File name: Pandora196s1_Sapporo_20220724_L2Fit_fout2c10d20220307p1-8.txt File generation date: 20250121T121310.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v10d20220307.txt Level 1 file used: Pandora196s1_Sapporo_20220724_L1_smca1c10d20220307p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20220724 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0528 305.1941 305.3353 305.4766 305.6178 305.7590 305.9003 306.0415 306.1826 306.3238 306.4650 306.6062 306.7473 306.8884 307.0296 307.1707 307.3118 307.4529 307.5940 307.7350 307.8761 308.0172 308.1582 308.2992 308.4402 308.5813 308.7223 308.8632 309.0042 309.1452 309.2861 309.4271 309.5680 309.7089 309.8498 309.9907 310.1316 310.2725 310.4134 310.5542 310.6951 310.8359 310.9767 311.1176 311.2584 311.3992 311.5399 311.6807 311.8215 311.9622 312.1030 312.2437 312.3844 312.5251 312.6658 312.8065 312.9472 313.0878 313.2285 313.3691 313.5097 313.6504 313.7910 313.9316 314.0721 314.2127 314.3533 314.4938 314.6344 314.7749 314.9154 315.0559 315.1964 315.3369 315.4774 315.6179 315.7583 315.8987 316.0392 316.1796 316.3200 316.4604 316.6008 316.7412 316.8815 317.0219 317.1622 317.3026 317.4429 317.5832 317.7235 317.8638 318.0040 318.1443 318.2846 318.4248 318.5650 318.7053 318.8455 318.9857 319.1258 319.2660 319.4062 319.5463 319.6865 319.8266 319.9667 320.1068 320.2469 320.3870 320.5271 320.6672 320.8072 320.9472 321.0873 321.2273 321.3673 321.5073 321.6473 321.7873 321.9272 322.0672 322.2071 322.3470 322.4870 322.6269 322.7667 322.9066 323.0465 323.1864 323.3262 323.4660 323.6059 323.7457 323.8855 324.0253 324.1651 324.3048 324.4446 324.5843 324.7241 324.8638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220724T002022.2Z 8240.014146 352 1 47.68 2 37.46 116.99 26.26 227.64 0.00 1 0.00 1 0 17 1.024e-02 6.902e-03 2.665e-03 1.306e-03 1.699152e-01 6.865152e-04 2.075907e-03 -6.000000e+00 6.067158e-03 232.78 -2.00 3.56 -2.00 316.26 0.00e+00 4.444096e-04 7.649446e-05 1.490159e-04 -6.000000e+00 2.675656e-04 288.16 -2.00 20.00 -2.00 315.49 0.00e+00 1.259 0.000 302.00 328.00 3 4.3806e+00 1.7972e-03 1.5528e-02 -6.0000e+00 1.5242e-02 5.4207e-02 1.9943e-03 9.0117e-03 -6.0000e+00 1.6400e-02 -4.4074e-03 1.1504e-03 4.3559e-03 -6.0000e+00 9.7589e-03 -5.8380e-03 5.3699e-04 1.1962e-03 -6.0000e+00 4.1896e-03 1.5799e-03 4.1191e-04 3.6936e-05 1.3678e-05 -6.0000e+00 2.7147e-04 -4.5252e-03 1.2239e-04 11 8 0 10 0 0 99.98 17.18 0.24 -0.00453 -0.00143 158 41 1 5 0 301.670 20.96 15.00 17.18 28.40 15.0 997.87 1244 -1039 -1104 -3087 -4457 -254 -424 1089 124 -874 -2629 -1333 35 25 1039 447 -303 548 902 771 1477 234 1967 