File name: Pandora196s1_Sapporo_20220427_L2Fit_fout2c10d20220307p1-8.txt File generation date: 20250121T101740.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v10d20220307.txt Level 1 file used: Pandora196s1_Sapporo_20220427_L1_smca1c10d20220307p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20220427 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0528 305.1941 305.3353 305.4766 305.6178 305.7590 305.9003 306.0415 306.1826 306.3238 306.4650 306.6062 306.7473 306.8884 307.0296 307.1707 307.3118 307.4529 307.5940 307.7350 307.8761 308.0172 308.1582 308.2992 308.4402 308.5813 308.7223 308.8632 309.0042 309.1452 309.2861 309.4271 309.5680 309.7089 309.8498 309.9907 310.1316 310.2725 310.4134 310.5542 310.6951 310.8359 310.9767 311.1176 311.2584 311.3992 311.5399 311.6807 311.8215 311.9622 312.1030 312.2437 312.3844 312.5251 312.6658 312.8065 312.9472 313.0878 313.2285 313.3691 313.5097 313.6504 313.7910 313.9316 314.0721 314.2127 314.3533 314.4938 314.6344 314.7749 314.9154 315.0559 315.1964 315.3369 315.4774 315.6179 315.7583 315.8987 316.0392 316.1796 316.3200 316.4604 316.6008 316.7412 316.8815 317.0219 317.1622 317.3026 317.4429 317.5832 317.7235 317.8638 318.0040 318.1443 318.2846 318.4248 318.5650 318.7053 318.8455 318.9857 319.1258 319.2660 319.4062 319.5463 319.6865 319.8266 319.9667 320.1068 320.2469 320.3870 320.5271 320.6672 320.8072 320.9472 321.0873 321.2273 321.3673 321.5073 321.6473 321.7873 321.9272 322.0672 322.2071 322.3470 322.4870 322.6269 322.7667 322.9066 323.0465 323.1864 323.3262 323.4660 323.6059 323.7457 323.8855 324.0253 324.1651 324.3048 324.4446 324.5843 324.7241 324.8638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220426T230718.2Z 8151.963406 188 1 48.89 2 52.68 107.67 52.65 167.21 0.00 1 0.00 1 0 17 1.107e-02 6.335e-03 1.296e-03 3.607e-04 2.412481e-01 1.857666e-04 2.908377e-03 -6.000000e+00 6.471346e-03 229.33 -2.00 3.56 -2.00 317.59 0.00e+00 8.744462e-04 2.858182e-05 2.476896e-04 -6.000000e+00 2.794463e-04 279.94 -2.00 20.00 -2.00 316.93 0.00e+00 1.645 0.000 302.00 328.00 3 1.2129e+00 4.9344e-04 2.0774e-02 -6.0000e+00 1.6165e-02 2.2426e-02 5.5372e-04 1.2589e-02 -6.0000e+00 1.7468e-02 2.2142e-03 3.4209e-04 6.2226e-03 -6.0000e+00 1.0372e-02 -8.6482e-03 1.7149e-04 1.8453e-03 -6.0000e+00 4.4468e-03 2.2566e-02 3.1722e-04 1.0367e-05 1.8180e-05 -6.0000e+00 2.9339e-04 -1.6888e-03 7.4001e-05 10 0 0 10 0 0 99.99 17.83 0.27 -0.00169 0.00069 3246 837 1 5 0 14.430 21.48 15.00 17.83 18.54 13.1 1019.53 -321 -1879 -1876 -3573 -4095 -1863 -1655 -159 -919 -2126 -4138 -2505 -785 -430 470 278 -323 983 774 1039 1175 