File name: Pandora196s1_Sapporo_20220408_L2Fit_fout2c10d20220307p1-8.txt File generation date: 20250121T095616.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v10d20220307.txt Level 1 file used: Pandora196s1_Sapporo_20220408_L1_smca1c10d20220307p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20220408 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0528 305.1941 305.3353 305.4766 305.6178 305.7590 305.9003 306.0415 306.1826 306.3238 306.4650 306.6062 306.7473 306.8884 307.0296 307.1707 307.3118 307.4529 307.5940 307.7350 307.8761 308.0172 308.1582 308.2992 308.4402 308.5813 308.7223 308.8632 309.0042 309.1452 309.2861 309.4271 309.5680 309.7089 309.8498 309.9907 310.1316 310.2725 310.4134 310.5542 310.6951 310.8359 310.9767 311.1176 311.2584 311.3992 311.5399 311.6807 311.8215 311.9622 312.1030 312.2437 312.3844 312.5251 312.6658 312.8065 312.9472 313.0878 313.2285 313.3691 313.5097 313.6504 313.7910 313.9316 314.0721 314.2127 314.3533 314.4938 314.6344 314.7749 314.9154 315.0559 315.1964 315.3369 315.4774 315.6179 315.7583 315.8987 316.0392 316.1796 316.3200 316.4604 316.6008 316.7412 316.8815 317.0219 317.1622 317.3026 317.4429 317.5832 317.7235 317.8638 318.0040 318.1443 318.2846 318.4248 318.5650 318.7053 318.8455 318.9857 319.1258 319.2660 319.4062 319.5463 319.6865 319.8266 319.9667 320.1068 320.2469 320.3870 320.5271 320.6672 320.8072 320.9472 321.0873 321.2273 321.3673 321.5073 321.6473 321.7873 321.9272 322.0672 322.2071 322.3470 322.4870 322.6269 322.7667 322.9066 323.0465 323.1864 323.3262 323.4660 323.6059 323.7457 323.8855 324.0253 324.1651 324.3048 324.4446 324.5843 324.7241 324.8638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220407T212954.8Z 8132.895774 110 1 5.10 2 75.46 93.91 106.86 24.66 0.00 1 0.00 1 0 17 5.710e-01 1.805e-02 2.706e-01 1.017e-02 6.902077e-01 5.643809e-03 8.485412e-03 -6.000000e+00 3.367118e-01 227.71 -2.00 3.56 -2.00 320.80 0.00e+00 6.999823e-03 2.352195e-03 3.897925e-03 -6.000000e+00 1.600658e-02 277.81 -2.00 20.00 -2.00 320.31 0.00e+00 3.901 0.001 302.00 328.00 3 3.3009e+00 1.7547e-02 5.5425e-02 -6.0000e+00 8.4354e-01 1.5163e-01 2.3233e-02 4.0708e-02 -6.0000e+00 9.1686e-01 -2.2919e-01 2.3423e-02 2.5392e-02 -6.0000e+00 5.4328e-01 9.0946e-02 1.1510e-02 1.0543e-02 -6.0000e+00 2.3328e-01 1.7301e-04 -7.9508e-04 2.7753e-04 1.4067e-04 -6.0000e+00 1.5815e-02 5.7934e-03 -1.9829e-05 12 9 9 12 1 1 -2788.92 17.27 0.36 0.00579 -0.00018 3 10 1 5 0 1231.230 20.87 15.00 17.27 7.97 12.5 979.52 -210868 900000 -196184 900000 -170413 3939 -89647 133221 900000 -165102 900000 -175590 900000 -133867 900000 -112795 900000 -53003 900000 -44355 15208 -9943 -36815 -9496 -65877 105737 -22029 284518 -65030 254186 -40008 2524 -25866 73139 22748 -3695 11433 -8984 34686 -7117 42612 -9182 25168 -11563 21121 -5811 7536 4686 10531 14519 6261 27124 7407 14053 -4098 10522 -1415 13893 -1921 8390 -2685 10688 3395 9233 6885 1893 6813 962 8990 -1076 3544 276 2695 151 275 52 624 839 -5979 797 -5984 1874 -4526 142 -2940 656 -1639 1153 -763 743 -175 -781 -1871 -2706 -786 -1989 765 -3008 401 -174 -159 -1839 -471 -288 -1528 -1844 208 367 -334 2149 817 486 -235 256 -800 1339 431 -513 1366 242 1134 -249 1147 -659 2162 -1312 1118 30 239 -734 216 89 -669 733 -674 204 157 505 -447 138 -526 -705 -4307 900000 -4489 900000 -2724 39 -887 1318 900000 -3413 900000 -4717 900000 -4106 900000 -4416 900000 -1479 900000 -1307 261 -212 -1060 -226 -2845 1046 -667 2816 -2959 2516 -1921 96 -1506 1784 850 -177 527 -586 1821 -657 2702 -1021 2155 -1438 1969 -720 848 569 1273 1810 940 3758 1341 2600 -940 2156 -335 2811 -441 1726 -643 2508 965 2801 2222 620 2161 331 3189 -479 1623 134 1251 67 112 19 222 308 -2644 391 -3559 1165 -3191 101 -2278 519 -1376 958 -639 591 -132 -566 -1342 -2052 -656 -1901 802 -3603 493 -211 -182 -1948 -464 -291 -1671 -2081 244 450 -446 3095 1277 787 -379 397 -1209 1936 646 -797 2190 397 1808 -387 1735 -981 3052 -1870 1524 44 386 -1301 403 173 -1353 1531 -1492 460 356 1153 -1014 301 -1107 -1417 SS 20220407T213939.0Z 8132.902534 113 1 47.14 2 73.69 95.61 106.11 26.69 0.00 1 0.00 1 0 17 2.895e-01 6.324e-03 1.075e-01 2.280e-03 6.319763e-01 1.247213e-03 7.538693e-03 -6.000000e+00 1.680135e-01 227.71 -2.00 3.56 -2.00 320.86 0.00e+00 5.398914e-03 5.202553e-04 2.238754e-03 -6.000000e+00 7.241758e-03 277.81 -2.00 20.00 -2.00 320.34 0.00e+00 3.502 0.001 302.00 328.00 3 2.5717e+00 3.9263e-03 4.9354e-02 -6.0000e+00 4.1836e-01 4.5428e-02 5.2265e-03 3.5337e-02 -6.0000e+00 4.5298e-01 -5.2158e-02 5.3987e-03 2.1860e-02 -6.0000e+00 2.6896e-01 9.6591e-03 2.6536e-03 9.5324e-03 -6.0000e+00 1.1533e-01 5.6433e-04 -4.0697e-04 6.3871e-05 1.0971e-04 -6.0000e+00 7.6787e-03 2.9663e-03 -3.9987e-05 12 1 1 12 1 1 99.86 17.28 0.26 0.00297 -0.00009 116 31 1 5 0 401.340 20.87 15.01 17.28 8.34 12.6 983.90 -125776 -77128 -99991 -46932 -104583 -127059 -99155 -80778 -72197 -89934 -59130 -95703 28 -51833 6464 -37927 -12515 -23904 -14252 -20473 -20341 -18678 -15273 -9858 -27290 -7329 -26402 -10604 -27214 -5231 -16968 -6020 -5223 870 -7627 -9043 -5459 -6247 -198 -5117 1038 -2556 1939 -2515 3048 -2 2732 771 -1297 1089 1710 4981 3316 3639 436 1861 -673 -145 -1656 69 1311 2867 3075 3249 3084 1013 1679 75 2517 