186 -867 232 305 138 -345 -333 -1053 570 460 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