File name: Pandora196s1_Sapporo_20220410_L2Fit_fout2c10d20220307p1-8.txt File generation date: 20250121T095511.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v10d20220307.txt Level 1 file used: Pandora196s1_Sapporo_20220410_L1_smca1c10d20220307p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20220410 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0528 305.1941 305.3353 305.4766 305.6178 305.7590 305.9003 306.0415 306.1826 306.3238 306.4650 306.6062 306.7473 306.8884 307.0296 307.1707 307.3118 307.4529 307.5940 307.7350 307.8761 308.0172 308.1582 308.2992 308.4402 308.5813 308.7223 308.8632 309.0042 309.1452 309.2861 309.4271 309.5680 309.7089 309.8498 309.9907 310.1316 310.2725 310.4134 310.5542 310.6951 310.8359 310.9767 311.1176 311.2584 311.3992 311.5399 311.6807 311.8215 311.9622 312.1030 312.2437 312.3844 312.5251 312.6658 312.8065 312.9472 313.0878 313.2285 313.3691 313.5097 313.6504 313.7910 313.9316 314.0721 314.2127 314.3533 314.4938 314.6344 314.7749 314.9154 315.0559 315.1964 315.3369 315.4774 315.6179 315.7583 315.8987 316.0392 316.1796 316.3200 316.4604 316.6008 316.7412 316.8815 317.0219 317.1622 317.3026 317.4429 317.5832 317.7235 317.8638 318.0040 318.1443 318.2846 318.4248 318.5650 318.7053 318.8455 318.9857 319.1258 319.2660 319.4062 319.5463 319.6865 319.8266 319.9667 320.1068 320.2469 320.3870 320.5271 320.6672 320.8072 320.9472 321.0873 321.2273 321.3673 321.5073 321.6473 321.7873 321.9272 322.0672 322.2071 322.3470 322.4870 322.6269 322.7667 322.9066 323.0465 323.1864 323.3262 323.4660 323.6059 323.7457 323.8855 324.0253 324.1651 324.3048 324.4446 324.5843 324.7241 324.8638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220410T001620.9Z 8135.011353 269 1 3.54 2 46.63 128.71 102.32 38.51 0.00 1 0.00 1 0 17 1.149e-02 7.519e-03 5.966e-03 2.805e-03 2.427488e-01 1.449246e-03 2.970037e-03 -6.000000e+00 6.672320e-03 227.88 -2.00 3.56 -2.00 316.22 0.00e+00 7.500019e-04 1.586125e-04 9.184553e-05 -6.000000e+00 2.876123e-04 278.05 -2.00 20.00 -2.00 315.63 0.00e+00 1.454 0.000 302.00 328.00 3 3.7796e+00 3.7602e-03 1.9302e-02 -6.0000e+00 1.6620e-02 3.0073e-02 4.1871e-03 1.2553e-02 -6.0000e+00 1.7989e-02 -7.2886e-03 2.4372e-03 6.1928e-03 -6.0000e+00 1.0681e-02 -3.5801e-03 1.1519e-03 1.7996e-03 -6.0000e+00 4.5821e-03 2.0735e-03 -1.6382e-04 7.8531e-05 2.0040e-05 -6.0000e+00 3.0448e-04 9.0014e-04 -3.0977e-06 12 9 1 12 1 1 96.53 17.50 0.29 0.00090 -0.00033 5 22 1 5 0 561.130 21.06 15.00 17.50 16.58 12.9 1048.28 -458 -2569 -2093 -2223 -2078 -4225 -1071 -1233 1531 -1941 -3883 -1385 -607 -1206 1870 354 1154 771 796 2119 807 