File name: Pandora196s1_Sapporo_20220705_L2Fit_fout2c10d20220307p1-8.txt File generation date: 20250121T120941.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v10d20220307.txt Level 1 file used: Pandora196s1_Sapporo_20220705_L1_smca1c10d20220307p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20220705 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0528 305.1941 305.3353 305.4766 305.6178 305.7590 305.9003 306.0415 306.1826 306.3238 306.4650 306.6062 306.7473 306.8884 307.0296 307.1707 307.3118 307.4529 307.5940 307.7350 307.8761 308.0172 308.1582 308.2992 308.4402 308.5813 308.7223 308.8632 309.0042 309.1452 309.2861 309.4271 309.5680 309.7089 309.8498 309.9907 310.1316 310.2725 310.4134 310.5542 310.6951 310.8359 310.9767 311.1176 311.2584 311.3992 311.5399 311.6807 311.8215 311.9622 312.1030 312.2437 312.3844 312.5251 312.6658 312.8065 312.9472 313.0878 313.2285 313.3691 313.5097 313.6504 313.7910 313.9316 314.0721 314.2127 314.3533 314.4938 314.6344 314.7749 314.9154 315.0559 315.1964 315.3369 315.4774 315.6179 315.7583 315.8987 316.0392 316.1796 316.3200 316.4604 316.6008 316.7412 316.8815 317.0219 317.1622 317.3026 317.4429 317.5832 317.7235 317.8638 318.0040 318.1443 318.2846 318.4248 318.5650 318.7053 318.8455 318.9857 319.1258 319.2660 319.4062 319.5463 319.6865 319.8266 319.9667 320.1068 320.2469 320.3870 320.5271 320.6672 320.8072 320.9472 321.0873 321.2273 321.3673 321.5073 321.6473 321.7873 321.9272 322.0672 322.2071 322.3470 322.4870 322.6269 322.7667 322.9066 323.0465 323.1864 323.3262 323.4660 323.6059 323.7457 323.8855 324.0253 324.1651 324.3048 324.4446 324.5843 324.7241 324.8638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220704T231655.2Z 8220.970084 200 1 48.86 2 46.18 99.31 103.73 64.35 0.00 1 0.00 1 0 17 1.751e-02 9.484e-03 1.669e-02 5.657e-03 2.190526e-01 2.956316e-03 2.671514e-03 -6.000000e+00 1.037864e-02 233.04 -2.00 3.56 -2.00 317.26 0.00e+00 7.624083e-04 4.146820e-04 2.687330e-04 -6.000000e+00 4.551670e-04 286.98 -2.00 20.00 -2.00 316.45 0.00e+00 1.442 0.000 302.00 328.00 3 6.6716e+00 7.8574e-03 1.8677e-02 -6.0000e+00 2.6100e-02 6.2171e-02 8.7773e-03 1.1677e-02 -6.0000e+00 2.8089e-02 1.8322e-03 5.2254e-03 5.6696e-03 -6.0000e+00 1.6697e-02 -8.2676e-03 2.5511e-03 1.5874e-03 -6.0000e+00 7.1528e-03 1.1950e-04 3.0110e-04 1.6320e-04 1.6615e-05 -6.0000e+00 4.6438e-04 -3.3185e-03 6.4748e-05 12 8 8 10 0 0 99.93 18.28 0.63 -0.00332 -0.00106 13 3 1 5 0 3757.380 21.98 15.00 18.28 34.12 14.7 1053.46 2084 -1080 -167 2799 -2471 -3365 -4414 -3948 -488 -1567 -4679 -8571 1812 -925 1379 1253 2148 322 2503 -1261 3 