File name: Pandora196s1_Sapporo_20220610_L2Fit_fout2c10d20220307p1-8.txt File generation date: 20250121T103622.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v10d20220307.txt Level 1 file used: Pandora196s1_Sapporo_20220610_L1_smca1c10d20220307p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20220610 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0528 305.1941 305.3353 305.4766 305.6178 305.7590 305.9003 306.0415 306.1826 306.3238 306.4650 306.6062 306.7473 306.8884 307.0296 307.1707 307.3118 307.4529 307.5940 307.7350 307.8761 308.0172 308.1582 308.2992 308.4402 308.5813 308.7223 308.8632 309.0042 309.1452 309.2861 309.4271 309.5680 309.7089 309.8498 309.9907 310.1316 310.2725 310.4134 310.5542 310.6951 310.8359 310.9767 311.1176 311.2584 311.3992 311.5399 311.6807 311.8215 311.9622 312.1030 312.2437 312.3844 312.5251 312.6658 312.8065 312.9472 313.0878 313.2285 313.3691 313.5097 313.6504 313.7910 313.9316 314.0721 314.2127 314.3533 314.4938 314.6344 314.7749 314.9154 315.0559 315.1964 315.3369 315.4774 315.6179 315.7583 315.8987 316.0392 316.1796 316.3200 316.4604 316.6008 316.7412 316.8815 317.0219 317.1622 317.3026 317.4429 317.5832 317.7235 317.8638 318.0040 318.1443 318.2846 318.4248 318.5650 318.7053 318.8455 318.9857 319.1258 319.2660 319.4062 319.5463 319.6865 319.8266 319.9667 320.1068 320.2469 320.3870 320.5271 320.6672 320.8072 320.9472 321.0873 321.2273 321.3673 321.5073 321.6473 321.7873 321.9272 322.0672 322.2071 322.3470 322.4870 322.6269 322.7667 322.9066 323.0465 323.1864 323.3262 323.4660 323.6059 323.7457 323.8855 324.0253 324.1651 324.3048 324.4446 324.5843 324.7241 324.8638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220609T194205.3Z 8195.820895 122 1 47.25 2 83.36 64.59 127.12 306.18 0.00 1 0.00 1 0 25 5.638e-01 3.729e-02 5.472e-01 3.942e-02 9.828634e-01 2.432902e-02 1.231945e-02 -6.000000e+00 3.433537e-01 232.60 -2.00 3.56 -2.00 322.32 0.00e+00 6.584585e-03 1.362713e-02 1.489506e-02 -6.000000e+00 1.705844e-02 284.61 -2.00 20.00 -2.00 321.87 0.00e+00 7.860 0.009 302.00 328.00 3 1.7932e+00 9.6410e-02 1.2415e-01 -6.0000e+00 8.6222e-01 1.5538e+00 1.2029e-01 1.1194e-01 -6.0000e+00 9.3191e-01 -1.7940e+00 8.6173e-02 4.4865e-02 -6.0000e+00 5.5531e-01 6.5832e-01 4.2071e-02 8.7681e-03 -6.0000e+00 2.3921e-01 1.0834e-05 -1.1915e-03 1.0805e-03 2.8914e-04 -6.0000e+00 1.6119e-02 3.3971e-03 -5.8547e-05 12 8 8 10 0 0 -72.69 17.84 0.90 0.00340 -0.00556 18 5 1 5 0 2624.430 21.48 15.01 17.84 18.09 13.7 985.06 900000 -84900 900000 -80415 900000 -75019 -10498 -138637 -29153 -107775 900000 -7328 -53124 21107 -56988 74673 -21518 900000 900000 175347 -869 900000 -15299 156962 64339 -7956 900000 29214 900000 -87609 900000 -19904 68174 18438 94323 18737 253487 -5311 900000 184233 18099 234673 144347 108814 16880 -8892 36559 96511 20672 76689 5329 11932 61000 80720 97905 46561 8892 28677 54113 20388 900000 12155 28779 -741 51961 29532 20644 18027 42334 42809 11811 18593 -7937 23379 -22964 -16486 -30665 -9254 9536 -2835 816 -9706 10201 -2539 30392 -9381 11642 -10922 731 -9432 -1907 -6716 398 -8978 11503 -8151 -749 3464 -540 -1470 -46 -9368 -8864 1504 -897 -8335 -5475 1870 -585 2513 2348 2894 578 -2013 -4010 -2331 451 262 2602 1375 2688 2512 -395 5633 2520 6123 -4694 762 -2449 946 -309 -974 -2043 1485 -676 311 679 841 314 -198 467 -2826 900000 -4508 900000 -3854 900000 -2877 -403 -7974 -1118 -4477 900000 -281 -2037 809 -2914 2863 -963 900000 900000 6724 -33 900000 -587 6019 2467 -305 900000 1120 900000 -6108 900000 -1041 2614 771 3617 718 9720 -278 900000 7065 1073 8999 5535 4173 1000 -682 1784 3701 1297 2941 464 1081 3615 4221 4437 3571 992 2499 3395 1706 900000 1229 2809 -111 4891 3397 2663 2514 5165 5969 2388 3565 -1882 3667 -5043 -2988 -6200 -1774 1792 -672 219 -3350 3165 -938 8581 -4120 4302 -5102 298 -4044 -705 -2505 153 -3787 4691 -4859 -489 2523 -446 -1209 -35 -6760 -5747 986 -591 -6159 -4237 1473 -542 2636 2815 3713 775 -2736 -5382 -3022 590 361 3692 1989 3664 3222 -555 7236 3256 7466 -6300 1093 -3935 1698 -632 -2166 -4963 3758 -1882 890 1949 2434 894 -526 1139 -6580 SS 20220609T195303.7Z 8195.828515 125 1 47.45 2 81.54 66.35 128.68 308.86 0.00 1 0.00 1 0 17 5.146e-01 1.933e-02 3.690e-01 1.107e-02 8.568593e-01 6.612020e-03 1.074584e-02 -6.000000e+00 3.058256e-01 232.60 -2.00 3.56 -2.00 322.17 0.00e+00 1.479655e-02 3.871199e-03 7.477963e-03 -6.000000e+00 1.356393e-02 284.61 -2.00 20.00 -2.00 321.71 0.00e+00 6.392 0.005 302.00 328.00 3 1.6507e+00 2.6441e-02 8.4756e-02 -6.0000e+00 7.6805e-01 8.1415e-01 3.6358e-02 5.6772e-02 -6.0000e+00 8.2786e-01 -1.1009e+00 3.3073e-02 3.4523e-02 -6.0000e+00 4.9077e-01 4.3499e-01 1.5154e-02 1.5065e-02 -6.0000e+00 2.1020e-01 6.7173e-05 -1.2275e-03 3.0835e-04 3.0012e-04 -6.0000e+00 1.3680e-02 4.2991e-03 -7.4679e-05 12 8 8 10 0 0 39.25 17.86 0.42 0.00430 -0.00493 60 15 1 5 0 790.760 21.48 15.01 17.86 18.75 13.6 989.49 -148502 900000 -157714 -32267 -190776 900000 -169174 -103683 -163484 -33547 -75269 -157328 116175 -137819 9855 -76717 161141 -41479 36718 -23292 53643 67942 -26197 -3320 -31876 7413 -86056 -28429 -61816 169165 -33215 92786 7817 87457 -8743 -18872 -15463 41045 7803 24368 32855 14784 36865 6872 83001 21408 38156 13658 54760 40744 65662 40430 23725 32748 9686 30494 8332 38192 1257 37820 15612 23985 13459 19638 21243 19634 15582 13001 18677 7622 16519 5974 10311 -3754 5023 -5385 2230 -1420 3699 1140 1522 2978 -2096 2860 -4186 5292 -126 3562 -1869 3804 1531 -1480 -3293 -5553 -1966 -3791 143 -2305 -987 -2415 -1712 -3776 -948 -4571 -2218 -4025 -2415 -1849 -899 55 -1074 534 -764 241 -1688 -174 -414 1338 1256 1236 2111 1453 2342 600 2394 829 677 -32 478 -4 932 -627 365 -379 -304 470 601 254 -494 175 -1093 -1110 -3070 900000 -4253 -348 -6174 900000 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-2.00 321.03 0.00e+00 5.057 0.002 302.00 328.00 3 1.3521e+00 6.9119e-03 6.9132e-02 -6.0000e+00 8.3442e-01 1.3718e-01 1.0108e-02 5.1855e-02 -6.0000e+00 8.9917e-01 -2.0703e-01 1.0539e-02 2.9826e-02 -6.0000e+00 5.3389e-01 7.3351e-02 4.8639e-03 1.0069e-02 -6.0000e+00 2.2800e-01 4.1153e-04 -6.5793e-04 9.3379e-05 1.7104e-04 -6.0000e+00 1.4920e-02 3.4575e-03 -5.4953e-05 11 8 0 10 0 0 16.78 17.91 0.31 0.00346 -0.00149 181 47 1 5 0 263.740 21.58 15.00 17.91 19.58 13.6 996.43 -248759 -122086 -192161 -199534 -195294 -219923 -160478 -132645 -46314 -151736 -146871 -171873 -22032 -141033 -32477 -82722 -39923 -90324 -61115 -49038 -62993 -3990 -35644 -3816 -55935 -22795 -67957 -2935 -69165 -8026 -29738 -4638 -9096 -13815 -11855 -28458 -4031 -6905 3977 -648 16423 -3341 10222 -1449 3034 3813 2059 2508 904 12129 6446 11265 5036 12198 2589 6802 1233 2868 -1395 772 3241 4450 7823 5134 7977 2239 6920 1226 4912 2693 3122 2080 1273 224 -595 -308 -3994 -2386 -2349 -673 -1882 -344 -2038 -1304 -808 -39 551 898 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