1857 1516 475 513 -290 -816 -1719 -2022 -1712 -2701 -630 -1531 -460 -2188 -1239 -913 -214 463 972 1166 878 623 44 -408 -772 -22 -204 540 254 44 -356 -568 -1156 -622 -447 -1081 -1660 -572 -536 609 778 658 164 171 -64 -162 221 372 174 443 -6 263 219 811 174 584 -246 -417 86 59 -320 -365 -642 -458 183 47 44 186 242 145 12 200 -543 -915 -446 -727 -219 -790 -1186 -749 -575 -530 -860 -434 -1149 0 -680 60 -674 -195 -468 -276 -446 -461 -411 -339 -226 -795 -184 -822 -276 -841 -141 -626 -237 -237 40 -363 -438 -284 -389 -14 -459 98 -268 206 -288 336 0 321 96 -174 152 265 839 616 736 95 416 -159 -34 -379 15 303 728 882 1046 1038 334 550 26 938 807 713 234 246 -132 -340 -647 -727 -628 -1140 -311 -876 -296 -1554 -916 -723 -178 402 854 1013 730 481 32 -289 -575 -18 -199 542 291 53 -427 -631 -1269 -632 -471 -1241 -1807 -656 -656 812 1156 1069 277 285 -102 -243 319 549 270 726 -10 432 344 1229 254 818 -335 -551 122 95 -575 -713 -1316 -986 416 115 102 435 573 337 30 454 -1171 SS 20220407T214637.5Z 8132.907378 117 1 47.59 2 72.42 96.85 105.55 28.14 0.00 1 0.00 1 0 17 2.168e-01 5.962e-03 9.155e-02 2.172e-03 5.876744e-01 1.171286e-03 6.892212e-03 -6.000000e+00 1.258227e-01 227.71 -2.00 3.56 -2.00 320.69 0.00e+00 4.630737e-03 4.669924e-04 1.659584e-03 -6.000000e+00 5.422509e-03 277.81 -2.00 20.00 -2.00 320.17 0.00e+00 3.264 0.001 302.00 328.00 3 2.6265e+00 3.6009e-03 4.5522e-02 -6.0000e+00 3.1330e-01 2.8130e-02 4.6827e-03 3.1981e-02 -6.0000e+00 3.3921e-01 -2.7864e-02 4.7297e-03 1.9211e-02 -6.0000e+00 2.0141e-01 -3.0283e-04 2.3587e-03 8.2908e-03 -6.0000e+00 8.6388e-02 7.0598e-04 -2.5615e-04 6.1617e-05 8.7635e-05 -6.0000e+00 5.7474e-03 2.4164e-03 -2.4438e-06 10 0 0 10 0 0 99.94 17.30 0.35 0.00242 0.00049 176 45 1 5 0 270.330 20.96 15.00 17.30 8.90 12.6 988.27 -26538 -77910 -35683 -67322 -77039 -93242 -103173 -61902 -74933 -46478 -79114 -28906 -52653 -1599 -29172 -15981 -19548 -9769 -7291 -11392 -12085 -20273 21 -18929 -5424 -13540 -10096 -20008 -12361 -12266 -7254 -3602 -146 -6768 -8393 -1612 -8734 -1798 -1829 2020 -1654 478 -1467 1468 63 971 432 231 699 57 3154 2139 1286 2122 1776 -267 208 -711 -161 972 1975 2729 2554 3282 1765 1783 222 663 1523 2506 6 779 185 140 -254 -2396 -1918 -3045 -995 -1512 -773 -1591 -1474 -1489 -587 -307 724 581 557 1058 545 604 -869 -1 -133 400 287 380 157 -19 -665 -893 -503 -524 -1052 -1585 -332 -642 626 717 832 19 283 -297 -44 88 336 119 297 -30 -116 392 719 414 410 110 -285 208 -285 -232 -253 -601 -376 -2 44 -64 399 212 202 -99 101 -557 -112 -585 -212 -542 -620 -869 -1136 -511 -794 -404 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