File name: Pandora196s1_Sapporo_20221213_L2Fit_fout2c1d20220907p1-8.txt File generation date: 20250123T064935.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v1d20220907.txt Level 1 file used: Pandora196s1_Sapporo_20221213_L1_smca1c1d20220907p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20221213 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0502 305.1915 305.3327 305.4740 305.6153 305.7565 305.8977 306.0389 306.1802 306.3214 306.4625 306.6037 306.7449 306.8860 307.0272 307.1683 307.3094 307.4506 307.5917 307.7327 307.8738 308.0149 308.1560 308.2970 308.4380 308.5791 308.7201 308.8611 309.0021 309.1431 309.2840 309.4250 309.5659 309.7069 309.8478 309.9887 310.1296 310.2705 310.4114 310.5523 310.6932 310.8340 310.9748 311.1157 311.2565 311.3973 311.5381 311.6789 311.8197 311.9604 312.1012 312.2419 312.3827 312.5234 312.6641 312.8048 312.9455 313.0861 313.2268 313.3675 313.5081 313.6487 313.7894 313.9300 314.0706 314.2112 314.3517 314.4923 314.6329 314.7734 314.9139 315.0545 315.1950 315.3355 315.4760 315.6164 315.7569 315.8974 316.0378 316.1782 316.3187 316.4591 316.5995 316.7399 316.8802 317.0206 317.1610 317.3013 317.4416 317.5820 317.7223 317.8626 318.0029 318.1431 318.2834 318.4237 318.5639 318.7041 318.8444 318.9846 319.1248 319.2649 319.4051 319.5453 319.6854 319.8256 319.9657 320.1058 320.2459 320.3860 320.5261 320.6662 320.8063 320.9463 321.0864 321.2264 321.3664 321.5064 321.6464 321.7864 321.9264 322.0663 322.2063 322.3462 322.4861 322.6261 322.7660 322.9059 323.0457 323.1856 323.3255 323.4653 323.6052 323.7450 323.8848 324.0246 324.1644 324.3042 324.4439 324.5837 324.7234 324.8632 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221212T233439.7Z 8381.982404 333 1 1.82 2 77.34 139.57 68.41 279.27 0.00 1 0.00 1 0 17 4.951e-01 1.733e-02 3.032e-01 1.251e-02 6.059116e-01 6.671834e-03 7.113601e-03 -6.000000e+00 2.828820e-01 222.41 -2.00 3.56 -2.00 320.57 0.00e+00 2.253433e-03 2.587541e-03 1.333634e-03 -6.000000e+00 1.355760e-02 275.47 -2.00 20.00 -2.00 320.09 0.00e+00 4.438 0.002 302.00 328.00 3 2.3173e+00 2.0129e-02 5.4183e-02 -6.0000e+00 6.9851e-01 1.9052e-02 2.5960e-02 3.2368e-02 -6.0000e+00 7.6013e-01 -1.1933e-01 2.5951e-02 1.7740e-02 -6.0000e+00 4.5108e-01 5.4616e-02 1.3035e-02 6.0711e-03 -6.0000e+00 1.9623e-01 3.4126e-04 -3.2440e-04 3.5026e-04 7.0825e-05 -6.0000e+00 1.3607e-02 -8.5410e-04 -8.5761e-05 12 9 9 12 1 1 999.00 16.56 0.28 -0.00085 -0.00329 2 22 1 5 0 549.200 20.35 14.90 16.56 8.57 17.5 899.00 -204005 35401 -145459 900000 -165771 -52927 -117993 -110668 900000 -134889 900000 -144645 900000 -85099 900000 -49371 39169 -69904 42760 -11610 8806 56011 -16440 281122 -32454 190117 -55576 72297 -28874 49196 -29778 -15077 -21480 9382 7747 -22355 47360 -19046 48985 -6129 22922 -8772 13628 -1353 17942 -4602 9643 3113 6531 5920 1633 16448 678 14052 -367 9901 4318 -498 3745 5132 6494 -2440 10125 2295 7315 899 5959 -1564 5925 -1519 1258 -1286 783 -2331 40 -1 -1760 -352 -1782 3148 -5924 974 -4944 -2152 -1822 766 -855 761 379 1047 1288 -1899 2603 -2766 1329 -1207 -301 -1546 1746 -1521 166 -358 -2019 394 -2389 -545 -1373 899 -295 1101 -609 1246 -14 334 -650 354 388 -204 703 -1592 2405 -1391 2401 -338 1764 -150 -199 157 348 206 -334 315 -179 867 -259 434 -82 323 -1091 394 -731 -537 -5379 432 -2738 900000 -3390 -645 -1618 -1628 900000 -3102 900000 -4200 900000 -2216 900000 -1370 517 -2905 652 -313 203 814 -499 3427 -1371 2317 -3154 1171 -1226 1053 -1600 -823 -1440 509 401 -1546 1878 -1682 2758 -691 2193 -1204 1596 -188 2101 -688 1283 453 960 931 296 2913 149 2988 -94 2374 1130 -136 948 1286 1666 -744 3107 836 2675 332 2110 -608 2376 -746 643 -693 409 -1197 19 0 -723 -145 -836 1639 -3766 652 -3738 -1666 -1484 646 -763 675 338 897 1032 -1497 1927 -2220 1138 -1190 -326 -1858 2171 -1893 194 -388 -2093 416 -2733 -637 -1695 1150 -409 1639 -975 2011 -22 521 -982 519 579 -315 1136 -2661 3850 -2218 3680 -511 2565 -217 -281 235 564 362 -618 601 -354 1772 -561 955 -184 726 -2459 846 -1537 -1082 SS 20221212T233910.5Z 8381.985538 336 1 47.65 2 76.81 140.49 69.21 279.95 0.00 1 0.00 1 0 25 2.978e-01 6.036e-03 6.228e-02 1.477e-03 5.866064e-01 7.904234e-04 6.866931e-03 -6.000000e+00 1.694962e-01 222.41 -2.00 3.56 -2.00 320.96 0.00e+00 4.605317e-03 3.397564e-04 1.300691e-03 -6.000000e+00 7.378321e-03 275.47 -2.00 20.00 -2.00 320.48 0.00e+00 4.272 0.001 302.00 328.00 3 1.0556e+00 2.4913e-03 5.2345e-02 -6.0000e+00 4.1736e-01 -1.9774e-02 3.3583e-03 3.1649e-02 -6.0000e+00 4.5365e-01 -1.7290e-02 3.5633e-03 1.9166e-02 -6.0000e+00 2.7008e-01 2.8150e-04 1.7550e-03 8.3490e-03 -6.0000e+00 1.1697e-01 1.4209e-03 -5.8526e-04 4.2697e-05 8.8725e-05 -6.0000e+00 7.8824e-03 -9.5883e-04 -5.6639e-05 10 0 0 10 0 0 99.81 16.57 0.27 -0.00096 -0.00536 412 106 1 5 0 115.630 20.35 15.01 16.57 8.75 17.6 901.60 -85607 -101970 -82808 -101643 -116197 -107799 -114437 -82987 -97198 -53898 -94922 -57168 -78664 -27984 -40701 -34348 -17426 -26338 -17067 -24391 -5506 -21021 -10220 -21291 -7281 -21318 -8265 -23837 -12865 -20025 -9312 -3369 -5514 387 -11300 -6141 -11367 77 -5971 1094 -3524 -315 -1638 -454 1792 1266 1954 1334 2253 663 4166 2716 3708 1729 2856 1007 1247 16 -721 511 740 2926 2877 4272 2117 2474 1003 825 