File name: Pandora196s1_Sapporo_20220627_L2Fit_fout2c10d20220307p1-8.txt File generation date: 20250121T120936.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v10d20220307.txt Level 1 file used: Pandora196s1_Sapporo_20220627_L1_smca1c10d20220307p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20220627 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0528 305.1941 305.3353 305.4766 305.6178 305.7590 305.9003 306.0415 306.1826 306.3238 306.4650 306.6062 306.7473 306.8884 307.0296 307.1707 307.3118 307.4529 307.5940 307.7350 307.8761 308.0172 308.1582 308.2992 308.4402 308.5813 308.7223 308.8632 309.0042 309.1452 309.2861 309.4271 309.5680 309.7089 309.8498 309.9907 310.1316 310.2725 310.4134 310.5542 310.6951 310.8359 310.9767 311.1176 311.2584 311.3992 311.5399 311.6807 311.8215 311.9622 312.1030 312.2437 312.3844 312.5251 312.6658 312.8065 312.9472 313.0878 313.2285 313.3691 313.5097 313.6504 313.7910 313.9316 314.0721 314.2127 314.3533 314.4938 314.6344 314.7749 314.9154 315.0559 315.1964 315.3369 315.4774 315.6179 315.7583 315.8987 316.0392 316.1796 316.3200 316.4604 316.6008 316.7412 316.8815 317.0219 317.1622 317.3026 317.4429 317.5832 317.7235 317.8638 318.0040 318.1443 318.2846 318.4248 318.5650 318.7053 318.8455 318.9857 319.1258 319.2660 319.4062 319.5463 319.6865 319.8266 319.9667 320.1068 320.2469 320.3870 320.5271 320.6672 320.8072 320.9472 321.0873 321.2273 321.3673 321.5073 321.6473 321.7873 321.9272 322.0672 322.2071 322.3470 322.4870 322.6269 322.7667 322.9066 323.0465 323.1864 323.3262 323.4660 323.6059 323.7457 323.8855 324.0253 324.1651 324.3048 324.4446 324.5843 324.7241 324.8638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220626T203916.1Z 8212.860603 136 1 47.54 2 74.02 72.77 55.20 89.55 0.00 1 0.00 1 0 17 1.723e-01 6.011e-03 3.405e-02 1.078e-03 5.340640e-01 5.884029e-04 6.438213e-03 -6.000000e+00 1.020381e-01 233.00 -2.00 3.56 -2.00 320.49 0.00e+00 3.051130e-03 2.247121e-04 2.196136e-03 -6.000000e+00 4.465494e-03 286.23 -2.00 20.00 -2.00 319.82 0.00e+00 3.569 0.001 302.00 328.00 3 1.2394e+00 1.8317e-03 4.6937e-02 -6.0000e+00 2.5663e-01 1.3688e-02 2.3128e-03 3.1211e-02 -6.0000e+00 2.7634e-01 -1.6919e-02 2.0982e-03 1.6457e-02 -6.0000e+00 1.6419e-01 -5.1497e-03 1.0497e-03 5.1874e-03 -6.0000e+00 7.0205e-02 2.3021e-03 -2.2191e-04 3.1182e-05 6.8996e-05 -6.0000e+00 4.5756e-03 1.3004e-03 -1.7394e-05 10 0 0 10 0 0 99.41 18.35 0.26 0.00130 -0.00037 403 104 1 5 0 117.940 22.09 15.00 18.35 25.36 14.3 1007.84 -77558 -32824 -69141 -62461 -59130 -66821 -41630 -57720 -35839 -54929 -27968 -57609 -11941 -27276 -14653 -15909 -6816 -12997 -9855 -4344 -6566 -7541 -9948 -760 -10430 -3612 -16364 -7068 -14320 -5050 -7158 -1181 -1456 -4642 -6057 -7976 -3528 -4149 791 -2080 225 -2271 583 -230 1120 500 -323 1464 -648 1207 824 2605 925 2902 473 1588 200 96 -947 345 1356 2597 3161 2494 2315 322 962 -197 1943 1671 1386 619 266 133 -669 -1273 -1977 -2252 -1975 -993 -1778 -1025 -2154 -1239 -363 70 568 823 886 568 836 56 -428 -613 93 -167 367 319 115 -458 -703 -1209 -636 -263 -1001 -1306 -578 -512 351 734 539 175 257 -41 -232 200 644 145 400 10 231 250 819 75 591 -146 -389 246 -132 -371 -436 -723 -419 39 144 93 341 332 101 36 -12 -474 -734 -252 -753 -627 -572 -688 -359 -667 -377 -762 -306 -932 -153 -510 -299 -391 -169 -378 -300 -132 -214 -246 -347 -26 -428 -146 -765 -291 -625 -211 -360 -65 -92 -325 -404 -544 -257 -361 80 -258 30 -335 88 -36 175 81 -53 242 -113 218 165 570 222 742 130 446 59 28 -272 98 396 829 1121 986 945 127 371 -78 836 835 751 352 149 71 -328 -563 -829 -952 -931 -547 -1125 -728 -1671 -1001 -313 64 494 730 858 528 717 45 -330 -489 83 -170 382 376 144 -563 -805 -1257 -680 -294 -1110 -1509 -706 -662 490 1127 895 299 429 -65 -346 285 938 222 654 17 387 403 1278 112 850 -203 -522 352 -211 -656 -829 -1433 -866 84 309 207 769 762 231 78 -27 -1021 SS 20220626T204610.1Z 8212.865395 140 1 47.41 2 72.81 73.84 53.96 90.68 0.00 1 0.00 1 0 17 1.223e-01 5.810e-03 2.282e-02 8.667e-04 5.002824e-01 4.682563e-04 5.997553e-03 -6.000000e+00 7.244771e-02 233.00 -2.00 3.56 -2.00 320.27 0.00e+00 2.636744e-03 1.650984e-04 1.772721e-03 -6.000000e+00 3.170417e-03 286.23 -2.00 20.00 -2.00 319.58 0.00e+00 3.333 0.001 302.00 328.00 3 1.1166e+00 1.4175e-03 4.3620e-02 -6.0000e+00 1.8221e-01 6.9890e-03 1.7550e-03 2.8520e-02 -6.0000e+00 1.9620e-01 -8.1159e-03 1.5415e-03 1.4826e-02 -6.0000e+00 1.1657e-01 -8.0502e-03 7.8133e-04 4.6296e-03 -6.0000e+00 4.9848e-02 3.3914e-03 -1.8778e-04 2.5154e-05 5.9087e-05 -6.0000e+00 3.2482e-03 1.2125e-03 -5.8885e-06 10 0 0 10 0 0 99.68 18.36 0.27 0.00121 -0.00020 531 137 1 5 0 89.260 22.09 15.00 18.36 26.05 14.4 1013.41 -50329 -26432 -39710 -33894 -46260 -41269 -46298 -38982 -36411 -34159 -37392 -36663 -17829 -18464 -8083 -9828 -4203 -9335 -2462 -5880 -3630 -5940 -6161 -4135 -5599 -4816 -7032 -7450 -7670 -3846 -2958 861 -1111 -2302 -6112 -5542 -5278 -2493 -920 -1235 -822 -1330 -87 -551 754 671 -104 422 129 178 1310 1846 1241 1925 752 1086 283 23 -438 412 978 2115 2547 2730 1492 328 738 -66 1601 1707 942 807 150 135 -415 -1259 -1414 -2139 -1624 -1222 -1570 -1359 -1972 -1274 -398 92 744 735 1026 676 572 347 -653 -330 -51 -35 235 290 51 -449 -635 -1219 -555 -218 -937 -1378 -517 -591 355 739 734 198 256 -91 -103 105 577 93 383 11 158 148 714 192 527 -123 -391 257 -156 -307 -429 -692 -305 49 89 -35 359 321 184 20 108 -589 -514 -244 -452 -357 -547 -457 -579 -517 -532 -531 -616 -654 -325 -420 -203 -296 -131 -337 -89 -233 -147 -243 -263 -188 -277 -249 -379 -388 -392 -197 -174 56 -84 -189 -489 -442 -467 -254 -113 -181 -133 -230 -16 -102 139 127 -20 82 26 37 298 463 336 561 231 345 93 7 -141 131 322 760 1015 1196 679 142 312 -28 750 925 555 495 91 78 -221 -606 -639 -973 -817 -718 -1053 -1026 -1614 -1088 -363 81 684 690 954 603 520 295 -530 -274 -47 -34 253 351 66 -566 -746 -1302 -556 -229 -1072 -1646 -650 -788 509 1158 1237 343 432 -145 -154 150 844 143 629 19 267 241 1128 291 765 -174 -530 368 -250 -539 -808 -1354 -620 96 188 -76 797 725 412 42 220 -1258 SS 20220626T205147.5Z 8212.869300 143 1 47.96 2 71.82 74.71 52.95 91.61 0.00 1 0.00 1 0 17 2.069e-01 1.018e-02 2.339e-01 9.488e-03 4.794559e-01 5.170713e-03 5.831286e-03 -6.000000e+00 1.243137e-01 233.00 -2.00 3.56 -2.00 320.21 0.00e+00 2.839842e-03 1.786485e-03 2.273165e-03 -6.000000e+00 5.509337e-03 286.24 -2.00 20.00 -2.00 319.53 0.00e+00 3.163 0.001 302.00 328.00 3 5.2515e+00 1.5513e-02 4.1866e-02 -6.0000e+00 3.1225e-01 7.1186e-02 1.9132e-02 2.8209e-02 -6.0000e+00 3.3645e-01 -1.5542e-03 1.6705e-02 1.4927e-02 -6.0000e+00 1.9854e-01 -1.0560e-02 8.5188e-03 4.7187e-03 -6.0000e+00 8.5006e-02 6.2255e-05 9.7502e-04 2.7981e-04 5.9276e-05 -6.0000e+00 5.5825e-03 -2.2431e-03 2.5276e-04 12 9 8 11 8 0 99.99 18.37 0.70 -0.00224 0.00508 17 4 1 5 0 2820.620 22.09 15.00 18.37 26.40 14.3 1015.48 900000 -93668 -54251 -11790 36812 900000 900000 760 -40509 -7470 14488 160499 -11365 15060 -35407 86469 3591 16711 23154 24758 -22517 -11453 14239 -12425 716 -16018 9717 -16084 15614 -4235 42056 -16519 15049 -10073 -5927 15840 10698 10345 1363 -2055 -3399 2576 -5246 -1144 -3606 4135 -5624 -2067 3372 1314 632 -175 6207 -2140 2411 -200 4397 -1408 1040 -2762 38 576 2208 3485 1313 -555 -194 -2609 16 3854 1771 2291 -1750 863 -907 545 -117 -2412 -631 -869 -1885 -2025 -286 -1991 -814 -719 1320 1327 1771 1485 683 -153 -1584 -515 -1059 -309 -1160 1075 -149 177 -1437 -822 -918 245 -1458 -1340 -773 -952 707 1050 1425 153 1266 -277 -544 -654 1350 -476 8 -284 729 1057 -287 920 -36 78 -1954 70 348 122 -380 -1165 -545 -2 564 -218 777 110 160 -337 372 -611 900000 -2123 -915 -130 340 900000 900000 8 -711 -104 167 1484 -221 277 -1297 1147 116 517 722 809 -1202 -547 552 -672 37 -1006 487 -1002 699 -239 1742 -1371 1042 -954 -510 1091 859 983 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