File name: Pandora196s1_Sapporo_20220715_L2Fit_fwvt1c10d20220307p1-8.txt File generation date: 20250121T121722.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v10d20220307.txt Level 1 file used: Pandora196s1_Sapporo_20220715_L1_smca1c10d20220307p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20220715 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1622 1771 Nominal wavelengths inside fitting window [nm]: 492.0250 492.1466 492.2682 492.3897 492.5113 492.6328 492.7544 492.8759 492.9974 493.1188 493.2403 493.3617 493.4832 493.6046 493.7260 493.8473 493.9687 494.0901 494.2114 494.3327 494.4540 494.5753 494.6965 494.8178 494.9390 495.0602 495.1814 495.3026 495.4237 495.5449 495.6660 495.7871 495.9082 496.0293 496.1503 496.2714 496.3924 496.5134 496.6344 496.7554 496.8764 496.9973 497.1182 497.2391 497.3600 497.4809 497.6018 497.7226 497.8434 497.9642 498.0850 498.2058 498.3266 498.4473 498.5680 498.6888 498.8094 498.9301 499.0508 499.1714 499.2920 499.4127 499.5332 499.6538 499.7744 499.8949 500.0155 500.1360 500.2565 500.3769 500.4974 500.6178 500.7383 500.8587 500.9790 501.0994 501.2198 501.3401 501.4604 501.5808 501.7010 501.8213 501.9416 502.0618 502.1820 502.3022 502.4224 502.5426 502.6628 502.7829 502.9030 503.0231 503.1432 503.2633 503.3833 503.5034 503.6234 503.7434 503.8634 503.9834 504.1033 504.2232 504.3432 504.4631 504.5830 504.7028 504.8227 504.9425 505.0623 505.1821 505.3019 505.4217 505.5414 505.6612 505.7809 505.9006 506.0203 506.1399 506.2596 506.3792 506.4988 506.6184 506.7380 506.8576 506.9771 507.0966 507.2162 507.3357 507.4551 507.5746 507.6940 507.8135 507.9329 508.0523 508.1717 508.2910 508.4104 508.5297 508.6490 508.7683 508.8876 509.0068 509.1261 509.2453 509.3645 509.4837 509.6029 509.7220 509.8412 509.9603 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220714T192025.1Z 8230.805846 173 1 15.86 2 88.94 60.89 83.47 227.99 0.00 1 0.00 1 0 29 1.090e-02 1.067e-02 2.367e-03 2.355e-03 2.401437e+04 1.934482e+02 1.385195e+03 -6.000000e+00 6.600375e+02 287.88 -2.00 20.00 -2.00 505.50 0.00e+00 3.408896e-03 6.878626e-05 2.187927e-04 -6.000000e+00 3.188664e-04 287.88 -2.00 20.00 -2.00 501.09 0.00e+00 1.752037e+00 4.745320e-02 1.736421e-01 -6.000000e+00 2.243040e-01 233.08 -2.00 3.56 -2.00 502.59 0.00e+00 18.362 0.119 489.00 513.00 1 5.4890e+00 3.6433e-03 3.4804e-02 -6.0000e+00 1.7286e-02 -5.4432e-02 8.8742e-04 4.3215e-03 -6.0000e+00 4.3957e-03 4.7980e-04 -7.9073e-03 2.2814e-04 1.1293e-04 -6.0000e+00 1.2787e-03 4.7476e-03 5.4746e-04 12 9 9 12 1 1 98.63 17.72 5.40 0.00475 -0.05010 3 3 1 4 0 3921.240 21.48 15.00 17.72 24.66 14.7 969.00 -3640 -3200 -1970 -146 -303 769 898 1162 1081 770 306 -513 -1093 -1238 -856 -1162 -1009 -80 554 512 774 948 1489 916 1395 988 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59 -121 -333 -83 780 1340 1124 1924 1611 952 266 177 -564 -729 -2235 -1986 -1170 -149 -23 256 -883 -911 -1441 -1416 -11 153 425 969 1426 1624 1866 2569 2026 31 336 -493 -424 91 1030 1226 