1473 2073 773 970 206 -198 -617 -2167 -1456 -2860 -1377 -1665 -952 -1380 -1896 -1691 -591 -121 677 866 878 1032 470 499 -949 -329 -471 99 372 374 89 -275 -457 -1117 -606 -628 -1033 -1587 -546 -728 644 729 810 445 395 98 -155 212 248 40 -134 -63 -242 222 485 316 536 138 -209 322 138 -71 -135 -447 -165 -97 86 -185 202 75 79 -18 127 -373 -481 -721 -585 -785 -1038 -870 -1055 -634 -966 -380 -1053 -486 -1065 -294 -616 -594 -286 -527 -339 -552 -108 -475 -216 -549 -175 -623 -218 -718 -347 -620 -311 -126 -243 18 -545 -281 -609 4 -440 90 -340 -32 -177 -50 196 144 225 161 281 89 604 448 656 341 585 218 278 4 -158 111 166 717 796 1309 693 773 316 267 525 853 349 455 96 -87 -249 -797 -503 -1020 -547 -789 -515 -853 -1280 -1198 -446 -96 563 735 740 832 354 353 -654 -235 -380 92 393 407 104 -315 -537 -1186 -595 -641 -1152 -1850 -671 -957 834 1050 1272 725 634 151 -224 294 353 59 -214 -103 -391 343 725 455 817 204 -299 494 218 -124 -257 -893 -346 -214 203 -456 502 190 199 -44 286 -802 SS 20221213T033137.0Z 8382.146955 473 1 47.91 2 67.78 195.64 105.23 318.40 0.00 1 0.00 1 0 17 4.755e-02 6.703e-03 3.439e-02 2.887e-03 3.763439e-01 1.470130e-03 4.588304e-03 -6.000000e+00 2.707398e-02 222.40 -2.00 3.56 -2.00 319.41 0.00e+00 1.689518e-03 3.850271e-04 5.716690e-04 -6.000000e+00 1.177825e-03 275.45 -2.00 20.00 -2.00 318.86 0.00e+00 2.622 0.000 302.00 328.00 3 4.3172e+00 4.0670e-03 3.2433e-02 -6.0000e+00 6.6668e-02 -1.1029e-02 4.7514e-03 1.9495e-02 -6.0000e+00 7.2448e-02 2.0662e-02 3.7977e-03 1.0277e-02 -6.0000e+00 4.3135e-02 -1.6941e-02 2.0200e-03 3.5184e-03 -6.0000e+00 1.8692e-02 3.2758e-04 -9.9763e-05 8.4935e-05 3.7102e-05 -6.0000e+00 1.2576e-03 -3.3826e-03 -3.2224e-06 11 8 0 10 0 0 99.95 16.71 0.30 -0.00338 -0.00413 51 13 1 5 0 939.270 20.56 15.06 16.71 10.66 17.7 915.80 -1786 -26216 9071 -23107 -2747 -17870 -5271 -23422 -2379 -9193 -16120 -5386 -6436 -3742 -5927 7774 -3410 4364 -2394 2064 -2537 3309 2402 1943 -1858 -2768 180 -4216 -551 -2596 4101 -1752 3178 -5839 -4703 -2742 -3955 -1970 -688 -1328 -1861 -380 -1671 330 -873 2055 -1625 1635 -1070 -152 599 1495 1487 759 1228 434 605 -1085 1251 14 1163 1466 2935 2153 1491 687 88 137 569 1936 170 1255 -355 576 -677 -529 -1620 -1735 -565 -1428 -1992 -1911 -1853 -1767 -198 -538 951 88 1091 586 720 266 -151 175 -189 173 326 536 -224 131 -976 -931 -1164 -124 -1209 -1269 -499 -711 539 685 978 354 677 -123 102 -58 428 -78 42 -406 -249 -93 389 631 329 561 -361 644 114 -15 -192 -433 -278 -19 230 -248 433 154 62 -110 48 -675 -38 -796 208 -712 -63 -457 -126 -758 -70 -313 -592 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