File name: Pandora196s1_Sapporo_20230206_L2Fit_fout2c1d20220907p1-8.txt File generation date: 20250123T071140.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v4d20210122.txt Instrument calibration file used: Pandora196s1_CF_v1d20220907.txt Level 1 file used: Pandora196s1_Sapporo_20230206_L1_smca1c1d20220907p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20230206 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0502 305.1915 305.3327 305.4740 305.6153 305.7565 305.8977 306.0389 306.1802 306.3214 306.4625 306.6037 306.7449 306.8860 307.0272 307.1683 307.3094 307.4506 307.5917 307.7327 307.8738 308.0149 308.1560 308.2970 308.4380 308.5791 308.7201 308.8611 309.0021 309.1431 309.2840 309.4250 309.5659 309.7069 309.8478 309.9887 310.1296 310.2705 310.4114 310.5523 310.6932 310.8340 310.9748 311.1157 311.2565 311.3973 311.5381 311.6789 311.8197 311.9604 312.1012 312.2419 312.3827 312.5234 312.6641 312.8048 312.9455 313.0861 313.2268 313.3675 313.5081 313.6487 313.7894 313.9300 314.0706 314.2112 314.3517 314.4923 314.6329 314.7734 314.9139 315.0545 315.1950 315.3355 315.4760 315.6164 315.7569 315.8974 316.0378 316.1782 316.3187 316.4591 316.5995 316.7399 316.8802 317.0206 317.1610 317.3013 317.4416 317.5820 317.7223 317.8626 318.0029 318.1431 318.2834 318.4237 318.5639 318.7041 318.8444 318.9846 319.1248 319.2649 319.4051 319.5453 319.6854 319.8256 319.9657 320.1058 320.2459 320.3860 320.5261 320.6662 320.8063 320.9463 321.0864 321.2264 321.3664 321.5064 321.6464 321.7864 321.9264 322.0663 322.2063 322.3462 322.4861 322.6261 322.7660 322.9059 323.0457 323.1856 323.3255 323.4653 323.6052 323.7450 323.8848 324.0246 324.1644 324.3042 324.4439 324.5837 324.7234 324.8632 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230205T230031.7Z 8436.958701 294 1 47.49 2 78.64 124.57 96.95 304.41 0.00 1 0.00 1 0 17 5.456e-01 8.272e-03 2.006e-01 3.040e-03 7.085345e-01 1.660385e-03 8.155367e-03 -6.000000e+00 3.127379e-01 224.36 -2.00 3.56 -2.00 321.46 0.00e+00 8.072560e-03 7.975442e-04 2.070943e-03 -6.000000e+00 1.339422e-02 273.21 -2.00 20.00 -2.00 321.05 0.00e+00 4.909 0.002 302.00 328.00 3 1.4329e+00 5.5797e-03 6.1960e-02 -6.0000e+00 7.7397e-01 9.5235e-02 8.3291e-03 3.9883e-02 -6.0000e+00 8.4058e-01 -1.6303e-01 9.5346e-03 2.7309e-02 -6.0000e+00 4.9906e-01 5.8646e-02 4.5099e-03 1.4529e-02 -6.0000e+00 2.1474e-01 4.5954e-04 -5.3085e-04 8.4900e-05 1.6287e-04 -6.0000e+00 1.4453e-02 3.6273e-04 -8.2379e-05 11 8 0 10 0 0 94.54 16.47 0.31 0.00036 -0.00363 211 54 1 5 0 225.030 20.14 15.01 16.47 4.13 18.0 905.35 -200252 -214149 -156031 -213981 -100781 -210119 -113195 -205084 