File name: Pandora196s1_Sapporo_20220710_L2Fit_fout2c10d20220307p1-8.txt File generation date: 20250121T121232.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v10d20220307.txt Level 1 file used: Pandora196s1_Sapporo_20220710_L1_smca1c10d20220307p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20220710 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0528 305.1941 305.3353 305.4766 305.6178 305.7590 305.9003 306.0415 306.1826 306.3238 306.4650 306.6062 306.7473 306.8884 307.0296 307.1707 307.3118 307.4529 307.5940 307.7350 307.8761 308.0172 308.1582 308.2992 308.4402 308.5813 308.7223 308.8632 309.0042 309.1452 309.2861 309.4271 309.5680 309.7089 309.8498 309.9907 310.1316 310.2725 310.4134 310.5542 310.6951 310.8359 310.9767 311.1176 311.2584 311.3992 311.5399 311.6807 311.8215 311.9622 312.1030 312.2437 312.3844 312.5251 312.6658 312.8065 312.9472 313.0878 313.2285 313.3691 313.5097 313.6504 313.7910 313.9316 314.0721 314.2127 314.3533 314.4938 314.6344 314.7749 314.9154 315.0559 315.1964 315.3369 315.4774 315.6179 315.7583 315.8987 316.0392 316.1796 316.3200 316.4604 316.6008 316.7412 316.8815 317.0219 317.1622 317.3026 317.4429 317.5832 317.7235 317.8638 318.0040 318.1443 318.2846 318.4248 318.5650 318.7053 318.8455 318.9857 319.1258 319.2660 319.4062 319.5463 319.6865 319.8266 319.9667 320.1068 320.2469 320.3870 320.5271 320.6672 320.8072 320.9472 321.0873 321.2273 321.3673 321.5073 321.6473 321.7873 321.9272 322.0672 322.2071 322.3470 322.4870 322.6269 322.7667 322.9066 323.0465 323.1864 323.3262 323.4660 323.6059 323.7457 323.8855 324.0253 324.1651 324.3048 324.4446 324.5843 324.7241 324.8638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220709T230654.8Z 8225.963134 217 1 48.01 2 48.47 97.78 156.28 9.30 0.00 1 0.00 1 0 17 1.015e-02 6.649e-03 3.144e-04 1.344e-04 2.071772e-01 7.048162e-05 2.531630e-03 -6.000000e+00 6.017978e-03 233.06 -2.00 3.56 -2.00 316.62 0.00e+00 5.937715e-04 8.497486e-06 1.614259e-04 -6.000000e+00 2.644424e-04 287.44 -2.00 20.00 -2.00 315.84 0.00e+00 1.505 0.000 302.00 328.00 3 4.9105e-02 1.8553e-04 1.8737e-02 -6.0000e+00 1.5132e-02 2.7393e-02 2.0608e-04 1.1043e-02 -6.0000e+00 1.6284e-02 -4.7795e-03 1.2015e-04 5.3388e-03 -6.0000e+00 9.6825e-03 -6.0091e-03 5.7320e-05 1.4759e-03 -6.0000e+00 4.1492e-03 8.8336e-02 -5.8857e-05 3.8348e-06 1.6536e-05 -6.0000e+00 2.6930e-04 -3.8432e-03 2.3972e-05 11 8 0 10 0 0 97.40 17.95 0.32 -0.00384 -0.00429 3762 970 1 5 0 12.160 21.69 15.00 17.95 28.44 14.7 1000.45 283 -1517 -1647 -3419 -3662 -1716 -996 424 110 -1513 -2790 -1969 29 -360 736 306 -223 834 950 1149 1246 443 