171 -549 626 3195 230 -1179 -2626 197 2159 2899 2144 98 810 -7032 -3564 -3449 -533 -231 -960 166 -1610 -903 -1296 654 894 536 -664 -192 -849 752 219 2135 1529 662 826 2141 616 335 752 -177 2048 1261 1091 270 -715 -1513 -1615 1614 2362 715 1019 997 112 515 -1413 -2019 -3567 -1218 -2547 -2709 -1402 -2408 -558 -127 -112 1146 1092 1157 1105 140 170 -1386 -518 -1157 -804 -137 662 415 -213 -1047 -1664 -690 -1082 -988 -1214 -208 -545 249 1278 1469 940 969 368 -1061 -519 47 -368 -106 218 219 443 794 335 601 -101 -42 -377 -13 16 -573 -133 318 651 405 -211 -122 192 -350 -37 -67 -788 248 -143 -22 351 -285 -372 -513 -518 -69 -235 -706 -1345 287 -170 280 280 496 78 616 -331 1 45 -148 176 915 70 -363 -777 53 549 785 622 31 266 -2272 -1092 -1155 -201 -104 -496 92 -941 -540 -783 384 534 312 -379 -106 -470 431 135 1348 1023 455 576 1502 435 236 528 -129 1574 1032 944 236 -571 -1134 -1193 1235 2014 665 982 953 104 443 -1122 -1466 -2534 -891 -2097 -2470 -1365 -2504 -593 -145 -134 1429 1393 1470 1365 160 180 -1354 -500 -1181 -899 -165 866 560 -284 -1314 -1967 -776 -1295 -1266 -1617 -289 -788 369 1985 2368 1513 1478 529 -1441 -665 60 -500 -152 331 338 667 1181 474 808 -132 -52 -481 -17 22 -852 -199 483 1029 673 -367 -216 347 -634 -65 -114 -1318 SS 20220704T232207.7Z 8220.973700 203 1 47.18 2 45.24 100.36 102.91 65.31 0.00 1 0.00 1 0 17 1.080e-02 6.954e-03 3.772e-03 1.561e-03 2.096700e-01 8.174173e-04 2.550074e-03 -6.000000e+00 6.401269e-03 233.04 -2.00 3.56 -2.00 316.68 0.00e+00 6.690494e-04 1.001490e-04 1.788980e-04 -6.000000e+00 2.807204e-04 286.98 -2.00 20.00 -2.00 315.90 0.00e+00 1.418 0.000 302.00 328.00 3 4.9262e+00 2.1556e-03 1.8135e-02 -6.0000e+00 1.6098e-02 4.5242e-02 2.3970e-03 1.1137e-02 -6.0000e+00 1.7324e-02 -3.2851e-03 1.3995e-03 5.3940e-03 -6.0000e+00 1.0298e-02 -6.2069e-03 6.6793e-04 1.5016e-03 -6.0000e+00 4.4120e-03 7.2109e-04 1.9196e-04 4.4557e-05 1.6210e-05 -6.0000e+00 2.8637e-04 -3.3810e-03 8.2806e-05 11 8 0 10 0 0 99.88 18.29 0.37 -0.00338 -0.00194 30 8 1 5 0 1572.370 21.98 15.00 18.29 34.34 14.6 1055.68 -610 -281 -2087 -2358 -4488 -1207 -986 -670 1793 -1491 -1031 -3173 1957 -709 963 -308 538 389 921 828 1465 442 1565 1193 542 1241 -1448 -566 -781 427 722 1158 437 -878 -3628 -2744 -1961 -1339 220 -979 -711 -691 -389 -1102 -106 -222 -882 -393 -579 -37 505 1671 573 1575 549 897 918 416 63 683 1077 1282 1699 1380 648 -316 287 -344 1292 1141 240 490 265 296 -78 -454 -1116 -1878 -1396 -1087 -2047 -1553 -2216 -1467 -504 -291 468 497 655 396 608 202 -203 -107 380 203 3 68 50 -428 -578 -1057 -873 -98 -964 -1199 -631 -643 414 896 591 497 348 212 -9 200 