File name: Pandora196s1_Sapporo_20220909_L2Fit_fout2c1d20220907p1-8.txt File generation date: 20250121T124251.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v1d20220907.txt Level 1 file used: Pandora196s1_Sapporo_20220909_L1_smca1c1d20220907p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20220909 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0502 305.1915 305.3327 305.4740 305.6153 305.7565 305.8977 306.0389 306.1802 306.3214 306.4625 306.6037 306.7449 306.8860 307.0272 307.1683 307.3094 307.4506 307.5917 307.7327 307.8738 308.0149 308.1560 308.2970 308.4380 308.5791 308.7201 308.8611 309.0021 309.1431 309.2840 309.4250 309.5659 309.7069 309.8478 309.9887 310.1296 310.2705 310.4114 310.5523 310.6932 310.8340 310.9748 311.1157 311.2565 311.3973 311.5381 311.6789 311.8197 311.9604 312.1012 312.2419 312.3827 312.5234 312.6641 312.8048 312.9455 313.0861 313.2268 313.3675 313.5081 313.6487 313.7894 313.9300 314.0706 314.2112 314.3517 314.4923 314.6329 314.7734 314.9139 315.0545 315.1950 315.3355 315.4760 315.6164 315.7569 315.8974 316.0378 316.1782 316.3187 316.4591 316.5995 316.7399 316.8802 317.0206 317.1610 317.3013 317.4416 317.5820 317.7223 317.8626 318.0029 318.1431 318.2834 318.4237 318.5639 318.7041 318.8444 318.9846 319.1248 319.2649 319.4051 319.5453 319.6854 319.8256 319.9657 320.1058 320.2459 320.3860 320.5261 320.6662 320.8063 320.9463 321.0864 321.2264 321.3664 321.5064 321.6464 321.7864 321.9264 322.0663 322.2063 322.3462 322.4861 322.6261 322.7660 322.9059 323.0457 323.1856 323.3255 323.4653 323.6052 323.7450 323.8848 324.0246 324.1644 324.3042 324.4439 324.5837 324.7234 324.8632 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220908T204823.8Z 8286.866942 182 1 47.95 2 83.33 88.77 118.99 271.37 0.00 1 0.00 1 0 17 6.148e-01 3.390e-02 3.631e-01 2.050e-02 8.132640e-01 1.267200e-02 9.430009e-03 -6.000000e+00 3.694125e-01 229.77 -2.00 3.56 -2.00 322.16 0.00e+00 -1.597441e-03 6.975674e-03 6.461637e-03 -6.000000e+00 1.927088e-02 286.70 -2.00 20.00 -2.00 321.67 0.00e+00 7.826 0.009 302.00 328.00 3 1.3403e+00 4.9774e-02 9.7882e-02 -6.0000e+00 9.2427e-01 1.0108e+00 6.4832e-02 6.9852e-02 -6.0000e+00 1.0022e+00 -1.4271e+00 5.0202e-02 2.8573e-02 -6.0000e+00 5.9049e-01 5.8105e-01 2.3640e-02 7.7143e-03 -6.0000e+00 2.5434e-01 2.6719e-05 -1.8294e-03 6.1687e-04 1.0291e-04 -6.0000e+00 1.7574e-02 1.2285e-03 -9.8176e-05 12 8 8 10 0 0 46.35 16.92 0.63 0.00123 -0.01252 35 9 1 5 0 1369.590 20.77 15.00 16.92 22.25 16.2 948.51 900000 -48753 134218 141501 -76059 900000 -78171 900000 -50728 900000 -117814 900000 -104822 900000 -2054 900000 -10381 38060 900000 6290 147832 -56733 900000 -46099 900000 -45714 900000 -27959 900000 -2184 243696 24538 25999 106623 -4746 258695 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-2223 994 -5704 2257 -2423 3410 -1048 3220 -1584 3286 -13 3091 740 -315 1845 -4276 3335 -6680 2759 -6193 1875 -5817 438 -3929 -595 -1276 -4912 -224 -5596 1005 -5336 595 -4984 3019 -3556 2980 -851 2514 811 -1880 760 -3399 3789 -3690 2936 40 8709 570 6017 -1308 3131 -583 1306 1617 -12 808 -5342 3301 -3456 4953 -3156 5779 -991 1204 -2641 -705 -4316 SS 20220908T205923.1Z 8286.874573 185 1 47.56 2 81.32 90.65 120.88 273.26 0.00 1 0.00 1 0 17 5.594e-01 1.242e-02 3.044e-01 5.792e-03 7.138623e-01 3.293711e-03 9.003126e-03 -6.000000e+00 3.274363e-01 229.77 -2.00 3.56 -2.00 321.74 0.00e+00 6.597208e-03 1.870274e-03 6.902720e-03 -6.000000e+00 1.463861e-02 286.69 -2.00 20.00 -2.00 321.21 0.00e+00 6.252 0.005 302.00 328.00 3 1.1159e+00 1.2658e-02 8.0210e-02 -6.0000e+00 8.1691e-01 2.2776e-01 1.8550e-02 5.7737e-02 -6.0000e+00 8.8156e-01 -3.3462e-01 1.8683e-02 3.0986e-02 -6.0000e+00 5.2591e-01 1.2850e-01 8.5161e-03 9.1574e-03 -6.0000e+00 2.2780e-01 1.7593e-04 -4.9850e-04 1.6533e-04 1.8061e-04 -6.0000e+00 1.4840e-02 6.3668e-05 -5.3838e-05 12 8 8 10 0 0 93.15 16.93 0.40 0.00006 -0.00368 112 29 1 5 0 424.570 20.77 15.00 16.93 22.81 16.2 952.13 -199401 900000 -225588 3270 -206773 -61623 -103447 -234627 -114704 -193072 -103174 -200388 107304 -157046 34481 -99858 152486 -69525 -31417 -26547 -53118 10611 -64237 -26736 -77942 45345 -83991 -8959 -81475 35471 -15181 15851 16336 -1284 3762 -28921 6574 -26395 12981 3314 15981 -2636 32782 2601 28583 6223 14653 12194 7702 11177 7108 20022 6853 13950 -2427 15146 2116 11155 1338 8911 5851 10565 9084 5409 6443 9 8627 -1598 8151 2267 6080 3171 3389 2144 -47 1334 -5159 -1972 -5812 -719 -2149 439 -3382 687 -111 1827 1046 1809 1289 1212 -175 -1962 -1034 -3747 -983 -2147 84 -660 78 -1483 -237 -2551 -1077 -384 -2435 -1985 -1873 -752 -681 1594 839 571 -52 -204 -640 125 354 489 346 213 920 269 1656 356 1013 -300 93 268 309 -23 -322 -576 -624 377 -10 478 -72 479 -251 143 -120 -757 -1842 900000 -3474 18 -2335 -348 -584 -3975 -648 -2577 -583 -3395 606 -2983 195 -1692 861 -1106 -408 -345 -845 96 -1270 -393 -2025 358 -2466 -121 -2300 340 -300 277 332 -34 89 -947 167 -1103 447 150 713 -152 1407 156 1340 380 844 757 531 802 598 1673 712 1481 -319 1736 284 1354 174 1067 753 1456 1452 1020 1273 2 1637 -350 1813 623 1744 972 1012 608 -12 311 -1232 -474 -1677 -238 -841 192 -1684 347 -61 1043 633 1111 791 713 -97 -1055 -537 -2131 -627 -1624 72 -654 83 -1571 -230 -2270 -875 -321 -2258 -1911 -1931 -826 -835 2163 1272 909 -83 -316 -946 178 519 752 567 359 1499 422 2491 523 1432 -417 125 395 526 -44 -679 -1289 -1483 863 -24 1220 -188 1261 -657 352 -307 -1836 SS 20220908T211228.0Z 8286.883658 190 1 47.65 2 78.94 92.90 123.12 275.56 0.00 1 0.00 1 0 17 3.373e-01 7.027e-03 1.118e-01 2.134e-03 5.988555e-01 1.171193e-03 7.281601e-03 -6.000000e+00 1.974226e-01 229.77 -2.00 3.56 -2.00 321.15 0.00e+00 4.524740e-03 5.655196e-04 3.880116e-03 -6.000000e+00 8.758024e-03 286.69 -2.00 20.00 -2.00 320.57 0.00e+00 5.024 0.002 302.00 328.00 3 8.2182e-01 4.0041e-03 6.1632e-02 -6.0000e+00 4.9250e-01 2.7189e-02 5.5395e-03 3.9208e-02 -6.0000e+00 5.3152e-01 -4.6017e-02 5.5253e-03 2.1526e-02 -6.0000e+00 3.1677e-01 5.7520e-03 2.6380e-03 6.8041e-03 -6.0000e+00 1.3647e-01 8.5690e-04 -3.5895e-04 6.1427e-05 9.8825e-05 -6.0000e+00 8.9468e-03 -2.5900e-04 -5.5841e-05 11 8 0 10 0 0 24.66 16.95 0.32 -0.00026 -0.00296 308 79 1 5 0 154.690 20.77 15.00 16.95 23.89 16.3 961.01 -86147 -143880 -98037 -138929 -70250 -157521 -59556 -133278 -51617 -119472 -80075 -68635 -64802 -20907 -55869 -17459 -35298 -1138 -37202 -14476 -34474 -8163 -35404 -22807 -13669 -16416 -18941 -30090 -13444 -27574 384 -4934 1670 -12182 -8029 -14172 -8923 -3702 -5340 -1228 -2515 1570 -350 2843 -810 5121 -70 4417 543 3212 739 2456 3104 3311 2979 257 2326 -958 -1 -1230 2983 2667 4304 3358 3682 1483 1147 1268 2167 2685 941 2120 -93 903 -697 -1229 -2970 -2669 -2120 -1726 -1454 -1317 -2199 -1829 14 -403 1400 459 1268 423 1075 -353 -661 -420 -543 -39 96 595 -95 -167 -878 -1262 -1181 -239 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