1506 1262 706 429 -590 -1043 -302 420 1235 1002 949 -869 -3603 -2191 -2035 -974 -74 -511 -1012 -788 -352 -452 -207 96 -708 -305 -685 -4 567 1000 733 1095 401 870 830 295 266 692 1098 1611 1532 1395 479 -486 -22 -338 1161 1335 276 595 84 378 -31 -655 -823 -1503 -1103 -1197 -1824 -1717 -2189 -1548 -543 -373 417 281 547 410 501 309 -239 203 413 93 163 224 -81 -369 -561 -969 -569 -15 -874 -1244 -567 -624 263 622 653 295 454 177 182 375 607 241 407 63 17 140 551 307 778 385 8 558 8 -80 -289 -574 -253 213 179 29 233 106 -38 -222 -230 -885 43 -252 -280 -617 -577 -252 -151 71 20 -301 -549 -383 6 -86 197 90 -68 258 303 376 421 147 502 443 261 164 -227 -376 -101 134 410 354 358 -348 -1352 -795 -806 -442 -40 -291 -628 -506 -232 -300 -135 63 -454 -189 -414 -2 353 663 508 797 300 657 639 227 200 519 846 1328 1355 1305 447 -412 -17 -258 932 1222 274 614 86 374 -29 -545 -622 -1190 -831 -1019 -1727 -1786 -2422 -1772 -609 -446 522 362 700 502 563 346 -244 202 437 108 191 289 -110 -484 -690 -1104 -678 -17 -1108 -1644 -784 -897 392 905 987 444 702 253 238 464 762 318 579 95 27 211 810 430 1031 489 11 685 11 -112 -422 -850 -381 334 276 47 382 178 -64 -362 -366 -1364 SS 20220709T231626.6Z 8225.969752 220 1 47.96 2 46.75 99.64 155.97 14.51 0.00 1 0.00 1 0 17 1.006e-02 6.675e-03 3.113e-04 1.387e-04 2.017547e-01 7.282321e-05 2.467976e-03 -6.000000e+00 5.962812e-03 233.06 -2.00 3.56 -2.00 316.50 0.00e+00 5.649600e-04 8.522985e-06 1.542488e-04 -6.000000e+00 2.620664e-04 287.44 -2.00 20.00 -2.00 315.72 0.00e+00 1.457 0.000 302.00 328.00 3 1.9092e-01 1.9140e-04 1.8174e-02 -6.0000e+00 1.4993e-02 2.6994e-02 2.1223e-04 1.0749e-02 -6.0000e+00 1.6136e-02 -4.4722e-03 1.2349e-04 5.1961e-03 -6.0000e+00 9.5940e-03 -6.1205e-03 5.8650e-05 1.4317e-03 -6.0000e+00 4.1106e-03 8.1206e-02 -2.5033e-04 3.9600e-06 1.6176e-05 -6.0000e+00 2.6693e-04 -3.6925e-03 -1.1429e-05 11 8 0 10 0 0 38.37 17.97 0.32 -0.00369 -0.00557 3331 859 1 5 0 13.800 21.69 15.01 17.97 30.00 14.7 1012.53 422 -1451 -1561 -3457 -3515 -1660 -984 534 211 -1259 -2716 -1814 99 -267 818 288 -245 887 938 1155 1300 400 1530 1228 772 387 -555 -1131 -267 379 1248 1003 927 -874 -3658 -2150 -2065 -905 -101 -473 -1002 -772 -355 -440 -217 94 -696 -309 -699 -20 519 999 693 1075 403 846 825 268 291 688 1088 1570 1508 1392 471 -496 -47 -354 1122 1367 272 570 56 394 -30 -700 -826 -1506 -1107 -1247 -1840 -1735 -2177 -1562 -528 -392 410 272 554 413 498 313 -251 215 398 67 171 222 -69 -327 -555 -961 -598 -59 -863 -1261 -554 -638 248 601 677 328 458 195 188 340 613 236 392 85 32 161 550 327 797 385 2 537 23 -83 -292 -564 -250 190 183 21 227 100 -30 -228 -214 -895 68 -255 -281 -659 -584 -257 -157 94 41 -263 -561 -370 22 -67 228 88 -78 285 312 393 456 138 529 448 296 153 -221 -423 -92 125 428 365 360 -360 -1411 -801 -840 -421 -56 -277 -638 -508 -240 -299 -145 63 -456 -196 -431 -12 329 674 489 795 306 649 645 209 222 524 851 1314 1354 1320 445 -427 -37 -273 909 1263 273 594 59 394 -28 -588 -631 -1203 -840 -1069 -1753 -1815 -2421 -1647 -596 -472 517 351 712 508 562 353 -257 214 422 79 201 286 -94 -429 -683 -1095 -713 -68 -1094 -1669 -766 -917 370 874 1022 493 652 279 245 421 766 310 556 128 49 243 806 456 1053 488 3 657 30 -116 -424 -830 -374 296 280 34 369 166 -49 -370 -337 -1372 SS 20220709T232318.8Z 8225.974524 224 1 48.10 2 45.51 101.03 155.66 18.19 0.00 1 0.00 1 0 17 9.929e-03 6.716e-03 3.054e-04 1.405e-04 1.968447e-01 7.370037e-05 2.403291e-03 -6.000000e+00 5.886541e-03 233.06 -2.00 3.56 -2.00 316.40 0.00e+00 5.417450e-04 8.447641e-06 1.424616e-04 -6.000000e+00 2.586073e-04 287.44 -2.00 20.00 -2.00 315.63 0.00e+00 1.425 0.000 302.00 328.00 3 2.5959e-01 1.9355e-04 1.7751e-02 -6.0000e+00 1.4802e-02 2.6592e-02 2.1463e-04 1.0474e-02 -6.0000e+00 1.5927e-02 -3.7021e-03 1.2450e-04 5.0624e-03 -6.0000e+00 9.4705e-03 -6.3522e-03 5.8823e-05 1.3988e-03 -6.0000e+00 4.0596e-03 7.8996e-02 2.2907e-04 3.9947e-06 1.5902e-05 -6.0000e+00 2.6327e-04 -4.2412e-03 7.7815e-05 11 8 0 10 0 0 99.79 17.97 0.31 -0.00424 -0.00252 3208 827 1 5 0 14.350 21.69 14.97 17.97 31.22 14.6 1022.72 420 -1420 -1512 -3278 -3400 -1584 -834 490 233 -1332 -2579 -1888 110 -282 832 231 -219 873 972 1180 1287 419 1473 1190 719 444 -477 -956 -202 442 1293 1013 946 -877 -3574 -2188 -2099 -996 -155 -535 -1014 -795 -363 -423 -213 108 -678 -296 -678 -2 521 992 685 1061 408 890 826 293 287 700 1066 1540 1474 1375 477 -494 -61 -386 1107 1323 274 567 70 424 13 -637 -851 -1510 -1097 -1228 -1883 -1753 -2198 -1572 -554 -400 411 281 548 417 526 295 -255 139 410 68 158 254 -61 -356 -566 -987 -565 -55 -853 -1241 -571 -626 258 620 671 319 450 185 162 342 606 222 416 74 30 148 538 306 802 366 -4 575 47 -69 -284 -569 -255 216 199 33 237 103 -34 -245 -241 -916 71 -261 -284 -652 -589 -255 -138 90 47 -290 -554 -400 25 -73 240 73 -71 289 333 414 465 149 525 446 283 181 -195 -367 -71 149 453 377 375 -369 -1406 -831 -871 -472 -87 -318 -657 -533 -249 -292 -145 74 -452 -190 -424 -1 334 678 489 794 313 690 653 231 222 538 842 1303 1336 1316 455 -428 -49 -299 902 1229 277 593 73 426 12 -538 -653 -1210 -835 -1056 -1799 -1837 -2448 -1660 -625 -482 519 363 706 514 595 333 -262 138 435 80 185 327 -82 -466 -694 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