File name: Pandora196s1_Sapporo_20220401_L2Fit_fout2c10d20220307p1-8.txt File generation date: 20250121T095535.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v10d20220307.txt Level 1 file used: Pandora196s1_Sapporo_20220401_L1_smca1c10d20220307p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20220401 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0528 305.1941 305.3353 305.4766 305.6178 305.7590 305.9003 306.0415 306.1826 306.3238 306.4650 306.6062 306.7473 306.8884 307.0296 307.1707 307.3118 307.4529 307.5940 307.7350 307.8761 308.0172 308.1582 308.2992 308.4402 308.5813 308.7223 308.8632 309.0042 309.1452 309.2861 309.4271 309.5680 309.7089 309.8498 309.9907 310.1316 310.2725 310.4134 310.5542 310.6951 310.8359 310.9767 311.1176 311.2584 311.3992 311.5399 311.6807 311.8215 311.9622 312.1030 312.2437 312.3844 312.5251 312.6658 312.8065 312.9472 313.0878 313.2285 313.3691 313.5097 313.6504 313.7910 313.9316 314.0721 314.2127 314.3533 314.4938 314.6344 314.7749 314.9154 315.0559 315.1964 315.3369 315.4774 315.6179 315.7583 315.8987 316.0392 316.1796 316.3200 316.4604 316.6008 316.7412 316.8815 317.0219 317.1622 317.3026 317.4429 317.5832 317.7235 317.8638 318.0040 318.1443 318.2846 318.4248 318.5650 318.7053 318.8455 318.9857 319.1258 319.2660 319.4062 319.5463 319.6865 319.8266 319.9667 320.1068 320.2469 320.3870 320.5271 320.6672 320.8072 320.9472 321.0873 321.2273 321.3673 321.5073 321.6473 321.7873 321.9272 322.0672 322.2071 322.3470 322.4870 322.6269 322.7667 322.9066 323.0465 323.1864 323.3262 323.4660 323.6059 323.7457 323.8855 324.0253 324.1651 324.3048 324.4446 324.5843 324.7241 324.8638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220331T215816.6Z 8125.915470 90 1 47.48 2 72.51 100.60 75.26 106.21 0.00 1 0.00 1 0 17 4.562e-01 9.764e-03 2.591e-01 5.030e-03 6.092369e-01 2.735508e-03 7.242947e-03 -6.000000e+00 2.652152e-01 227.17 -2.00 3.56 -2.00 320.85 0.00e+00 7.187431e-03 1.132341e-03 2.075685e-03 -6.000000e+00 1.150258e-02 277.04 -2.00 20.00 -2.00 320.36 0.00e+00 3.281 0.001 302.00 328.00 3 4.1080e+00 8.5293e-03 4.6512e-02 -6.0000e+00 6.6125e-01 5.3395e-02 1.1331e-02 3.3265e-02 -6.0000e+00 7.1672e-01 -5.0211e-02 1.1758e-02 2.2372e-02 -6.0000e+00 4.2391e-01 1.0574e-02 5.8065e-03 1.1670e-02 -6.0000e+00 1.8150e-01 1.5140e-04 -1.8500e-04 1.4265e-04 1.2286e-04 -6.0000e+00 1.2150e-02 1.4915e-03 2.9953e-05 12 8 8 10 0 0 99.84 17.18 0.17 0.00149 0.00010 41 11 1 5 0 1157.800 20.77 15.00 17.18 5.67 12.4 967.11 -104667 -39092 61582 -55193 130584 -157945 141068 -135275 900000 -143722 222631 -91636 289922 -38958 14584 