935 829 0 122 -52 -451 -1015 -1070 -1699 -1209 -213 -289 -126 387 594 27 288 505 118 722 -19 -875 -1647 -1846 900000 SQ 20220714T205453.1Z 8230.871448 233 1 47.34 2 72.94 76.14 96.97 243.85 0.00 1 0.00 1 0 22 2.784e-03 2.752e-03 1.587e-04 1.582e-04 5.805020e+03 1.109790e+01 3.891372e+02 -6.000000e+00 1.685345e+02 287.89 -2.00 20.00 -2.00 505.26 0.00e+00 5.217357e-04 4.546237e-06 3.531281e-05 -6.000000e+00 8.139599e-05 287.89 -2.00 20.00 -2.00 500.38 0.00e+00 2.240723e-01 3.245321e-03 3.925083e-02 -6.000000e+00 5.707806e-02 233.08 -2.00 3.56 -2.00 501.98 0.00e+00 3.356 0.001 489.00 513.00 1 3.7193e+00 2.5067e-04 5.8851e-03 -6.0000e+00 4.4033e-03 7.6941e-03 6.2361e-05 9.6625e-04 -6.0000e+00 1.1123e-03 2.8530e-02 2.3225e-03 1.7412e-05 3.2848e-05 -6.0000e+00 3.2698e-04 5.2502e-03 -9.6957e-05 10 0 0 10 0 0 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142 48 -210 -443 -450 -298 SQ 20220714T213935.9Z 8230.902499 258 1 5.16 2 64.91 83.23 104.09 250.76 0.00 1 0.00 1 0 22 2.671e-03 2.654e-03 8.335e-05 8.319e-05 4.357738e+03 5.675929e+00 2.890664e+02 -6.000000e+00 1.615714e+02 287.89 -2.00 20.00 -2.00 505.29 0.00e+00 3.972448e-04 2.378807e-06 2.778745e-05 -6.000000e+00 7.804112e-05 287.89 -2.00 20.00 -2.00 500.45 0.00e+00 9.991327e-02 1.696761e-03 3.217437e-02 -6.000000e+00 5.467221e-02 233.08 -2.00 3.56 -2.00 502.05 0.00e+00 2.343 0.000 489.00 513.00 1 3.6684e-01 1.3050e-04 4.3417e-03 -6.0000e+00 4.2177e-03 4.4171e-03 3.2750e-05 7.6163e-04 -6.0000e+00 1.0649e-03 9.5449e-01 7.3194e-04 9.2630e-06 2.2226e-05 -6.0000e+00 3.1113e-04 -1.7498e-03 1.9126e-05 10 0 0 10 0 0 99.19 17.78 0.57 -0.00175 0.00333 2004 517 1 4 0 2.400 21.48 15.00 17.78 27.18 14.7 987.84 -478 -338 -270 41 -109 -179 183 251 322 168 -31 187 -23 -196 -189 -197 -146 -98 270 205 8 198 234 265 382 270 152 247 47 -446 -373 -97 -343 71 279 -23 -258 -130 -49 8 156 225 252 301 388 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428 295 289 125 211 510 358 139 206 -32 43 208 -67 -302 -151 -268 -347 -47 77 -98 6 48 38 63 132 93 106 41 -188 -402 -403 -255 SQ 20220714T213954.1Z 8230.902709 258 4 5.12 2 64.86 83.28 104.14 250.80 0.00 1 0.00 1 0 22 2.678e-03 2.657e-03 7.982e-05 7.968e-05 4.357189e+03 5.410952e+00 2.889642e+02 -6.000000e+00 1.619996e+02 287.89 -2.00 20.00 -2.00 505.27 0.00e+00 4.145065e-04 2.289840e-06 2.854767e-05 -6.000000e+00 7.825183e-05 287.89 -2.00 20.00 -2.00 500.45 0.00e+00 9.280927e-02 1.624861e-03 3.224271e-02 -6.000000e+00 5.483274e-02 233.08 -2.00 3.56 -2.00 502.04 0.00e+00 2.338 0.000 489.00 513.00 1 2.9970e-01 1.2547e-04 4.3446e-03 -6.0000e+00 4.2299e-03 3.9967e-03 3.1301e-05 7.6319e-04 -6.0000e+00 1.0683e-03 1.0217e+00 1.2099e-03 8.8250e-06 2.3425e-05 -6.0000e+00 3.1283e-04 2.4049e-04 -1.6824e-05 10 0 0 10 0 0 99.82 17.78 0.56 0.00024 0.00863 2004 517 1 4 0 2.400 21.48 15.00 17.78 27.18 14.7 987.84 -464 -336 -272 44 -91 -152 188 262 327 180 -39 191 -26 -179 -189 -196 -160 -102 264 197 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