File name: Pandora196s1_Sapporo_20221204_L2Fit_fout2c1d20220907p1-8.txt File generation date: 20250121T132148.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v1d20220907.txt Level 1 file used: Pandora196s1_Sapporo_20221204_L1_smca1c1d20220907p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20221204 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0502 305.1915 305.3327 305.4740 305.6153 305.7565 305.8977 306.0389 306.1802 306.3214 306.4625 306.6037 306.7449 306.8860 307.0272 307.1683 307.3094 307.4506 307.5917 307.7327 307.8738 308.0149 308.1560 308.2970 308.4380 308.5791 308.7201 308.8611 309.0021 309.1431 309.2840 309.4250 309.5659 309.7069 309.8478 309.9887 310.1296 310.2705 310.4114 310.5523 310.6932 310.8340 310.9748 311.1157 311.2565 311.3973 311.5381 311.6789 311.8197 311.9604 312.1012 312.2419 312.3827 312.5234 312.6641 312.8048 312.9455 313.0861 313.2268 313.3675 313.5081 313.6487 313.7894 313.9300 314.0706 314.2112 314.3517 314.4923 314.6329 314.7734 314.9139 315.0545 315.1950 315.3355 315.4760 315.6164 315.7569 315.8974 316.0378 316.1782 316.3187 316.4591 316.5995 316.7399 316.8802 317.0206 317.1610 317.3013 317.4416 317.5820 317.7223 317.8626 318.0029 318.1431 318.2834 318.4237 318.5639 318.7041 318.8444 318.9846 319.1248 319.2649 319.4051 319.5453 319.6854 319.8256 319.9657 320.1058 320.2459 320.3860 320.5261 320.6662 320.8063 320.9463 321.0864 321.2264 321.3664 321.5064 321.6464 321.7864 321.9264 322.0663 322.2063 322.3462 322.4861 322.6261 322.7660 322.9059 323.0457 323.1856 323.3255 323.4653 323.6052 323.7450 323.8848 324.0246 324.1644 324.3042 324.4439 324.5837 324.7234 324.8632 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221203T231041.1Z 8372.965754 193 1 13.41 2 79.03 135.08 130.25 359.38 0.00 1 0.00 1 0 17 5.029e-01 1.194e-02 3.377e-01 8.347e-03 7.148738e-01 4.569883e-03 8.575683e-03 -6.000000e+00 2.865843e-01 222.53 -2.00 3.56 -2.00 321.34 0.00e+00 7.248934e-03 2.213833e-03 3.675411e-03 -6.000000e+00 1.325359e-02 276.48 -2.00 20.00 -2.00 320.89 0.00e+00 5.067 0.002 302.00 328.00 3 2.5989e+00 1.5294e-02 6.4102e-02 -6.0000e+00 7.0524e-01 1.3611e-01 2.1995e-02 4.1717e-02 -6.0000e+00 7.6635e-01 -2.1380e-01 2.4069e-02 2.7707e-02 -6.0000e+00 4.5657e-01 8.1266e-02 1.1434e-02 1.2449e-02 -6.0000e+00 1.9873e-01 1.2120e-04 -3.9174e-04 2.3034e-04 1.6460e-04 -6.0000e+00 1.3470e-02 3.9179e-04 -1.7859e-05 12 9 9 12 1 1 71.12 16.50 0.23 0.00039 -0.00255 12 12 1 5 0 1017.650 20.35 15.12 16.50 5.21 17.1 864.88 -141655 -52867 -102192 -117368 -62653 -81373 -186018 -228708 -104009 -238351 900000 -188816 -127648 -133922 -47936 -79777 -15232 -42765 -55635 -18922 -57544 900000 -84810 28767 -55260 126415 -9014 -31094 -33266 -9045 25762 -6233 14873 -34139 9497 -21223 48282 -5687 21567 3951 12524 604 7149 4399 12905 5930 -1998 14628 -6471 4636 7870 17841 334 9514 3548 9787 11554 8231 -120 1792 12068 7494 9674 2727 5019 3201 6499 2320 269 5847 715 2665 231 619 -356 -591 -5935 -2492 -3286 -660 -1116 -1404 -1524 -1403 -1666 -340 -103 526 -222 -74 455 -1357 445 -3222 -1188 -877 411 59 799 -370 -1002 -324 -1521 -289 -1560 -2021 -868 -289 697 960 464 67 819 -228 -248 -564 989 74 896 -152 879 -459 1129 157 -184 805 187 1449 -478 76 -194 -647 -484 -412 -410 234 433 561 201 -454 376 -887 -1152 -430 -831 -955 -510 -662 -1886 -3890 -846 -5376 900000 -3167 -1574 -2313 -470 -1318 -156 -641 -1018 -261 -1189 900000 -2296 284 -1299 1028 -148 -616 -685 -164 419 -164 379 -1512 265 -788 1021 -236 832 213 708 41 481 315 877 451 -167 1113 -637 441 816 1894 46 1313 547 1469 1750 1272 -20 284 1830 1316 1905 657 1254 792 1574 610 81 1898 264 1000 86 219 -116 -172 -1753 -752 -1137 -269 -523 -757 -884 -856 -1095 -233 -73 377 -161 -51 292 -855 269 -2116 -881 -749 395 64 915 -427 -1077 -312 -1386 -269 -1566 -2120 -963 -338 889 1362 723 108 1324 -359 -376 -830 1473 114 1462 -255 1421 -726 1708 234 -267 1120 258 2135 -805 141 -385 -1360 -1061 -949 -999 580 1081 1421 504 -1093 866 -1940 SS 20221203T231509.3Z 8372.968858 196 1 47.58 2 78.46 135.96 130.23 0.77 0.00 1 0.00 1 0 17 5.322e-01 9.594e-03 2.229e-01 4.058e-03 6.957633e-01 2.252306e-03 8.133407e-03 -6.000000e+00 3.030241e-01 222.53 -2.00 3.56 -2.00 321.52 0.00e+00 6.737917e-03 1.121910e-03 2.277941e-03 -6.000000e+00 1.404902e-02 276.48 -2.00 20.00 -2.00 321.08 0.00e+00 4.836 0.002 302.00 328.00 3 1.8206e+00 7.7470e-03 6.1068e-02 -6.0000e+00 7.4596e-01 8.7619e-02 1.1337e-02 3.9377e-02 -6.0000e+00 8.1082e-01 -1.6304e-01 1.2522e-02 2.5084e-02 -6.0000e+00 4.8355e-01 6.0150e-02 5.9013e-03 1.1295e-02 -6.0000e+00 2.1132e-01 3.3854e-04 -1.0048e-03 1.1656e-04 1.4102e-04 -6.0000e+00 1.4263e-02 1.6275e-03 -1.1402e-04 12 8 8 10 0 0 99.96 16.50 0.31 0.00163 -0.00592 218 56 1 5 0 218.210 20.35 14.94 16.50 5.36 17.2 866.41 -218876 900000 -223945 -101780 -160184 -216175 -148693 -201492 -65327 -176426 900000 -188832 107878 -124780 70814 -81622 -23737 -38998 -53320 -39351 -29070 3056 -66342 -1072 -52515 13695 -45671 5545 -45072 3398 -35143 -8332 13343 -2748 1109 -21292 11080 -4372 30041 -8706 12066 -6136 8099 -1553 1818 7299 4703 7808 4302 11447 3208 14632 1865 11572 682 7134 -387 3623 -922 1998 3577 1405 8407 3076 8971 2022 6802 272 4654 1958 4212 1880 440 673 -706 657 -3755 -299 -4652 926 -3025 260 -2953 -1253 -1118 -531 451 440 706 -146 1740 -1529 -195 -2363 183 -1511 598 4 245 -145 -700 -1262 -1540 -256 -1854 -1055 -1302 -224 135 1277 245 380 351 -87 -201 -298 416 -341 472 -94 715 209 1437 -31 860 -407 -103 309 -95 43 -278 -385 -348 236 -96 96 14 292 93 -16 17 -631 -2280 900000 -3115 -444 -1136 -2537 -973 -2418 -258 -2001 900000 -2913 427 -1855 280 -1269 -236 -511 -880 -596 -412 32 -1394 -13 -1110 163 -972 72 -987 50 -920 -210 317 -84 31 -714 308 -162 1002 -493 624 -409 499 -109 126 499 340 577 350 934 320 1471 232 1435 99 1009 -61 540 -139 292 536 242 1542 678 1974 462 1498 67 1215 611 1390 658 152 218 -211 173 -992 -82 -1481 336 -1327 127 -1620 -711 -681 -340 300 299 475 -95 1029 -886 -109 -1427 124 -1215 543 4 275 -160 -721 -1164 -1313 -222 -1775 -1042 -1379 -252 168 1781 382 616 566 -136 -297 -427 608 -526 766 -157 1151 323 2127 -45 1192 -554 -135 444 -157 80 -564 -827 -763 548 -240 247 37 775 244 -40 40 -1435 SS 20221203T231943.7Z 8372.972034 199 1 47.63 2 77.88 136.86 130.19 2.20 0.00 1 0.00 1 0 17 4.030e-01 6.774e-03 1.182e-01 2.042e-03 6.659997e-01 1.105005e-03 7.711642e-03 -6.000000e+00 2.293981e-01 222.53 -2.00 3.56 -2.00 321.27 0.00e+00 5.412506e-03 5.210270e-04 1.922056e-03 -6.000000e+00 1.002514e-02 276.48 -2.00 20.00 -2.00 320.81 0.00e+00 4.624 0.002 302.00 328.00 3 1.1437e+00 3.6187e-03 5.7893e-02 -6.0000e+00 5.6480e-01 4.0849e-02 5.2310e-03 3.6720e-02 -6.0000e+00 6.1384e-01 -8.8051e-02 5.8095e-03 2.3452e-02 -6.0000e+00 3.6564e-01 2.6516e-02 2.7813e-03 1.0505e-02 -6.0000e+00 1.5837e-01 8.4443e-04 -5.8548e-04 5.7636e-05 1.1158e-04 -6.0000e+00 1.0672e-02 1.1794e-03 -8.0284e-05 11 8 0 10 0 0 99.37 16.51 0.29 0.00118 -0.00322 302 78 1 5 0 157.670 20.35 14.95 16.51 5.63 17.2 869.25 -90048 -166014 -101719 -109693 -153281 -108820 -162644 -108624 -147150 -76642 -150130 -82192 -111094 -35883 -58244 -22327 -35635 -22111 -23635 -28674 -15231 -37794 -18789 -43730 -231 -44246 -2207 -41708 -12175 -31045 -6763 -7030 -4743 -2046 -18825 -10998 -15610 -813 -11692 5891 -5601 1422 -2657 2827 1561 4679 1304 -537 3816 -238 6526 870 6233 1617 4599 2172 2218 -775 -147 265 661 3342 2440 5079 2303 2696 664 1633 1858 3216 1285 1618 264 67 -712 -2108 -1397 -4223 -1209 -1698 -768 -1593 -1276 -1709 -377 -244 904 1241 872 1332 220 103 -1635 -788 -682 5 -72 666 135 -143 -624 -1067 -505 -791 -923 -1991 -413 -942 681 648 861 91 389 -111 -205 123 319 114 -11 -55 23 647 657 360 412 -127 -403 549 110 -303 -211 -630 -108 -95 60 -218 346 148 197 -84 122 -499 -305 -1292 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