18286 -26042 50039 -37066 32887 -46272 17432 -26539 11368 -31723 15614 -22361 1546 187 -25411 -9933 -2367 20727 -18273 8133 -23130 13065 -24605 13803 -4864 3486 509 8851 2532 -2323 5899 -8793 8967 -6352 10965 -2435 6900 2575 5175 1891 2327 110 -2230 1495 -4522 2826 -3339 7048 831 4223 -558 3811 1104 4347 2263 1403 1958 -453 602 -3138 -1078 -5745 431 -4377 895 -2099 -247 -1684 -1180 80 -817 1258 -25 1697 -763 1637 -1034 108 -1421 1191 -231 784 703 -276 64 -1498 -44 -1418 289 -2085 -226 -1095 -292 45 478 370 217 324 -363 364 -866 336 -128 797 -355 1001 39 1043 85 718 422 -283 564 -574 260 -1002 -20 -881 152 -254 248 330 418 204 -193 262 -838 -798 -192 302 -339 640 -2314 692 -1884 900000 -2587 1092 -1174 1422 -508 144 213 -519 542 -992 480 -1493 304 -724 234 -1034 341 -720 39 5 -905 -369 -97 790 -1092 355 -1378 608 -1918 904 -449 330 53 904 285 -279 688 -1198 1079 -931 1437 -401 1173 488 1040 410 524 26 -533 335 -1075 652 -915 1966 277 1419 -188 1238 378 1596 970 654 940 -218 269 -1344 -405 -2145 156 -1866 431 -1181 -155 -1159 -848 61 -665 1053 -21 1427 -628 1218 -751 74 -1038 948 -215 815 820 -347 78 -1742 -46 -1386 288 -2305 -255 -1307 -368 62 723 603 365 535 -576 545 -1265 497 -199 1302 -602 1641 61 1605 127 1021 589 -383 817 -929 462 -1927 -40 -1833 332 -588 592 795 1011 494 -444 574 -1770 SS 20220331T220322.0Z 8125.919005 93 1 47.59 2 71.60 101.53 74.38 107.11 0.00 1 0.00 1 0 17 2.080e-01 5.870e-03 6.146e-02 1.624e-03 5.871026e-01 8.779182e-04 6.947026e-03 -6.000000e+00 1.204705e-01 227.17 -2.00 3.56 -2.00 320.58 0.00e+00 4.081195e-03 3.361290e-04 1.365735e-03 -6.000000e+00 5.186593e-03 277.04 -2.00 20.00 -2.00 320.06 0.00e+00 3.128 0.001 302.00 328.00 3 2.3627e+00 2.6716e-03 4.4512e-02 -6.0000e+00 2.9967e-01 2.5381e-02 3.4381e-03 3.1844e-02 -6.0000e+00 3.2464e-01 -2.2009e-02 3.4256e-03 1.8501e-02 -6.0000e+00 1.9275e-01 -2.4090e-03 1.7161e-03 7.7088e-03 -6.0000e+00 8.2697e-02 1.0464e-03 -4.2073e-04 4.5808e-05 8.1939e-05 -6.0000e+00 5.5162e-03 2.5696e-03 -4.7281e-05 10 0 0 10 0 0 99.32 17.18 0.24 0.00257 -0.00059 203 52 1 5 0 234.370 20.77 15.02 17.18 5.70 12.4 967.40 -65817 -66017 -43986 -60317 -59479 -89603 -53763 -80751 -67198 -76394 -56077 -66154 -39144 -30559 -23222 -17824 -17930 -10034 -9246 -3123 -15472 -830 -11700 -379 -10982 -11677 -12157 -14520 -8692 -4778 -2059 -5501 3460 -6313 -4807 -8456 -3914 -5618 -765 -1849 -1571 -670 -1868 299 -296 1552 -2023 2720 -572 2404 1634 2577 1582 2232 1557 735 1233 -1125 -611 239 1464 1732 3274 2829 2188 404 1035 712 1678 1525 657 1222 -175 216 -1002 -1074 -1709 -2212 -2031 -950 -1541 -1509 -1780 -1662 -236 -484 855 577 1273 662 810 159 -420 -659 -132 25 303 576 86 -88 -732 -1077 -687 -3 -1237 -1342 -542 -457 441 531 646 179 289 -278 42 137 693 -78 332 -159 96 188 719 232 431 -59 -408 370 -247 -142 -353 -567 -254 37 75 -28 301 96 214 -39 187 -509 -438 -512 -300 -478 -424 -851 -383 -857 -702 -956 -595 -870 -502 -460 -408 -358 -403 -232 -230 -77 -451 -21 -339 -11 -369 -416 -445 -529 -297 -168 -84 -274 182 -397 -279 -512 -252 -436 -69 -201 -191 -86 -257 41 -42 221 -304 403 -91 395 301 525 352 537 394 194 334 -309 -162 63 395 517 1083 1050 847 152 383 271 702 740 347 665 -95 109 -468 -449 -681 -900 -931 -511 -954 -1059 -1354 -1326 -200 -434 795 547 1188 593 670 124 -316 -518 -117 25 317 679 109 -108 -839 -1220 -724 -3 -1343 -1512 -645 -578 606 808 1067 306 483 -445 63 197 1015 -121 542 -269 158 297 1097 340 608 -81 -538 522 -396 -250 -673 -1130 -529 81 175 -62 679 220 485 -92 415 -1072 SS 20220331T220838.6Z 8125.922669 96 1 47.55 2 70.66 102.49 73.47 108.05 0.00 1 0.00 1 0 17 1.631e-01 5.647e-03 2.163e-02 6.908e-04 5.576515e-01 3.670013e-04 6.547990e-03 -6.000000e+00 9.449393e-02 227.17 -2.00 3.56 -2.00 320.37 0.00e+00 3.467670e-03 1.316224e-04 1.245396e-03 -6.000000e+00 4.068153e-03 277.04 -2.00 20.00 -2.00 319.86 0.00e+00 2.985 0.000 302.00 328.00 3 1.0479e+00 1.0923e-03 4.2203e-02 -6.0000e+00 2.3505e-01 2.2495e-02 1.3771e-03 2.9870e-02 -6.0000e+00 2.5464e-01 -1.4223e-02 1.3380e-03 1.6882e-02 -6.0000e+00 1.5119e-01 -6.1660e-03 6.7956e-04 6.7277e-03 -6.0000e+00 6.4867e-02 4.6263e-03 -3.7834e-04 1.9433e-05 7.2253e-05 -6.0000e+00 4.3263e-03 2.4940e-03 -4.0016e-05 10 0 0 10 0 0 99.17 17.18 0.26 0.00249 -0.00035 672 173 1 5 0 70.740 20.77 15.00 17.18 5.85 12.5 969.49 -52855 -50882 -49573 -61000 -51697 -67950 -53407 -60215 -35814 -48821 -40565 -45938 -28041 -26235 -17379 -12306 -13433 -5038 -7472 -4115 -6856 -5043 -8827 -4996 -9135 -8404 -9355 -11644 -10113 -8962 -2586 -2723 -899 -4628 -5820 -6317 -4088 -3076 -845 -1606 -1822 -1605 -982 -319 64 1292 309 1564 277 1081 1445 2373 1635 2082 864 559 281 -604 -493 -6 1262 2315 3074 2721 2064 517 770 99 1496 1619 522 835 27 319 -521 -1051 -1650 -1980 -1634 -975 -1413 -1385 -1970 -1468 -313 -350 730 529 1065 650 794 287 -420 -330 88 155 281 425 42 -256 -687 -989 -660 -93 -971 -1286 -704 -590 377 558 525 109 228 -122 18 78 514 84 360 -75 139 265 672 198 406 -51 -302 380 -155 -200 -404 -634 -363 12 39 39 333 189 171 -24 71 -602 -424 -463 -484 -657 -460 -700 -511 -702 -369 -625 -495 -656 -423 -491 -371 -299 -366 -140 -229 -129 -230 -164 -312 -185 -377 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