File name: Pandora196s1_Sapporo_20221024_L2Fit_fout2c1d20220907p1-8.txt File generation date: 20250121T130029.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v1d20220907.txt Level 1 file used: Pandora196s1_Sapporo_20221024_L1_smca1c1d20220907p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20221024 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0502 305.1915 305.3327 305.4740 305.6153 305.7565 305.8977 306.0389 306.1802 306.3214 306.4625 306.6037 306.7449 306.8860 307.0272 307.1683 307.3094 307.4506 307.5917 307.7327 307.8738 308.0149 308.1560 308.2970 308.4380 308.5791 308.7201 308.8611 309.0021 309.1431 309.2840 309.4250 309.5659 309.7069 309.8478 309.9887 310.1296 310.2705 310.4114 310.5523 310.6932 310.8340 310.9748 311.1157 311.2565 311.3973 311.5381 311.6789 311.8197 311.9604 312.1012 312.2419 312.3827 312.5234 312.6641 312.8048 312.9455 313.0861 313.2268 313.3675 313.5081 313.6487 313.7894 313.9300 314.0706 314.2112 314.3517 314.4923 314.6329 314.7734 314.9139 315.0545 315.1950 315.3355 315.4760 315.6164 315.7569 315.8974 316.0378 316.1782 316.3187 316.4591 316.5995 316.7399 316.8802 317.0206 317.1610 317.3013 317.4416 317.5820 317.7223 317.8626 318.0029 318.1431 318.2834 318.4237 318.5639 318.7041 318.8444 318.9846 319.1248 319.2649 319.4051 319.5453 319.6854 319.8256 319.9657 320.1058 320.2459 320.3860 320.5261 320.6662 320.8063 320.9463 321.0864 321.2264 321.3664 321.5064 321.6464 321.7864 321.9264 322.0663 322.2063 322.3462 322.4861 322.6261 322.7660 322.9059 323.0457 323.1856 323.3255 323.4653 323.6052 323.7450 323.8848 324.0246 324.1644 324.3042 324.4439 324.5837 324.7234 324.8632 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221023T214148.2Z 8331.904030 109 1 47.58 2 83.37 112.74 65.65 119.16 0.00 1 0.00 1 0 17 5.452e-01 1.993e-02 4.385e-01 1.318e-02 9.875585e-01 8.023897e-03 1.109678e-02 -6.000000e+00 3.142681e-01 224.84 -2.00 3.56 -2.00 322.48 0.00e+00 9.598204e-03 4.985708e-03 1.969095e-03 -6.000000e+00 1.442146e-02 281.39 -2.00 20.00 -2.00 322.09 0.00e+00 7.879 0.009 302.00 328.00 3 2.7177e-01 3.3631e-02 9.8100e-02 -6.0000e+00 7.7624e-01 1.1832e+00 4.6596e-02 6.5716e-02 -6.0000e+00 8.4343e-01 -1.5652e+00 4.3069e-02 3.2085e-02 -6.0000e+00 5.0206e-01 6.1820e-01 1.9773e-02 1.4242e-02 -6.0000e+00 2.1691e-01 5.7969e-05 -1.7279e-03 3.6211e-04 1.9712e-04 -6.0000e+00 1.4592e-02 1.8215e-03 -1.0342e-04 12 8 8 10 0 0 66.12 16.91 0.48 0.00182 -0.01116 90 23 1 5 0 528.590 21.17 15.00 16.91 13.51 17.0 899.32 74968 -69535 -43930 -21649 -163346 153455 -160512 -12416 -155721 -71265 -178926 87702 -129363 900000 -42124 23478 33107 -47122 112428 -46739 900000 -61316 253321 -49096 144962 -41632 900000 -21027 62604 21015 -18965 900000 31985 107701 -34666 43019 -39189 52479 -23192 126649 14853 119194 9356 40054 30639 3577 14212 8332 58360 -3130 118281 31059 53621 22003 70834 45091 43255 45607 6257 30347 5415 21593 -5044 39306 13094 38515 10883 35367 13895 17830 24622 19372 20203 9765 10510 -15637 7229 -14828 4248 -8638 9384 -231 11076 1582 334 2174 -533 4798 -2021 2738 -3920 -1205 -9329 1440 -5910 438 172 -231 -176 -1595 -1691 -3627 -1753 -4707 -1129 -5437 -477 -5305 445 -739 762 -1161 194 -322 -1421 -181 -1583 -301 -239 2408 -295 3315 2549 3124 1176 1653 342 -246 541 -422 766 -455 -47 -585 541 166 594 305 122 -307 -797 -1378 962 -1041 -564 -278 -4718 1970 -4121 -159 -3816 -915 -5429 1126 -3472 900000 -787 301 425 -1320 1443 -1309 900000 -1717 3252 -1203 1861 -923 900000 -344 804 270 -463 900000 657 1383 -1214 718 -1560 943 -1042 1626 572 1683 408 1285 1062 165 602 396 1798 -193 2429 1714 2547 1554 3183 2663 2610 2576 490 1792 417 1580 -557 3229 1513 3412 1313 3541 1926 2747 3793 3208 3164 1542 1457 -2489 891 -2455 693 -1985 2132 -67 3185 526 120 801 -210 1817 -807 995 -1419 -410 -3473 532 -2807 236 110 -174 -146 -1327 -1305 -2500 -1065 -2985 -746 -3916 -353 -4529 414 -816 951 -1597 271 -446 -1931 -239 -2189 -432 -361 3571 -429 4354 3265 3870 1449 1988 411 -336 879 -804 1625 -1060 -119 -1586 1560 497 1783 927 364 -854 -2049 -3283 SS 20221023T215306.4Z 8331.911880 112 1 47.59 2 81.49 114.79 63.95 121.56 0.00 1 0.00 1 0 17 7.065e-01 1.227e-02 2.509e-01 4.239e-03 8.559045e-01 2.410882e-03 9.859351e-03 -6.000000e+00 4.063923e-01 224.84 -2.00 3.56 -2.00 321.99 0.00e+00 8.742619e-03 1.428297e-03 3.583755e-03 -6.000000e+00 1.826052e-02 281.39 -2.00 20.00 -2.00 321.56 0.00e+00 6.362 0.005 302.00 328.00 3 2.1079e-01 9.4188e-03 7.9606e-02 -6.0000e+00 1.0033e+00 3.7009e-01 1.4971e-02 5.1050e-02 -6.0000e+00 1.0879e+00 -5.2189e-01 1.6384e-02 3.2578e-02 -6.0000e+00 6.4831e-01 2.0527e-01 7.3419e-03 1.4573e-02 -6.0000e+00 2.8080e-01 3.2993e-04 -1.0310e-03 1.1389e-04 2.0096e-04 -6.0000e+00 1.8900e-02 1.0699e-03 -8.5158e-05 12 8 8 10 0 0 -5.38 16.93 0.33 0.00107 -0.00668 249 64 1 5 0 191.060 21.17 15.00 16.93 14.20 17.0 903.79 -194029 -263818 -105469 -238134 900000 -274490 -103476 -259119 -137439 -261113 -178588 -256077 -162164 -139167 -125974 -43309 -115350 -9728 -101824 -39873 -124917 -27378 -123953 -54479 -62392 -61738 -62956 -55612 -24170 -58028 -1888 -41928 6406 -17044 40585 -43299 18033 -22465 9955 -542 4948 9771 17211 26543 628 31349 801 32770 6282 32937 4803 18593 10257 12758 18600 10394 12419 5801 12050 -2958 15026 6507 20268 9458 15616 7372 9863 5303 5859 7494 4260 7520 2740 5132 -1056 2446 -4973 -1635 -3084 666 -615 -11 121 -1345 1488 -878 1542 177 2455 -302 1815 -1725 -1027 -3665 -1550 -1266 -1054 -21 -582 -126 -1894 -704 -1982 -174 -2407 -1920 -1880 -899 -431 263 630 -218 280 -632 -81 -384 816 -231 649 289 904 717 1661 845 388 150 -549 828 26 477 -381 -35 -466 166 -21 -58 311 215 97 -274 -1 -985 -948 -3072 -436 -2326 900000 -3300 -428 -3018 -568 -3629 -1141 -4137 -1401 -1307 -1372 -260 -1647 -60 -1568 -379 -2581 -226 -2514 -653 -851 -867 -911 -735 -240 -911 -22 -901 101 -373 470 -1145 283 -622 243 -17 170 343 597 866 27 1036 37 1192 322 1415 312 1199 788 1054 1530 962 1155 566 1061 -298 1316 702 2211 1333 2233 1130 1520 905 1118 1641 1042 1840 681 1152 -227 454 -966 -327 -738 189 -208 -4 52 -617 710 -453 813 97 1293 -157 858 -811 -476 -1898 -923 -896 -872 -20 -604 -128 -1820 -590 -1530 -135 -2067 -1709 -1798 -926 -502 351 857 -318 411 -912 -123 -569 1232 -369 987 447 1471 1104 2454 1218 546 206 -744 1232 47 868 -778 -77 -1091 414 -57 -162 869 610 270 -718 -1 -2249 SS 20221023T220711.2Z 8331.921657 117 1 46.90 2 79.18 117.39 61.89 124.66 0.00 1 0.00 1 0 17 4.534e-01 1.721e-02 4.365e-01 1.524e-02 6.974821e-01 8.600925e-03 8.651113e-03 -6.000000e+00 2.610550e-01 224.84 -2.00 3.56 -2.00 321.59 0.00e+00 1.086734e-02 4.437096e-03 4.463919e-03 -6.000000e+00 1.221668e-02 281.39 -2.00 20.00 -2.00 321.09 0.00e+00 5.129 0.003 302.00 328.00 3 3.7526e+00 3.0643e-02 6.4874e-02 -6.0000e+00 6.4433e-01 2.6955e-01 4.2112e-02 4.1210e-02 -6.0000e+00 6.9851e-01 -3.8214e-01 4.1724e-02 2.7127e-02 -6.0000e+00 4.1629e-01 1.5116e-01 1.9647e-02 1.2980e-02 -6.0000e+00 1.8102e-01 3.5070e-05 -1.0802e-03 4.3754e-04 1.9798e-04 -6.0000e+00 1.2140e-02 5.3959e-05 -2.9012e-05 12 8 8 10 0 0 99.69 16.98 0.40 0.00005 -0.00806 26 7 1 5 0 1803.480 21.27 15.00 16.98 15.62 17.0 914.87 -154498 -83358 -123728 -132267 900000 -237830 -41649 -204269 -160952 -80903 -75859 900000 -49264 -15197 -85023 -54231 -30947 18809 -120568 -7944 -72328 900000 6305 -3499 -48326 35873 8935 -29472 67044 -5931 -6980 -55382 64352 28708 86155 -290 4048 5321 -9538 -7630 -1978 5462 3084 22094 24809 53767 1409 18501 -4574 33765 5143 33393 23577 20936 23954 419 25960 2389 19703 -5882 10162 8316 18254 3694 15825 -4598 3933 5776 13527 8879 -1289 5835 -4923 2008 -3380 -1265 -2776 1224 -5284 2579 935 -644 -3429 -372 1693 -2738 2878 343 1248 -2703 -281 -2798 120 -2147 -1447 -3557 -1321 921 1127 -118 -1814 -342 -554 -1919 -3558 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