171619 -175749 -35141 -159424 -85036 -110744 -70550 -32929 -59682 -3138 -56190 26404 -35011 6749 -60497 -12359 -33566 -21284 -57215 -42417 -30216 -38597 -12975 -23457 13198 -8967 3300 -23181 3499 -3095 4423 -10978 -3003 369 6520 3635 -4158 2999 1436 12954 540 11857 1571 9011 2654 9071 4191 2587 2902 -60 1114 -1585 3760 3114 7259 4677 4467 2589 2899 1060 2091 4204 2251 2803 -242 1407 -1535 -215 -4304 -2666 -2980 -472 -2154 -1491 -1792 -1105 -324 -710 1240 425 1797 324 1401 -884 -1636 -1953 -797 -217 227 541 175 242 -1284 -976 -1237 41 -1402 -1324 -936 -564 -44 744 576 167 128 -471 -121 -435 794 -132 408 205 682 412 834 531 249 -96 -652 591 -195 22 -413 -434 -335 34 4 -43 333 162 172 -121 131 -675 -1457 -2135 -967 -2364 -358 -1982 -470 -2155 509 -1823 -104 -1701 -580 -1313 -732 -293 -796 -27 -899 196 -498 62 -1130 -154 -547 -322 -1272 -805 -519 -801 -262 -640 293 -274 84 -770 99 -110 178 -615 -174 22 396 236 -298 210 106 898 45 956 158 954 327 1148 585 380 437 -9 164 -239 562 527 1351 1019 1034 593 670 260 567 1298 767 984 -85 456 -466 -58 -1157 -734 -951 -178 -958 -755 -993 -640 -200 -466 838 295 1222 214 850 -521 -946 -1206 -560 -178 213 582 204 275 -1375 -926 -1086 37 -1380 -1354 -1019 -659 -57 1081 927 257 215 -767 -185 -650 1206 -213 691 355 1142 658 1289 793 361 -136 -899 882 -338 43 -800 -889 -725 77 11 -111 857 424 443 -296 301 -1463 SS 20230205T230558.7Z 8436.962485 297 1 47.57 2 77.83 125.62 97.75 305.36 0.00 1 0.00 1 0 17 4.496e-01 7.061e-03 1.416e-01 2.929e-03 6.705393e-01 1.588874e-03 7.706952e-03 -6.000000e+00 2.576576e-01 224.36 -2.00 3.56 -2.00 321.29 0.00e+00 6.891552e-03 7.251027e-04 1.598048e-03 -6.000000e+00 1.103534e-02 273.21 -2.00 20.00 -2.00 320.86 0.00e+00 4.605 0.002 302.00 328.00 3 1.8549e+00 5.1171e-03 5.7988e-02 -6.0000e+00 6.3765e-01 6.8108e-02 7.3735e-03 3.6990e-02 -6.0000e+00 6.9254e-01 -1.1854e-01 8.3031e-03 2.4222e-02 -6.0000e+00 4.1116e-01 3.9223e-02 3.9944e-03 1.2293e-02 -6.0000e+00 1.7691e-01 4.1725e-04 -5.1500e-04 8.2521e-05 1.2522e-04 -6.0000e+00 1.1908e-02 3.8738e-04 -8.6891e-05 11 8 0 10 0 0 91.97 16.48 0.33 0.00039 -0.00348 144 37 1 5 0 330.260 20.25 15.00 16.48 4.39 18.0 907.43 -126314 -163664 -171196 -147170 -133635 -126579 -138192 -118605 -119959 -141274 -133814 -141527 -105984 -89854 -49455 -47257 -38452 -17686 -34706 -11942 -36727 -33638 -40605 -32688 -18899 -42723 -35268 -32961 -24705 -32018 -10676 -14004 7489 -8717 -12234 -12203 -10230 -8885 -2171 -1215 -3114 513 -258 2123 2280 5526 1979 7378 1813 3842 2146 4151 3730 4284 3001 2156 3608 -738 781 1141 4221 3536 5842 4310 3079 1692 1794 357 1321 3098 1435 1383 1322 1129 -1073 -1732 -3389 -2461 -3164 -1205 -1125 -1225 -1784 -1977 -441 -173 1175 1058 1013 622 345 -633 -1238 -1703 -986 -292 300 621 -42 47 -407 -1199 -535 -358 -1107 -1430 -1007 -683 608 746 649 280 400 -27 -337 -150 478 1 277 12 23 432 580 244 342 31 -368 700 19 -46 -205 -521 -371 -81 -47 39 273 80 169 -83 182 -563 -590 -1317 -1645 -1108 -798 -690 -897 -779 -891 -1284 -1299 -1543 -1181 -1129 -537 -621 -527 -222 -565 -164 -671 -586 -789 -635 -340 -1025 -806 -725 -508 -777 -259 -424 214 -321 -440 -439 -400 -406 -113 -75 -220 37 -20 169 184 451 172 641 176 393 251 536 526 658 490 368 624 -132 134 194 727 688 1266 1076 820 442 471 98 403 1078 549 549 512 411 -363 -529 -1008 -749 -1113 -500 -540 -673 -1073 -1253 -296 -122 863 794 754 444 229 -402 -767 -1122 -738 -253 297 701 -52 56 -452 -1196 -491 -340 -1146 -1544 -1156 -839 818 1024 982 442 626 -41 -482 -228 741 2 435 19 37 710 924 374 508 45 -516 1059 33 -82 -397 -1065 -801 -185 -114 98 699 210 435 -203 417 -1223 SS 20230205T231131.9Z 8436.966342 300 1 47.63 2 77.01 126.70 98.56 306.34 0.00 1 0.00 1 0 17 3.702e-01 7.950e-03 1.870e-01 3.484e-03 6.361587e-01 1.886957e-03 7.441277e-03 -6.000000e+00 2.122043e-01 224.36 -2.00 3.56 -2.00 321.16 0.00e+00 5.454840e-03 8.288298e-04 2.175732e-03 -6.000000e+00 9.088008e-03 273.21 -2.00 20.00 -2.00 320.72 0.00e+00 4.334 0.001 302.00 328.00 3 2.4762e+00 6.0338e-03 5.4997e-02 -6.0000e+00 5.2517e-01 5.3273e-02 8.3901e-03 3.5420e-02 -6.0000e+00 5.7035e-01 -8.6974e-02 9.2065e-03 2.2910e-02 -6.0000e+00 3.3862e-01 2.5913e-02 4.4798e-03 1.0468e-02 -6.0000e+00 1.4572e-01 2.9882e-04 -4.5932e-04 9.9827e-05 1.2141e-04 -6.0000e+00 9.8052e-03 -2.9085e-05 -7.6811e-05 11 8 0 10 0 0 93.75 16.50 0.24 -0.00003 -0.00348 99 26 1 5 0 481.020 20.25 15.00 16.50 4.67 18.0 909.20 -100965 -133746 -92826 -115298 -149605 -60805 -170467 -72428 -159588 -8692 -136905 -42386 -106842 -12664 -61284 -23127 -22625 -26415 3320 -26906 933 -46943 25435 -31019 23641 -46708 1741 -42729 -1077 -27032 -9891 106 -10653 3271 -17247 6304 -15714 12043 -10569 4463 -1903 4483 -5544 -314 3678 -797 6390 -2553 6738 441 9089 1076 7857 2993 6953 -856 1889 -378 -189 1522 -100 5647 3195 5808 1738 4119 154 3067 1286 3412 1321 1188 653 -1039 -234 -3699 -1119 -4172 -1209 -1915 -453 -2046 -1589 -2197 -175 -74 637 894 469 1105 -47 985 -1760 -372 -1541 553 -53 494 -136 -263 -548 -1147 -164 -905 -742 -1901 -38 -641 782 448 664 399 114 63 -549 175 180 195 -7 449 212 796 473 450 201 -291 -424 207 252 -681 -37 -816 -95 -139 227 -270 558 153 250 -110 -17 -507 -521 -1107 -572 -885 -1441 -246 -2116 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