513 -69 489 128 54 75 760 347 756 252 -75 398 114 -75 -183 -628 -265 126 198 183 309 105 -47 -166 -312 -902 -95 -47 -364 -390 -661 -168 -142 -108 312 -283 -190 -594 388 -163 245 -87 154 115 281 259 470 140 496 399 191 447 -534 -193 -256 134 237 401 163 -345 -1337 -982 -761 -580 112 -569 -446 -449 -260 -746 -70 -148 -573 -247 -364 -23 318 1113 402 1153 414 684 713 322 48 516 836 1069 1469 1264 590 -270 226 -264 1042 1023 233 494 266 286 -73 -378 -874 -1401 -1089 -927 -1947 -1569 -2386 -1586 -583 -358 587 638 836 485 702 219 -206 -106 400 229 3 88 67 -560 -728 -1234 -1006 -115 -1249 -1573 -866 -916 595 1359 911 761 520 300 -11 253 656 -92 688 191 79 111 1098 478 1013 324 -94 509 153 -106 -262 -913 -392 194 316 304 509 177 -79 -273 -512 -1432 SS 20220704T232616.4Z 8220.976579 206 1 4.37 2 44.50 101.21 102.26 66.07 0.00 1 0.00 1 0 17 1.012e-02 7.311e-03 3.283e-03 1.839e-03 2.055258e-01 9.698452e-04 2.490337e-03 -6.000000e+00 5.996051e-03 233.04 -2.00 3.56 -2.00 315.68 0.00e+00 5.084044e-04 9.566171e-05 8.733731e-05 -6.000000e+00 2.630488e-04 286.98 -2.00 20.00 -2.00 314.97 0.00e+00 1.400 0.000 302.00 328.00 3 3.3445e+00 2.5263e-03 1.7815e-02 -6.0000e+00 1.5078e-02 3.3742e-02 2.7965e-03 1.0856e-02 -6.0000e+00 1.6229e-02 -4.6252e-03 1.6059e-03 5.2479e-03 -6.0000e+00 9.6471e-03 -4.4239e-03 7.3432e-04 1.4475e-03 -6.0000e+00 4.1314e-03 3.6193e-03 -1.9286e-04 5.1372e-05 1.6779e-05 -6.0000e+00 2.6846e-04 -3.4072e-03 -9.6566e-06 12 9 1 12 1 1 57.54 18.29 0.28 -0.00341 -0.00486 10 32 1 5 0 381.370 21.98 15.00 18.29 34.59 14.6 1057.29 843 -386 -1292 -2524 -2381 -2725 602 -726 1248 -2165 -2417 -1886 842 462 844 387 -142 421 563 1002 1093 589 1561 1700 793 57 -22 -975 700 523 1490 891 1480 -1379 -3550 -2542 -1623 -1230 230 -858 -1090 -1129 -83 -703 96 72 -857 -9 -1081 -29 592 1013 629 1325 178 575 851 343 274 816 1305 1246 1392 1169 659 -513 -71 -442 1090 1701 536 558 -171 521 192 -725 -512 -1221 -1424 -1090 -2200 -1716 -2375 -1397 -475 -412 309 540 839 409 567 -121 -268 10 360 69 384 -68 -62 -33 -702 -1032 -361 -44 -762 -1320 -446 -576 244 512 669 346 503 133 304 416 827 44 456 -113 26 103 633 211 661 493 164 527 -202 -194 -292 -374 -98 134 -6 227 55 266 38 -240 -188 -1062 196 -98 -337 -629 -516 -563 125 -171 319 -604 -658 -509 246 152 312 144 -54 165 228 415 467 247 656 750 369 28 -11 -443 290 229 677 395 698 -695 -1666 -1159 -801 -700 143 -579 -798 -857 -64 -550 74 56 -646 -6 -769 -20 431 786 510 1124 145 475 715 287 225 666 1092 1123 1342 1117 624 -472 -61 -392 949 1682 540 585 -179 523 192 -653 -447 -1015 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