670 123 1241 891 579 -759 -1181 -572 -560 1938 1644 908 -222 -3632 -2799 -2306 -718 -7 -941 -725 -854 195 -144 263 -350 39 -8 -587 -1 378 880 736 1512 428 1005 618 411 399 643 799 1029 1748 1492 716 -826 -293 -849 925 1747 74 619 217 114 -116 -811 -1058 -1338 -1698 -1011 -1995 -2317 -2088 -1569 -455 -197 419 778 612 754 594 365 -304 106 294 59 577 157 -197 -465 -633 -538 -778 59 -1330 -1337 -845 -444 368 701 631 269 396 288 -11 97 513 412 496 70 383 -17 724 136 1059 335 -55 441 381 -150 -76 -676 41 45 142 142 -21 170 -90 -37 -496 -1000 -82 -509 -424 -426 -348 -689 -177 -229 306 -425 -847 -298 -146 -314 537 114 379 264 268 765 288 247 44 462 349 235 -311 -454 -216 -206 740 673 383 -99 -1520 -1146 -1030 -366 -4 -606 -482 -591 138 -102 185 -249 27 -5 -388 -1 262 651 545 1174 343 815 513 338 321 516 661 879 1595 1390 664 -734 -253 -718 792 1627 76 625 218 115 -108 -707 -881 -1112 -1439 -925 -1961 -2421 -2304 -1729 -535 -238 510 966 757 921 693 404 -321 110 316 67 696 203 -258 -607 -802 -649 -904 72 -1669 -1740 -1115 -607 509 1027 935 398 575 399 -14 126 674 547 687 100 548 -24 1018 189 1391 438 -68 562 504 -205 -109 -982 59 67 220 228 -33 276 -145 -58 -779 -1516 SS 20220410T002056.9Z 8135.014548 272 1 47.89 2 45.98 130.00 101.82 39.40 0.00 1 0.00 1 0 17 1.107e-02 6.449e-03 8.073e-04 2.708e-04 2.382700e-01 1.396255e-04 2.895105e-03 -6.000000e+00 6.432716e-03 227.88 -2.00 3.56 -2.00 317.25 0.00e+00 8.122506e-04 1.915896e-05 1.845745e-04 -6.000000e+00 2.772113e-04 278.05 -2.00 20.00 -2.00 316.62 0.00e+00 1.437 0.000 302.00 328.00 3 1.4297e+00 3.6667e-04 1.9012e-02 -6.0000e+00 1.6023e-02 9.7340e-03 4.1023e-04 1.2301e-02 -6.0000e+00 1.7341e-02 -1.5753e-03 2.4718e-04 6.1046e-03 -6.0000e+00 1.0297e-02 -6.9445e-03 1.2165e-04 1.8175e-03 -6.0000e+00 4.4186e-03 2.2459e-02 2.6764e-04 7.7940e-06 1.8598e-05 -6.0000e+00 2.9333e-04 7.0264e-04 6.6407e-05 11 8 0 10 0 0 99.97 17.51 0.30 0.00070 0.00271 1306 337 1 5 0 36.270 21.17 15.00 17.51 17.09 12.9 1053.28 -349 -2043 -1828 -3916 -3937 -2542 -1657 -498 -670 -2177 -3640 -2628 -441 -574 465 334 -256 949 785 1272 1265 512 1392 984 455 49 -818 -1231 -350 358 1346 973 885 -988 -3457 -2206 -2166 -936 -180 -609 -1110 -830 -395 -363 -143 156 -600 -107 -567 150 587 1101 827 1159 472 871 862 252 285 737 1148 1682 1625 1474 595 -333 35 -170 1190 1344 344 615 123 429 -35 -607 -820 -1509 -1153 -1210 -1814 -1714 -2144 -1568 -543 -371 451 290 590 450 555 329 -236 192 369 97 133 213 -112 -400 -635 -1018 -583 -123 -875 -1247 -505 -597 333 605 651 219 412 77 124 264 573 138 388 16 31 154 585 323 803 345 -20 493 -20 -98 -304 -567 -165 