419 1213 781 364 -194 -908 -1442 -350 236 1231 951 965 -1050 -3602 -2260 -2264 -1073 -358 -725 -1224 -983 -521 -430 -178 185 -585 -202 -503 122 618 1035 830 1159 522 832 798 224 244 685 1109 1654 1585 1474 593 -364 31 -212 1124 1355 351 566 95 368 -44 -698 -842 -1602 -1125 -1272 -1797 -1756 -2124 -1607 -514 -340 453 327 577 472 556 333 -254 158 363 122 178 252 -61 -333 -641 -998 -587 -142 -844 -1249 -541 -598 317 643 720 281 412 42 89 190 511 129 350 51 31 110 533 239 732 277 -67 475 -27 -103 -320 -645 -250 211 243 59 306 143 17 -190 -191 -874 -31 -198 -204 -374 -377 -160 -148 -16 -102 -252 -491 -295 -103 -64 79 52 -62 194 159 220 256 90 263 180 88 -49 -230 -378 -85 55 305 253 277 -320 -1030 -628 -690 -375 -149 -352 -590 -492 -268 -245 -100 105 -324 -109 -266 64 341 611 514 756 350 566 554 155 165 462 769 1233 1273 1257 505 -284 22 -151 845 1163 327 546 92 339 -38 -539 -594 -1084 -803 -1033 -1626 -1750 -2251 -1766 -549 -387 538 398 698 547 650 356 -250 152 374 140 224 317 -81 -426 -846 -1216 -684 -174 -1139 -1597 -725 -833 461 992 1158 452 629 59 127 258 703 186 496 76 47 163 769 361 1049 381 -88 636 -39 -159 -470 -962 -381 333 410 104 547 262 32 -337 -329 -1456 SS 20220426T231530.3Z 8151.969100 191 1 1.91 2 51.26 109.44 52.32 169.69 0.00 1 0.00 1 0 17 1.245e-02 7.326e-03 5.178e-03 2.356e-03 2.354987e-01 1.223286e-03 2.862110e-03 -6.000000e+00 7.279618e-03 229.33 -2.00 3.56 -2.00 316.32 0.00e+00 6.804806e-04 1.369824e-04 1.025819e-04 -6.000000e+00 3.143095e-04 279.94 -2.00 20.00 -2.00 315.69 0.00e+00 1.594 0.000 302.00 328.00 3 2.6758e+00 3.1866e-03 2.0171e-02 -6.0000e+00 1.8184e-02 4.1532e-02 3.5440e-03 1.2259e-02 -6.0000e+00 1.9649e-02 -4.2190e-03 2.0660e-03 6.0064e-03 -6.0000e+00 1.1667e-02 -3.8911e-03 9.7863e-04 1.7284e-03 -6.0000e+00 5.0028e-03 5.5102e-03 3.0686e-04 6.6225e-05 1.8822e-05 -6.0000e+00 3.2995e-04 -2.0823e-03 9.0819e-05 12 9 1 12 1 1 99.98 17.85 0.28 -0.00208 0.00022 12 92 1 5 0 133.310 21.48 15.00 17.85 19.15 13.2 1024.99 -3092 470 -4309 -3045 -4768 -327 -1684 357 712 -2064 -1664 -4602 1097 -1403 2004 -303 678 547 509 983 1331 1012 1497 2467 258 1486 -1030 -749 -1301 1703 672 1391 689 -772 -3782 -2494 -1495 -1760 -58 -852 -484 -1110 70 -739 277 126 275 -146 -789 507 1327 1038 459 1235 430 1546 373 474 -6 716 402 1628 1410 1356 374 -682 -279 -626 1611 1110 432 352 239 358 74 -1001 -1100 -1477 -1273 -1228 -2095 -1790 -2098 -1498 -923 -94 274 383 705 683 333 268 -456 -454 368 -182 471 178 252 -459 -270 -1089 -596 108 -582 -1178 -759 -382 25 732 726 547 396 294 -35 426 279 246 401 -33 37 369 751 274 799 183 186 320 293 -92 -191 -863 -332 313 -83 295 146 223 39 -286 -390 -909 -535 85 -839 -562 -794 -50 -274 63 139 -430 -343 -968 246 -360 556 -94 214 179 171 337 469 349 530 900 101 585 -415 -285 -477 598 249 540 286 -334 -1560 -1012 -649 -854 -32 -529 -321 -761 48 -518 192 88 187 -98 -528 334 904 744 341 952 337 1221 304 382 -5 570 327 1381 1261 1272 351 -604 -235 -521 1389 1041 429 357 243 352 70 -883 -915 -1186 -1067 -1115 -2057 -1871 -2283 -1655 -1073 -113 341 482 881 831 388 294 -474 -468 395 -208 572 230 334 -597 -337 -1297 -692 129 -735 -1541 -1022 -523 35 1071 1089 816 578 407 -46 542 362 327 559 -47 54 530 1057 375 1064 238 233 410 392 -127 -272 -1240 -486 466 -128 468 234 362 63 -458 -611 -1402 SS 20220426T232159.5Z 8151.973605 195 1 48.97 2 50.15 110.89 52.11 171.66 0.00 1 0.00 1 0 17 1.082e-02 6.561e-03 3.711e-04 1.372e-04 2.295075e-01 7.085183e-05 2.815986e-03 -6.000000e+00 6.319931e-03 229.33 -2.00 3.56 -2.00 316.98 0.00e+00 7.160410e-04 9.202839e-06 1.689701e-04 -6.000000e+00 2.730592e-04 279.94 -2.00 20.00 -2.00 316.32 0.00e+00 1.557 0.000 302.00 328.00 3 4.4011e-02 1.8592e-04 1.9731e-02 -6.0000e+00 1.5786e-02 2.2011e-02 2.0733e-04 1.2028e-02 -6.0000e+00 1.7063e-02 -1.8546e-03 1.2323e-04 5.9125e-03 -6.0000e+00 1.0131e-02 -6.3514e-03 6.0185e-05 1.6995e-03 -6.0000e+00 4.3409e-03 8.0986e-02 -2.8881e-04 3.9205e-06 1.8344e-05 -6.0000e+00 2.8689e-04 -9.4072e-04 -4.0391e-05 11 8 0 10 0 0 34.41 17.86 0.31 -0.00094 -0.00311 3699 954 1 5 0 12.630 21.48 15.00 17.86 20.00 13.3 1034.02 62 -1765 -1952 -3807 -4168 -2255 -1535 -83 -443 -1957 -3232 -2217 -254 -491 699 326 -253 929 975 1250 1304 455 1498 1158 573 205 -750 -1215 -389 265 1187 948 895 -929 -3606 -2149 -2065 -931 -46 -543 -1030 -806 -427 -460 -174 144 -621 -201 -607 120 619 1105 819 1153 498 899 821 246 245 666 1098 1617 1574 1419 514 -421 -35 -285 1179 1351 287 580 68 340 -56 -717 -861 -1526 -1142 -1219 -1825 -1719 -2165 -1594 -560 -398 414 249 536 422 531 326 -189 219 431 132 169 235 -74 -362 -625 -1001 -579 -110 -852 -1243 -546 -616 286 592 634 262 412 147 165 325 593 179 392 29 57 140 566 335 797 400 41 546 29 -51 -270 -555 -200 207 207 35 247 77 -37 -230 -237 -884 8 -241 -274 -566 -544 -275 -194 -12 -69 -327 -534 -365 -46 -101 162 83 -67 252 274 360 387 133 440 360 188 70 -257 -390 -116 76 358 306 311 -341 -1242 -719 -756 -391 -23 -288 -594 -482 -262 -285 -106 88 -372 -117 -346 68 367 699 543 804 357 652 608 182 177 479 812 1284 1345 1285 464 -347 -27 -213 933 1220 281 588 69 329 -51 -583 -639 -1191 -854 -1034 -1724 -1787 -2393 -1673 -629 -476 517 319 682 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