955 1358 156 -202 -1091 -284 313 887 1376 604 -493 -4002 -1881 -2509 -1093 -247 -337 -1010 -891 -356 -621 -458 -227 -648 -328 -412 -30 574 1114 906 1120 621 773 792 180 301 835 987 1520 1531 1481 392 -171 -72 -346 1232 1275 376 652 113 510 116 -844 -652 -1629 -1135 -1261 -1848 -1775 -2273 -1501 -541 -415 402 304 565 494 417 234 -369 201 157 -55 63 280 12 -448 -585 -1045 -438 -160 -804 -1268 -329 -644 342 672 715 313 589 255 191 369 389 294 242 115 -40 175 431 364 828 282 -53 455 -15 -177 -198 -528 -157 278 261 55 163 129 -55 -238 -257 -952 254 -232 -251 -673 -854 -44 -76 214 27 -204 -605 -298 9 7 309 145 -101 184 312 273 534 83 696 357 527 63 -81 -412 -108 113 331 536 251 -215 -1640 -737 -1078 -534 -142 -205 -667 -608 -248 -436 -317 -157 -434 -232 -282 -20 399 820 694 816 462 581 606 151 248 683 830 1363 1333 1354 355 -154 -60 -277 1031 1216 353 635 110 525 112 -734 -511 -1210 -875 -1093 -1774 -1866 -2534 -1725 -605 -496 502 389 719 602 467 263 -376 197 164 -63 79 347 16 -564 -759 -1258 -505 -196 -1078 -1613 -436 -886 486 1004 1105 481 851 340 255 467 499 395 351 162 -57 246 592 521 1122 366 -66 567 -20 -249 -288 -778 -235 432 392 86 260 211 -90 -380 -399 -1440 SS 20220724T010149.6Z 8240.042936 380 1 47.90 2 31.15 130.23 32.30 242.26 0.00 1 0.00 1 0 17 1.164e-02 8.355e-03 5.346e-03 2.886e-03 1.697229e-01 1.520067e-03 2.064645e-03 -6.000000e+00 6.893829e-03 232.78 -2.00 3.56 -2.00 315.89 0.00e+00 5.463768e-04 1.562089e-04 1.360102e-04 -6.000000e+00 3.040800e-04 288.16 -2.00 20.00 -2.00 315.15 0.00e+00 1.168 0.000 302.00 328.00 3 6.2452e+00 3.9715e-03 1.4791e-02 -6.0000e+00 1.7318e-02 8.6988e-02 4.3976e-03 8.9438e-03 -6.0000e+00 1.8636e-02 -1.4203e-02 2.5262e-03 4.3234e-03 -6.0000e+00 1.1089e-02 -2.8622e-03 1.1584e-03 1.1937e-03 -6.0000e+00 4.7595e-03 2.6513e-04 1.2181e-04 8.1789e-05 1.3859e-05 -6.0000e+00 3.0861e-04 -4.0885e-03 8.2773e-05 11 8 0 10 0 0 99.92 17.15 0.29 -0.00409 -0.00317 12 3 1 5 0 3991.320 20.96 15.00 17.15 29.72 15.0 1007.95 -1382 -155 -981 -2245 -2883 -2665 -1417 1555 -238 -3055 -1980 -2534 267 -589 938 -367 1624 536 1830 964 1820 1124 1729 787 925 931 -767 159 -1474 2064 180 827 454 -580 -3631 -2950 -2295 -1749 -116 -255 -315 -705 564 -978 452 -429 7 -788 -1115 -512 674 1423 702 1363 177 982 1230 571 -1036 1053 502 1907 1177 1867 797 -420 -489 -1359 1002 833 357 414 653 453 -90 -799 -1177 -2319 -1796 -1435 -2293 -1839 -2674 -1181 -649 33 815 857 555 613 434 -82 -843 -765 199 -553 371 204 788 -437 -309 -1336 -869 -494 -826 -1100 -275 -374 364 1217 972 764 483 519 -580 -233 746 88 329 10 271 204 811 -115 1071 260 -296 -298 -164 -537 -398 -768 -219 532 98 140 107 429 69 -68 -290 -958 -324 -38 -248 -548 -622 -540 -292 346 -59 -825 -511 -647 74 -180 314 -135 594 202 701 386 743 449 692 332 405 419 -349 68 -595 769 71 338 198 -264 -1545 -1234 -1038 -893 -68 -171 -225 -523 423 -748 341 -327 5 -567 -776 -348 472 1053 535 1081 144 804 1020 472 -864 860 424 1679 1113 1814 779 -378 -412 -1110 847 781 361 429 680 455 -86 -696 -944 -1790 -1415 -1246 -2176 -1903 -2900 -1310 -763 41 1047 1110 719 771 508 -90 -854 -751 205 -618 443 259 1040 -564 -378 -1568 -977 -579 -1044 -1446 -371 -524 520 1817 1485 1156 701 712 -744 -286 917 112 446 15 394 292 1137 -156 1389 324 -354 -363 -209 -714 -548 -1069 -309 763 149 221 169 692 113 -109 -451 -1450 SS 20220724T011435.0Z 8240.051794 389 1 11.72 2 29.44 135.11 34.33 245.93 0.00 1 0.00 1 0 17 9.722e-03 7.397e-03 2.908e-03 1.970e-03 1.579460e-01 1.046330e-03 1.929691e-03 -6.000000e+00 5.758646e-03 232.78 -2.00 3.56 -2.00 314.91 0.00e+00 5.404512e-04 8.833347e-05 5.102834e-05 -6.000000e+00 2.540013e-04 288.16 -2.00 20.00 -2.00 314.26 0.00e+00 1.148 0.000 302.00 328.00 3 4.7143e+00 2.7091e-03 1.4248e-02 -6.0000e+00 1.4466e-02 5.9439e-02 2.9841e-03 8.3653e-03 -6.0000e+00 1.5567e-02 -8.1007e-03 1.7067e-03 4.0305e-03 -6.0000e+00 9.2630e-03 -4.1910e-03 7.5910e-04 1.1255e-03 -6.0000e+00 3.9760e-03 1.2933e-03 2.4166e-04 5.4824e-05 1.3898e-05 -6.0000e+00 2.5777e-04 -4.2542e-03 8.6226e-05 12 9 1 12 1 1 99.90 17.16 0.33 -0.00425 -0.00244 9 11 1 5 0 1154.460 20.96 15.00 17.16 30.16 15.0 1010.63 1020 -577 -1188 -2565 -3518 -1299 -347 1369 587 -170 -2012 -1574 -40 -605 625 73 464 561 1157 721 1608 87 2185 1313 921 617 -178 -1184 -673 820 1228 1483 626 -562 -3410 -1748 -2388 -834 -450 -355 -593 -1038 -434 -486 -180 -298 -406 -622 -641 -254 557 1064 717 1138 218 1058 380 445 482 680 876 1788 1281 1250 349 -427 131 -89 1028 1147 492 540 191 179 117 -741 -477 -1533 -1208 -1392 -1678 -2010 -2367 -1771 -852 -376 30 517 567 381 266 448 -229 493 412 68 304 81 187 -243 -469 -926 -454 -238 -758 -1124 -551 -599 400 357 891 547 405 265 87 410 610 238 273 115 -11 63 519 431 772 393 -93 459 532 -16 -315 -712 -278 73 151 65 319 169 -280 -99 -306 -965 322 -197 -414 -851 -1121 -381 -104 448 194 -60 -692 -529 -15 -245 277 35 226 278 586 374 851 45 1126 713 522 360 -104 -648 -338 387 596 751 338 -317 -1797 -884 -1324 -524 -308 -280 -466 -846 -361 -406 -148 -245 -322 -515 -511 -199 449 907 586 971 190 928 341 396 420 591 782 1695 1302 1235 367 -405 114 -81 902 1146 493 563 198 193 118 -673 -422 -1285 -1050 -1255 -1667 -2192 -2537 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