216 263 32 290 81 6 -228 -241 -908 -39 -250 -229 -474 -459 -279 -188 -63 -94 -327 -542 -391 -73 -107 98 78 -62 235 202 335 344 137 375 281 137 15 -257 -363 -96 95 375 291 285 -338 -1106 -688 -740 -367 -84 -331 -598 -463 -226 -209 -82 89 -337 -64 -333 87 360 656 517 763 319 598 603 176 194 500 802 1261 1312 1264 508 -259 26 -133 898 1156 321 594 118 395 -30 -467 -635 -1121 -907 -981 -1640 -1706 -2267 -1719 -637 -464 539 355 717 523 645 351 -230 184 379 110 166 269 -148 -513 -831 -1229 -675 -150 -1174 -1597 -676 -833 484 933 1049 352 627 108 161 354 780 181 549 24 47 228 843 442 1139 469 -26 655 -28 -136 -445 -842 -250 341 442 55 518 148 12 -402 -413 -1506 SS 20220410T002548.2Z 8135.017919 275 1 2.84 2 45.31 131.40 101.28 40.33 0.00 1 0.00 1 0 17 1.225e-02 7.541e-03 5.586e-03 2.733e-03 2.387526e-01 1.415134e-03 2.923249e-03 -6.000000e+00 7.118096e-03 227.88 -2.00 3.56 -2.00 316.11 0.00e+00 5.768679e-04 1.507132e-04 1.052974e-04 -6.000000e+00 3.067251e-04 278.05 -2.00 20.00 -2.00 315.52 0.00e+00 1.420 0.000 302.00 328.00 3 3.5514e+00 3.6680e-03 1.8900e-02 -6.0000e+00 1.7730e-02 3.0927e-02 4.0798e-03 1.2323e-02 -6.0000e+00 1.9189e-02 -7.6932e-03 2.3679e-03 6.0831e-03 -6.0000e+00 1.1394e-02 -2.7158e-03 1.1126e-03 1.7451e-03 -6.0000e+00 4.8896e-03 2.7125e-03 1.0276e-04 7.6501e-05 1.9513e-05 -6.0000e+00 3.2453e-04 6.3478e-04 8.0974e-05 12 9 1 12 1 1 90.30 17.51 0.31 0.00063 0.00141 5 28 1 5 0 443.050 21.17 15.00 17.51 17.61 12.9 1057.54 -3842 -543 -1931 -2593 -5819 103 -239 569 269 -246 -1158 -4662 2024 -1117 1303 -1160 1458 95 1214 274 1441 308 1045 1558 -970 1924 -1988 690 -406 633 1138 2956 752 -531 -3473 -2539 -1363 -1324 -146 -703 -896 -282 -196 -277 310 -117 -220 -778 -271 568 532 1741 745 1015 -327 695 799 185 172 471 967 1819 2136 1004 690 -435 23 -666 997 1121 104 524 150 181 -384 -957 -1116 -1622 -1402 -926 -1850 -1858 -2478 -1324 -401 -413 370 229 296 738 517 427 306 118 227 -185 200 300 210 -453 -528 -1193 -400 -100 -940 -1041 -582 -439 217 538 541 565 586 410 163 81 722 220 341 -305 -105 428 937 195 982 157 14 488 60 47 -438 -838 -215 526 409 26 249 203 -105 -395 -342 -1055 -741 -110 -405 -518 -1099 17 -42 112 57 -55 -255 -1070 490 -316 391 -393 496 34 427 100 536 113 404 606 -406 807 -865 273 -158 237 451 1228 329 -245 -1508 -1075 -624 -676 -85 -460 -614 -199 -138 -196 224 -85 -156 -541 -183 394 375 1304 568 788 -262 563 659 152 138 377 795 1598 1948 951 648 -386 19 -557 881 1060 103 539 153 183 -363 -865 -953 -1325 -1210 -843 -1826 -1959 -2701 -1486 -468 -499 454 289 370 904 599 466 314 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